Citation: Jiang WU, Jin-Zhong GU. Synthesis, Structures, Luminescence and Catalytic Activity in the Knoevenagel Condensation Reaction of Two Cd(II) Coordination Polymers Based on a Biphenyl-dicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220203. doi: 10.14102/j.cnki.0254-5861.2011-3250 shu

Synthesis, Structures, Luminescence and Catalytic Activity in the Knoevenagel Condensation Reaction of Two Cd(II) Coordination Polymers Based on a Biphenyl-dicarboxylic Acid

Jiang WU ^a,, ,
Jin-Zhong GU ^b,,

a.
Key Laboratory for Tibet Plateau Phytochemistry of Qinghai Province, School of Pharmacy, Qinghai University for Nationalities, Xining 810007, China
b.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Jiang WU, wujiang@lzu.edu.cn Jin-Zhong GU, gujzh@lzu.edu.cn
Received Date: 11 May 2021
Accepted Date: 26 July 2021

Fund Project: the Science and Technology Plan of Qinghai Province 2018-ZJ-919

Figures(14)

Two cadmium(II) coordination polymers, namely [Cd(μ-dda)(H₂biim)]_n (1) and [Cd(μ₄-dda)(py)]_n (2) have been constructed hydrothermally using H₂dda (H₂dda = 4, 4΄-dihydroxybiphenyl-3, 3΄-dicarboxylic acid), H₂biim (H₂biim = 2, 2΄-biimidazole), py (py = pyridine), and cadmium chloride at 160 ℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA), and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that both compounds crystallize in the monoclinic system, space group C2/c. Compound 1 discloses a 1D chain structure. Compound 2 features a 3D framework. The luminescent properties of compounds 1 and 2 were evaluated. Besides, the catalytic activities in the Knoevenagel condensation reaction of two compounds were investigated. Compound 1 exhibits an excellent catalytic activity in the Knoevenagel condensation reaction at room temperature.
- coordination polymer,
- dicarboxylic acid,
- luminescence,
- catalytic properties,
- Knoevenagel condensation reaction
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