Citation: Jie-Fen HUANG, Yi-Hao CHEN, Zhen-Hua LIANG, Sheng-Run ZHENG, Jun CAO. Structure and Properties of a Cd(II) Metal-organic Framework Based on a Newly Designed Heterotopic Tripodal N-Donor Ligand[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220207. doi: 10.14102/j.cnki.0254-5861.2011-3274 shu

Structure and Properties of a Cd(II) Metal-organic Framework Based on a Newly Designed Heterotopic Tripodal N-Donor Ligand

a.
School of Chemistry, South China Normal University, Guangzhou 510006, China
b.
School of Materials Science and Hydrogen Energy & Guangdong Key Laboratory for Hydrogen Energy Technologies, Foshan University, Foshan, Guangdong 528000, China

Corresponding author: Sheng-Run ZHENG, zhengsr@scnu.edu.cn Jun CAO, caojunbnu@mail.bnu.edu.cn
Received Date: 17 June 2021
Accepted Date: 2 September 2021

Fund Project: the Natural Science Foundation of China 22073032

Figures(7)

In this paper, a Cd(II) metal-organic framework (MOF), Cd-DIBT (HDIBT = 5-(3΄, 5΄-di(1H-imidazol-1-yl)-[1, 1΄-biphenyl]-4-yl)-1H-tetrazole), has been constructed based on a newly designed heterotopic tripodal ligand containing both imidazolyl and pyrazolyl groups. The Cd-DIBT exhibits a new three-dimensional (3, 3, 9)-connected trinodal network topology with point symbol of (4²·6)(4³)₂(4⁸·6¹⁵·8¹²·10) (namely scnu) based on binuclear secondary building blocks (SBUs). Staggered 1D channels were observed in such framework and was estimated to have 5487 Å³ potential solvent area (56%). The stability study reveals that the framework is unstable and easily transforms into amorphous MOF after the removal of guest molecules. In addition, the Cd-DIBT shows a ligand-centered luminescence.
- heterotopic tripodal ligand,
- metal-organic framework,
- topology,
- crystal structure
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