Citation: Bing-Ben CHEN, Wen-Zhuo ZHAO, Zi-Bin CHEN, Yi-Hang WEN, Jian-Wen CHENG. Luminescent Tetra-nuclear Lanthanide-titanium-organic Compound Obtained by the Mixed-ligand[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1668-1672. doi: 10.14102/j.cnki.0254-5861.2011-3220 shu

Luminescent Tetra-nuclear Lanthanide-titanium-organic Compound Obtained by the Mixed-ligand

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: Jian-Wen CHENG, jwcheng@zjnu.cn
Received Date: 15 April 2021
Accepted Date: 14 May 2021

Fund Project: the NNSF of China 21975224

Figures(3)

A new heterometallic lanthanide-titanium-organic compound: [Eu₂Ti₂(dip)₆(dig)₂(H₃O)₂]·solvent (1, dip = diphenylglycolic acid, dig = diglycolic acid) has been synthesized under solvothermal conditions. Compound 1 contains a tetra-nuclear {Eu₂Ti₂} unit with the mixed ligands of dip and dig. Compound 1 displays intense red luminescence. Furthermore, the IR, PXRD, UV-vis and TGA spectra were also studied.
- lanthanide,
- titanium,
- luminescence
1. [1]
  Narayanam, N.; Chintakrinda, K.; Fang, W. H.; Kang, Y.; Zhang, L.; Zhang, J. Azole functionalized polyoxo-titanium clusters with sunlight-driven dye degradation applications: synthesis, structure, and photocatalytic studies. Inorg. Chem. 2016, 55, 10294−10301. doi: 10.1021/acs.inorgchem.6b01551
2. [2]
  Wang, J. F.; Fang, W. H.; Li, D. S.; Zhang, L.; Zhang, J. Cocrystal of {Ti₄} and {Ti₆} clusters with enhanced photochemical properties. Inorg. Chem. 2017, 56, 2367−2370. doi: 10.1021/acs.inorgchem.6b02913
3. [3]
  Gao, M. Y.; Fan, X.; Zhang, L.; Zhang, J. Dicarboxylate ligands oriented assembly of {Ti₃(μ₃-O)} units: from dimer to coordination triangles and rectangles. Inorg. Chem. 2018, 57, 5642−5647. doi: 10.1021/acs.inorgchem.8b00586
4. [4]
  Lv, H. T.; Cui, Y.; Zou, G. D.; Li, N.; Yang, P.; Fan, Y. Synthesis of titanium-oxo macrocyles and their catalytic properties for oxidative desulfurization. Dalton Trans. 2019, 48, 14044–14048. doi: 10.1039/C9DT03057C
5. [5]
  Fan, X.; Fu, H.; Gao, M. Y.; Zhang, L.; Zhang, J. One-pot and postsynthetic phenol-thermal synthesis toward highly stable titanium-oxo clusters. Inorg. Chem. 2019, 58, 13353−13359. doi: 10.1021/acs.inorgchem.9b02238
6. [6]
  Zhu, B. C.; Hong, Q. L.; Yi, X.; Zhang, J.; Zhang, L. Supramolecular co-assembly of the Ti₈L₁₂ cube with [Ti(DMF)₆] species and Ti₁₂-oxo cluster. Inorg. Chem. 2020, 59, 8291−8297. doi: 10.1021/acs.inorgchem.0c00682
7. [7]
  Wu, Y. Y.; Luo, W.; Wang, Y. H.; Pu, Y. Y.; Zhang, X.; You, L. S.; Zhu, Q. Y.; Dai, J. Titanium-oxo-clusters with dicarboxylates: single-crystal structure and photochromic effect. Inorg. Chem. 2012, 51, 8982−8988. doi: 10.1021/ic301092b
8. [8]
  Huang, Y.; Zou, G. D.; Li, H. M.; Cui, Y.; Fan, Y. A photoactive {Ti₁₆} metal-organic capsule: structural, photoelectrochemical and photocatalytic properties. New J. Chem. 2018, 42, 14079−14082. doi: 10.1039/C8NJ02992J
9. [9]
  Gao, M. Y.; Wang, F.; Gu, Z. G.; Zhang, D. X.; Zhang, L.; Zhang, J. Fullerene-like polyoxotitanium cage with high solution stability. J. Am. Chem. Soc. 2016, 138, 2556−2559. doi: 10.1021/jacs.6b00613
10. [10]
  Fang, W. H.; Zhang, L.; Zhang, J. A 3.6 nm Ti₅₂-oxo nanocluster with precise atomic structure. J. Am. Chem. Soc. 2016, 138, 7480−7483. doi: 10.1021/jacs.6b03489
11. [11]
  Fang, W. H.; Zhang, L.; Zhang, J. Synthetic strategies, diverse structures and tunable properties of polyoxo-titanium clusters. Chem. Soc. Rev. 2018, 47, 404−421. doi: 10.1039/C7CS00511C
12. [12]
  Liu, Y. J.; Fang, W. H.; Zhang, L.; Zhang, J. Recent advances in heterometallic polyoxotitanium clusters. Coord. Chem. Rev. 2020, 404, 213099. doi: 10.1016/j.ccr.2019.213099
13. [13]
  Wang, C.; Liu, C.; Li, L. J.; Sun, Z. M. Synthesis, crystal structures, and photochemical properties of a family of heterometallic titanium oxo clusters. Inorg. Chem. 2019, 58, 6312−6319. doi: 10.1021/acs.inorgchem.9b00508
14. [14]
  Fu, H.; Lin, Q.; Wang, F.; Zhang, J. Construction of titanium-based metal-organic frameworks based on the Ti/Cu heteronuclear cluster. Inorg. Chem. 2021, 60, 24−27. doi: 10.1021/acs.inorgchem.0c03257
15. [15]
  Yu, Y. Z.; Guo, Y.; Zhang, Y. R.; Liu, M. M.; Feng, Y. R.; Geng, C. H.; Zhang, X. M. A series of silver doped butterfly-like Ti₈Ag₂ clusters with two Ag ions paneled on a Ti₈ surface. Dalton Trans. 2019, 48, 13423–13429. doi: 10.1039/C9DT02508A
16. [16]
  Fan, X.; Narayanam, N.; Gao, M.; Zhang, L.; Zhang, J. Ligand dependent assembly of trinuclear titanium-oxo units into coordination tetrahedral and capsules. Dalton Trans. 2018, 47, 663–665. doi: 10.1039/C7DT04204C
17. [17]
  Fang, W. H.; Wang, J. F.; Zhang, L.; Zhang, J. Titanium-oxo cluster based precise assembly for multidimensional materials. Chem. Mater. 2017, 29, 2681−2684. doi: 10.1021/acs.chemmater.7b00324
18. [18]
  Chen, Y.; Trzop, E.; Makal, A.; Chen, Y. S.; Coppens, P. A novel manganese-doped large polyoxotitanate nanocluster. Dalton Trans. 2014, 43, 3839–3841. doi: 10.1039/C3DT53416B
19. [19]
  Hou, S. M.; Li, Q. H.; Ding, Q. R.; Kang, Y.; Zhang, J.; Zhang, L. Heterometallic Ag₂Ti₁₀ and Ag₄Ti₈-oxo clusters with different silver doping models: synthesis, structure, and theoretical studies. Dalton Trans. 2020, 49, 11005–11009. doi: 10.1039/D0DT02396E
20. [20]
  Li, N.; Matthews, P. D.; Leung, J. J.; King, T. C.; Wood, P. T.; Luo, H. K.; Wright, D. S. Synthesis, structure and properties of the manganese-doped polyoxotitanate cage [Ti₁₈MnO₃₀(OEt)₂₀(MnPhen)₃] (Phen = 1, 10-phenanthroline). Dalton Trans. 2015, 44, 19090–19096. doi: 10.1039/C5DT03617H
21. [21]
  Zheng, H.; Deng, Y. K.; Ye, M. Y.; Xu, Q. F.; Kong, X. J.; Long, L. S.; Zheng, L. S. Lanthanide-titanium oxo clusters as the luminescence sensor for nitrobenzene detection. Inorg. Chem. 2020, 59, 12404−12409. doi: 10.1021/acs.inorgchem.0c01494
22. [22]
  Chen, Z. B.; Chen, B. B.; Cheng, J. W. Luminescent lanthanide-titanium-organic compound constructed by tetra-nuclear Ln-Ti building units and diphenylglycolic acid. Chin. J. Struct. Chem. 2021, 40, 182−186.
23. [23]
  (a) Sheldrick, G. M. SHELXS97, Program for Crystal Structure Solution. University of Göttingen, Göttingen, Germany 1997; (b) Sheldrick, G. M. SHELXL97, Program for Crystal Structure Refinement. University of Göttingen, Göttingen, Germany 1997. (24) Crystal data for 1: monoclinic, P2₁/c, a = 20.0807(3), b = 19.0807(3), c = 26.9589(5) Å, β = 93.6970(10)^o, V = 10307.9(3) Å³, Z = 4, μ = 1.422 mm⁻¹, S = 1.096. The final least-squares refinements converged at R₁ (wR₂) = 0.0586 (0.1905) and for 18965 reflections with I > 2σ(I).
24. [24]
  Crystal data for 1: monoclinic, P2₁/c, a = 20.0807(3), b = 19.0807(3), c = 26.9589(5) Å, β = 93.6970(10)^o, V = 10307.9(3) Å³, Z = 4, μ = 1.422 mm⁻¹, S = 1.096. The final least-squares refinements converged at R₁ (wR₂) = 0.0586 (0.1905) and for 18965 reflections with I > 2σ(I).
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