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Citation: Jian-Dong-Yong LIU, Xu YU, Jing-Ze BAO, Ying-Xi LIN. A Polyanionic, Quasi-zero-strain and Open-framework K0.76V0.55Nb0.45OPO4 for Sodium-ion Batteries[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1631-1638. doi: 10.14102/j.cnki.0254-5861.2011-3221 shu

A Polyanionic, Quasi-zero-strain and Open-framework K0.76V0.55Nb0.45OPO4 for Sodium-ion Batteries

  • a.

    CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • b.

    College of Chemistry, Fuzhou University, Fuzhou 350108, China

  • Corresponding author: Ying-Xi LIN, linyingxi90@foxmail.com
    • * These authors have contributed equally
  • Received Date: 15 April 2021
    Accepted Date: 31 May 2021

    Fund Project: the National Natural Science Foundation of China 21771180

Figures(5)

  • A carbon-coated K0.76V0.55Nb0.45OPO4 (KVNP@C) polyanion material was successfully synthesized by a simple sol-gel method. The KVNP@C possesses a highly stable inorganic open-framework structure, which is hard to be affected by the Na+ intercalation/deintercalation when used as an anode material for sodium-ion batteries (NIBs). The assembled KVNP@C/Na half-cell shows a capacity retention of 81.2% and an average Coulombic efficiency of 99.8% at a current density of 300 mA/g after 1500 cycles. In-situ XRD analysis reveals a single-phase solid solution reaction mechanism with a lattice expansion of 4.76%. This work sheds insights into the quest for developing novel polyanion-based anode materials for sodium-ion batteries.
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