Citation: Min CHENG, Jian-Ce JIN, Jian-Rong LI, Zhi-Zhuan ZHANG, Liao-Kuo GONG, Xiao-Ying HUANG. Two Manganese Halide Hybrids Based on 1-Butyl-2, 3-dimethylimidazolium: Synthesis, Crystal Structure and Photoluminescence[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 857-864. doi: 10.14102/j.cnki.0254-5861.2011-3089 shu

Two Manganese Halide Hybrids Based on 1-Butyl-2, 3-dimethylimidazolium: Synthesis, Crystal Structure and Photoluminescence

Min CHENG ^{a, b} ,
Jian-Ce JIN ^b ,
Jian-Rong LI ^b ,
Zhi-Zhuan ZHANG ^{a, b} ,
Liao-Kuo GONG ^b,, ,
Xiao-Ying HUANG ^b,,

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Liao-Kuo GONG, lkgong@fjirsm.ac.cn Xiao-Ying HUANG, xyhuang@fjirsm.ac.cn
Received Date: 6 January 2021
Accepted Date: 21 February 2021

Fund Project: the National Natural Science Foundation of China 21671187the Natural Science Foundation of Fujian Province 2020J01118

Figures(7)

Two new inorganic-organic hybrid manganese(Ⅱ) halide crystals, namely [BMMIm]₂[MnCl₄] (1, BMMIm = 1-butyl-2, 3-dimethylimidazolium) and [BMMIm]₂[MnBr₄] (2), have been obtained simply by heating/stirring with nearly 100% yield. Single-crystal X-ray diffraction (SCXRD) study reveals that 1 crystallizes in triclinic space group of P\begin{document}$ \overline 1 $\end{document} with a = 10.0176(7), b = 14.9603(11), c = 12.9086(8) Å, α = 91.060(4)°, β = 110.204(5)°, γ = 92.361(4)°, V = 1235.19(12) Å³, Z = 2, D_c = 1.353 g·cm^-3, F(000) = 526, μ = 0.978 mm^-1, R = 0.0410 and wR = 0.0690 (I > 2σ(I)) and M_r = 503.23; 2 belongs to orthorhombic space group of P2₁2₁2₁ with a = 10.0176(7), b = 14.9603(11), c = 17.4450(14) Å, V = 2614.4(3) Å³, Z = 4, D_c = 1.730 g·cm^-3, F(000) = 1340, μ = 6.629 mm^-1, R = 0.0440 and wR = 0.0520 (I > 2σ(I)) and M_r = 681.07. The ionic compounds 1 and 2 are composed of mononuclear tetrahedral [MnX₄]^2- anion and two ionic liquid cations of [BMMIm]⁺. The photoluminescence (PL) of 1 and 2 was characterized and the influence of halogen atom types on PL was investigated.
- manganese halide,
- ionic liquid,
- organic-inorganic hybrid,
- crystal structure,
- luminescence property
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