Citation: Hao GU, Shan-Ci CHEN, Qing-Dong ZHENG. Long-term Stable 2D Dion-Jacobson Phase Perovskite Photodiode with Low Dark Current and High On/off Ratio[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1621-1630. doi: 10.14102/j.cnki.0254-5861.2011-3200 shu

Long-term Stable 2D Dion-Jacobson Phase Perovskite Photodiode with Low Dark Current and High On/off Ratio

Hao GU ^{a, b} ,
Shan-Ci CHEN ^b,, ,
Qing-Dong ZHENG ^b,,

a.
College of Chemistry, Fuzhou University, Fuzhou 350000, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Shan-Ci CHEN, Qing-Dong ZHENG,
Received Date: 31 March 2021
Accepted Date: 26 May 2021

Fund Project: the National Natural Science Foundation of China U1605241the Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China 2021ZR116the Natural Science Foundation of Fujian Province for Distinguished Young Scholars 2019J06023

Figures(7)

A two-dimensional (2D) organic-inorganic hybrid perovskite (OIHP) material is considered as a promising candidate for a long-term stable photodetector owing to its outstanding phase and environmental stability. Herein, we demonstrate a perovskite photodiode based on the DJ phase 2D perovskite (PDA)(MA)_n-1Pb_nI_3n+1 (where PDA is 1, 3-propylenediamine, MA is methylamine, nominal n = 4). The best-performance device exhibits a high detectivity of 4.57 × 10¹¹ Jones, a responsivity of 0.25 A⋅W⁻¹ at 480 nm, a low dark current density of 9.60 × 10⁻⁴ mA⋅cm⁻², and a remarkable on/off ratio of 3.10 × 10⁵. The unencapsulated device can maintain 95% of the initial photocurrent density after 90 days under an ambient atmosphere with relative humidity (RH) of 65%, demonstrating its improved stability than the 3D counterpart. The excellent stability of the photodiode based on 2D perovskite promises its bright commercial application future.
- two-dimensional perovskite,
- Dion-Jacobson,
- photodiode,
- on/off ratio,
- stability
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