Citation: Yong-Lan FENG, Wu-Jiu JIANG, Fu-Xing ZHANG, Dai-Zhi KUANG. Synthesis, Structural Characterization, Fluorescence Properties and Herbicidal Activity of Bis(substituted salicylaldehyde) Carbohydrazide Dibutyltin Complexes[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1639-1646. doi: 10.14102/j.cnki.0254-5861.2011-3214 shu

Synthesis, Structural Characterization, Fluorescence Properties and Herbicidal Activity of Bis(substituted salicylaldehyde) Carbohydrazide Dibutyltin Complexes

Key Laboratory of Functional Metal-organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: Dai-Zhi KUANG, hnkcq@qq.com
Received Date: 10 April 2021
Accepted Date: 19 August 2021

Fund Project: the Innovation Platform Open Foundation for Colleges and Universities of Hunan Province 16k011

Figures(2)

A series of dibutyltin complexes, (Bu₂Sn)₂L, [(Bu₂Sn)₂L]₃ and H₂LSnBu₂, were synthesized by microwave-assisted methanolic solvothermal method, where H₄L is [2-(OH)-R-ArCH=NNH]₂CX, and X = O, R = 4-NEt₂ (T1), 5-Br (T2); X = S, R = H (T3); R = 5-Br (T4). Their structures were characterized by elemental analysis, IR and (¹H, ¹³C)-NMR spectra. The molecular structure of T2 was confirmed by X-ray diffraction. The crystal of T2 belongs to monoclinic system, space group Ia. Five-coordinated distorted triangular bipyramids and six-coordinated distorted octahedral configurations were formed by the coordination of oxygen and nitrogen atoms of ligand with two dibutyltins, thus forming a trimeric hexanuclear butyltin complex by the cross coordination of three units (Bu₂Sn)₂L with enol imines. The T2 and T4 exhibit fluorescence emission in DMF solvents and DMF-water mixture. The fluorescence intensity of T2-DMF-H₂O system decreases almost linearly with the increase of water volume fraction (WVF). The aggregation fluorescence enhancement effect of T4-DMF-H₂O solution system increases with the increase of WVF at the range of 0~20% WVF. When WVF is more than 20%, the fluorescence intensity decreases with the increase of WVF. In addition, T1~T4 have broad growth activities on target plants, such as Portulaca oleracea L., Amaranthus spinosus L., Cassia tora L., Brassica campestris L.ssp.chinensis var.utilis Tsen et Lee, and Amaranthus tricolor L., and can be used as a candidate herbicide for further research.
- bis(substituted salicylaldehyde) carbohydrazide dibutyltin,
- fluorescence properties,
- herbicidal activity
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