Citation: Yi-Man WANG, Zhi-Wei PENG, Jia-Min LIAO, Ao LI, Yuan-Yan LIU, Jing-Jing ZHANG, Nian ZHOU, Xu-Dong LI, Shu LI, Wei MENG. A New Heterometallic 3d-3d Transition Metal Oxo-cluster {Cu₆^IIMn^III}: Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1661-1667. doi: 10.14102/j.cnki.0254-5861.2011-3229 shu

A New Heterometallic 3d-3d Transition Metal Oxo-cluster {Cu₆^IIMn^III}: Synthesis, Crystal Structure and Magnetic Property

Department of Materials & Chemistry Engineering, Hunan City University, Yiyang 413000, China

Corresponding author: Wei MENG, mengw198503@163.com
Received Date: 21 April 2021
Accepted Date: 28 May 2021

Fund Project: the National Natural Science Foundation of China 22001064the Natural Science Foundation of Hunan Province 2020JJ4155the Hunan Province College Students' Innovation Entrepreneurship Training Program 2020 No. 3373the Hunan Province College Students' Innovation Entrepreneurship Training Program 2021 No. 3340the Scientific Research Project of Hunan Province Department of Education 20B105

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A new transition metal-antimony oxo-cluster based compound has been synthesized in water under room temperature. Its formula is Na₆[Cu₆MnSb₆(μ₃-OH)₂(OH)(μ₄-O)₆(tartrate)₆]·20H₂O (1), where tartrate represents rac-tartaric acid. It was characterized by elemental analysis, infrared spectrum and X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system, space group P2₁/n. Structural analyses revealed that two Sb₃(μ₃-O)(tartrate)₃ scaffolds sandwich a Cu₆^IIMn^III middle layer to form the cluster. In the middle layer, all the seven metal ions lie in an almost regular hexagon, with Mn^III ion in the center and six Cu^II ions along the edges of the hexagon. As a 4-connected node, each cluster is interlinked to its nearest four {Cu₆Mn} neighbors through Na⁺, generating a 3D supramolecular framework. The temperature-dependent magnetic susceptibilities indicated dominating antiferromagnetic interactions in 1 with J_Cu–Cu = 176.34 and J_Cu–Mn = –14.44 cm⁻¹.
- dipotassium bis(μ-tartrato)-diantimony(III) ligand,
- heterometallic transition metal oxo-cluster,
- crystal structure,
- magnetic study
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A New Heterometallic 3d-3d Transition Metal Oxo-cluster {Cu₆^IIMn^III}: Synthesis, Crystal Structure and Magnetic Property