Citation: Fang-Min CHEN, Chi-Chi ZHOU, Xiong HE, Yan LI, Xiu-Qing ZHANG. Temperature-controlled Structural Diversity of Two Cd(II) Coordination Polymers Based on the Dicarboxylate Ligand[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220201. doi: 10.14102/j.cnki.0254-5861.2011-3234 shu

Temperature-controlled Structural Diversity of Two Cd(II) Coordination Polymers Based on the Dicarboxylate Ligand

a.
College of Chemistry and Bioengineering, Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, Guilin University of Technology, Guilin 541004, China

Corresponding author: Yan LI, ly741110@163.com Xiu-Qing ZHANG, glutchem@163.com
Received Date: 25 April 2021
Accepted Date: 29 June 2021

Fund Project: the Foundation of Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials EMFM20161102the National Natural Science Foundation of China 61765005

Figures(10)

Two new 3-D Cd(II) coordination polymers with p-phthalic acid (p-BDC) and 4, 4΄-dipyridylamine (4, 4΄-dpa), namely [Cd₂(p-BDC)₂(4, 4΄-dpa)₂]_n 1 and {[Cd(p-BDC)(4, 4΄-dpa) (H₂O)]·4H₂O}_n 2 were successfully synthesized under hydrothermal conditions at 120 and 140 ℃. They were characterized by single-crystal X-ray diffraction, IR, PXRD and TGA. It was further characterized by Hirshfeld surface (HS) analysis for complex 2. The luminescent properties of the complexes have also been investigated.
- Cd(II) coordination polymers,
- p-phthalic acid,
- Hirshfeld surface,
- Luminescent properties
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沈阳化工大学材料科学与工程学院沈阳 110142