Citation: Yi-Man WANG, Zhi-Wei PENG, Jia-Min LIAO, Ao LI, Yuan-Yan LIU, Jing-Jing ZHANG, Nian ZHOU, Xu-Dong LI, Shu LI, Wei MENG. A New Heterometallic 3d-3d Transition Metal Oxo-cluster {Cu₆^IIMn^III}: Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1661-1667. doi: 10.14102/j.cnki.0254-5861.2011-3229 shu

A New Heterometallic 3d-3d Transition Metal Oxo-cluster {Cu₆^IIMn^III}: Synthesis, Crystal Structure and Magnetic Property

Department of Materials & Chemistry Engineering, Hunan City University, Yiyang 413000, China

Corresponding author: Wei MENG, mengw198503@163.com
Received Date: 21 April 2021
Accepted Date: 28 May 2021

Fund Project: the National Natural Science Foundation of China 22001064the Natural Science Foundation of Hunan Province 2020JJ4155the Hunan Province College Students' Innovation Entrepreneurship Training Program 2020 No. 3373the Hunan Province College Students' Innovation Entrepreneurship Training Program 2021 No. 3340the Scientific Research Project of Hunan Province Department of Education 20B105

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A new transition metal-antimony oxo-cluster based compound has been synthesized in water under room temperature. Its formula is Na₆[Cu₆MnSb₆(μ₃-OH)₂(OH)(μ₄-O)₆(tartrate)₆]·20H₂O (1), where tartrate represents rac-tartaric acid. It was characterized by elemental analysis, infrared spectrum and X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system, space group P2₁/n. Structural analyses revealed that two Sb₃(μ₃-O)(tartrate)₃ scaffolds sandwich a Cu₆^IIMn^III middle layer to form the cluster. In the middle layer, all the seven metal ions lie in an almost regular hexagon, with Mn^III ion in the center and six Cu^II ions along the edges of the hexagon. As a 4-connected node, each cluster is interlinked to its nearest four {Cu₆Mn} neighbors through Na⁺, generating a 3D supramolecular framework. The temperature-dependent magnetic susceptibilities indicated dominating antiferromagnetic interactions in 1 with J_Cu–Cu = 176.34 and J_Cu–Mn = –14.44 cm⁻¹.
- dipotassium bis(μ-tartrato)-diantimony(III) ligand,
- heterometallic transition metal oxo-cluster,
- crystal structure,
- magnetic study
1. [1]
  Zhang, Y. Y.; Gao, W. X.; Lin, L.; Jin, G. X. Recent advances in the construction and applications of heterometallic macrocycles and cages. Coord. Chem. Rev. 2017, 344, 323−344. doi: 10.1016/j.ccr.2016.09.010
2. [2]
  Ma, W.; Hu, B.; Jing, K. Q.; Li, Z.; Jin, J. C.; Zheng, S. T.; Huang, X. Y. Proton-conducting layered structures based on transition metal oxo-clusters supported by Sb(III) tartrate scaffolds. Dalton Trans. 2020, 49, 3849−3855. doi: 10.1039/C9DT04333K
3. [3]
  Sun, Y. Y.; Lu, D. F.; Sun, Y. X.; Gao, M. Y.; Zheng, N.; Gu, C.; Wang, F.; Zhang, J. Large titanium-oxo clusters as precursors to synthesize the single crystals of Ti-MOFs. ACS Materials Lett. 2021, 3, 64−68.
4. [4]
  Chen, W. T. A one-dimensional manganese(III)-porphyrin coordination polymer: crystal structure and photophysical properties. Acta Crystallogr. C 2020, 76, 375−380. doi: 10.1107/S2053229620004350
5. [5]
  Tan, Y. X.; Wang, F.; Zhang, J. Design and synthesis of multifunctional metal-organic zeolites. Chem. Soc. Rev. 2018, 47, 2130–2144. doi: 10.1039/C7CS00782E
6. [6]
  Chen, W. T. Structure, photophysical and electrochemical properties of a copper porphyrin with a three-dimensional framework. Acta Crystallogr. C 2020, 76, 133−138. doi: 10.1107/S2053229619017273
7. [7]
  Tan, H. H.; Lv, X. L.; Liu, J. L.; Cheng, Y. F.; Zhou, Q. L.; Lin, Y. T.; Meng, W. A 2D layer copper(II) coordination polymer with 3-nitrophthalic acid: synthesis, crystal structure and copper 3-nitrophthalate metal-organic framework-graphene oxide nanocomposite. Chin. J. Struct. Chem. 2021, 40, 459−464.
8. [8]
  O'Connor, H. M.; Sanz, S.; Scott, A. J.; Pitak, M. B.; Klooster, W. T.; Coles, S. J.; Chilton, N. F.; McInnes, E. J. L.; Lusby, P. J.; Weihe, H.; Piligkos, S.; Brechin, E. K. [Cr₈^IIINi₆^II]ⁿ⁺ heterometallic coordination cubes. Molecules 2021, 26, 757−766. doi: 10.3390/molecules26030757
9. [9]
  Dutta, S.; Ghosh, T. K.; Mahapatra, P.; Ghosh, A. Joining of trinuclear heterometallic Cu₂^II–M^II (M = Mn, Cd) nodes by nicotinate to form 1D chains: magnetic properties and catalytic activities. Inorg. Chem. 2020, 59, 14989−15003. doi: 10.1021/acs.inorgchem.0c01733
10. [10]
  Diego, R.; Pavlov, A.; Darawsheh, M.; Aleshin, D.; Nehrkorn, J.; Nelyubina, Y.; Roubeau, O.; Novikov, V.; Aromí, G. Coordination [Co₂^II] and [Co^IIZn^II] helicates showing slow magnetic relaxation. Inorg. Chem. 2019, 58, 9562−9566. doi: 10.1021/acs.inorgchem.9b01334
11. [11]
  Kobayashi, F.; Ohtani, R.; Kusumoto, S.; Lindoy, L. F.; Hayami, S.; Nakamura, M. Wheel-type heterometallic ferromagnetic clusters: [Ni₇-XM_x(HL)₆(μ₃-OMe)₄(μ₃-OH)₂]Cl₂ (M = Zn, Co, Mn; x = 1, 3). Dalton Trans. 2018, 47, 16422−16428. doi: 10.1039/C8DT03275K
12. [12]
  Stetsiuk, O.; Synytsia, V.; Petrusenko, S. R.; Kokozay, V. N.; El-Ghayoury, A.; Cano, J.; Lloret, F.; Julve, M.; Fleury, B.; Avarvari, N. Co-existence of ferro- and antiferromagnetic interactions in a hexanuclear mixed-valence Co₂^IIIMn₂^IIMn₂^IV cluster sustained by a multidentate Schiff base ligand. Dalton Trans. 2019, 48, 11862−11871. doi: 10.1039/C9DT02503K
13. [13]
  Liu, J.; Qu, M.; Clérac, R.; Zhang, X. M. A two-dimensional honeycomb coordination network based on fused triacontanuclear heterometallic {Co¹²Mn¹⁸} wheels. Chem. Commun. 2015, 51, 7356−7359. doi: 10.1039/C5CC01199J
14. [14]
  Milway, V. A.; Tuna, F.; Farrell, A. R.; Sharp, L. E.; Parsons, S.; Murrie, M. Directed synthesis of {Mn₁₈Cu₆} heterometallic complexes. Angew. Chem. Int. Ed. 2013, 52, 1949−1952. doi: 10.1002/anie.201208781
15. [15]
  Dutta, S.; Bhunia, P.; Mayans, J.; Drewc, M. G. B.; Ghosh, A. Roles of basicity and steric crowding of anionic coligands in catechol oxidase-like activity of Cu(II)–Mn(II) complexes. Dalton Trans. 2020, 49, 5730−5735. doi: 10.1039/D0DT00976H
16. [16]
  Grancha, T.; Mon, M.; Lloret, F.; Ferrando-Soria, J.; Journaux, Y.; Pasán, J.; Pardo, E. Double interpenetration in a chiral three-dimensional magnet with a (10, 3)‑a structure. Inorg. Chem. 2015, 54, 8890−8892. doi: 10.1021/acs.inorgchem.5b01738
17. [17]
  Liu, K.; Shi, W.; Cheng, P. Toward heterometallic single-molecule magnets: synthetic strategy, structures and properties of 3d-4f discrete complexes. Coord Chem Rev. 2015, 74−122.
18. [18]
  Meng, W.; Deng, Y. M.; Xu, F. Facile and environmentally friendly one-step synthesis of hexanuclear Cu(II)-Ni(II) and Cu(II)-Co(II) clusters and their binding interactions with bovine serum albumin. J. Solid State Chem. 2021, 295, 121904−121912. doi: 10.1016/j.jssc.2020.121904
19. [19]
  Meng, W.; Xu, F.; Xu, W. J. An anionic heptacopper(II) oxo-cluster {Cu₇^II} with an S = 7/2 ground state. Inorg. Chem. 2016, 55, 540−542. doi: 10.1021/acs.inorgchem.5b02206
20. [20]
  Gao, Q.; Wang, X. Q.; Tapp, J.; Moeller, A.; Jacobson, A. J. Antimony tartrate transition-metal-oxo chiral clusters. Inorg. Chem. 2013, 52, 6610−6616. doi: 10.1021/ic4006345
21. [21]
  Gao, Q.; Wang, X. Q.; Jacobson, A. J. A homochiral diamond framework constructed from Fe(III) and Mn(II) oxo-clusters supported by Sb(III) tartrate scaffolds. Chem. Commun. 2012, 48, 3990−3992. doi: 10.1039/c2cc18174f
22. [22]
  Gao, Q.; Wang, X. Q.; Conato, M. T.; Makarenko, T.; Jacobson, A. J. Microporous, homochiral structures containing iron oxo-clusters supported by antimony(III) tartrate scaffolds. Cryst. Growth Des. 2011, 11, 4632−4638. doi: 10.1021/cg200899w
23. [23]
  Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Solution. University of Göttingen, Germany 1997.
24. [24]
  Henkelis, J. J.; Jones, L. F.; Miranda, M. P.; Kilner, C. A.; Halcrow, M. A. Two heptacopper(II) disk complexes with a [Cu₇(μ₃-OH)₄(μ-OR)₂]⁸⁺ core. Inorg. Chem. 2010, 49, 11127−11132. doi: 10.1021/ic1020093
25. [25]
  Evans, H. T. Jr. The crystal structures of ammonium and potassium molybdotellurates. J. Am. Chem. Soc. 1948, 70, 1291−1292. doi: 10.1021/ja01183a521
26. [26]
  Ugandhar, U.; Navaneetha, T.; Ali, J.; Mondal, S.; Vaitheeswaran, G.; Baskar, V. Assembling homometallic Sb₆ and heterometallic Ti₄Sb₂ oxo clusters. Inorg. Chem. 2020, 59, 6689−6696. doi: 10.1021/acs.inorgchem.9b03238
27. [27]
  Fan, L. M.; Gao, L. L.; Wang, X. Q.; Wang, J.; Zhao, L.; Fang, K. G.; Hua, T. P. Structural diversity and magnetic properties of four Cu(II)/Co(II) coordination complexes based on 3, 5-bis(2-carboxylphenoxy)benzoic acid. Polyhedron 2018, 141, 133−139.
28. [28]
  Li, C. H.; Kuang, Y. F.; Li, W.; Li, Y. L. Hydrothermal synthesis, crystal structure and properties of a new binuclear cage-like yttrium(III) complex Y₂(TMBA)₆(phen)₂. Chin. J. Struct. Chem. 2020, 39, 2016−2020.
29. [29]
  Chilton, N. F.; Anderson, R. P.; Turner, L. D.; Soncini, A.; Murray, K. S. PHI: a powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d- and f-block complexes. J. Comput. Chem. 2013, 34, 1164−1175.
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A New Heterometallic 3d-3d Transition Metal Oxo-cluster {Cu₆^IIMn^III}: Synthesis, Crystal Structure and Magnetic Property