Citation: Meng-Qi PAN, Run-Qi YANG, Yaseen MUHAMMAD, Kun-Tong CAI, Feng HAN, Hao-Chen ZHANG, Yuan-Qing NIU, Hao WANG. Crystal Structure, Fe³⁺ Luminescence Sensing and Color Tuning of 2D Lanthanide-metal-organic Frameworks Constructed from Tricarboxylic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220202. doi: 10.14102/j.cnki.0254-5861.2011-3243 shu

Crystal Structure, Fe³⁺ Luminescence Sensing and Color Tuning of 2D Lanthanide-metal-organic Frameworks Constructed from Tricarboxylic Acid Ligand

a.
Beijing Key Lab of Special Elastomer Composite Materials, College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
b.
Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan

Corresponding author: Hao WANG, wangh@bipt.edu.cn
Received Date: 30 April 2021
Accepted Date: 15 July 2021

Fund Project: the High-level Teachers in Beijing Municipal Universities in the Period of 13th Five-year Plan CIT & TCD201904044URT program of Beijing Institute of Petrochemical Technology 2020J00009

Figures(11)

A new lanthanide metal-organic framework (MOF) [Eu(BTB)(phen)(DMF)]žDMF (1, DMF = N, N-dimethylformamide) was synthesized using H₃BTB (1, 3, 5-tri(4-carboxyphenyl)benzene) and phen (1, 10-phenanthroline) under solvothermal conditions. The structure of the prepared MOF was characterized by single-crystal X-ray diffraction analyses, elemental analysis, fluorescence spectrum, FT-IR spectroscopy, powder X-ray diffraction and thermogravimetric analyses. The structure of 1 can be viewed as a 3-D supramolecular network, which is formed by the stacking of 2D layers through π-π interaction. The luminescence explorations revealed that 1 possesses favorable selectivity and sensitivity for testing Fe³⁺. Additionally, color tuning was achieved by varying Eu³⁺: Tb³⁺ ratios in the reaction mixtures.
- lanthanide metal-organic frameworks,
- sensing,
- luminescence,
- Fe³⁺,
- color tuning
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Crystal Structure, Fe3+ Luminescence Sensing and Color Tuning of 2D Lanthanide-metal-organic Frameworks Constructed from Tricarboxylic Acid Ligand

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Crystal Structure, Fe³⁺ Luminescence Sensing and Color Tuning of 2D Lanthanide-metal-organic Frameworks Constructed from Tricarboxylic Acid Ligand