Citation: Lao-Bang WANG, Ji-Jiang WANG, Long TANG, Xiao WANG, Xiang-Yang HOU, Er-Lin YUE, Yu-Qi ZHANG. Two Co(Ⅱ) Complexes Constructed from 1-(3, 5-Dicarboxybenzyl)-3, 5-pyrazole Dicarboxylic Acid: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 885-891. doi: 10.14102/j.cnki.0254-5861.2011-3071 shu

Two Co(Ⅱ) Complexes Constructed from 1-(3, 5-Dicarboxybenzyl)-3, 5-pyrazole Dicarboxylic Acid: Syntheses, Structures and Magnetic Properties

Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000, China

Corresponding author: Ji-Jiang WANG, yadxwjj@126.com Long TANG, ydtanglong@163.com
Received Date: 17 December 2020
Accepted Date: 10 March 2021

Fund Project: the National Natural Science Foundation of China 21373178

Figures(7)

Two new complexes [Co₂(L)(4, 4´-bip)(H₂O)₃]_n (1) and {[Co(L´)₂(phen)]·2H₂O)}_n (2) (H₄L = 1-(3, 5-dicarboxybenzyl)-3, 5-pyrazole dicarboxylic acid, H₃L´ = 1-(3, 5-dicarboxybenzyl)-3-pyrazole carboxylic acid, 4, 4´-bip = 4, 4´-bis(1-imidazolyl)biphenyl, phen = 1, 10-phenanthroline) were synthesized. Complexes 1 and 2 have been characterized by IR spectrography, X-ray single-crystal diffraction, elemental analysis and thermogravimetry. 1 crystallizes in monoclinic system, space group P2₁/c. Complex 2 crystallizes in monoclinic system, space group I2/a. It is remarkable that in situ hydrothermal decarboxylation was observed during preparing complex 2. In addition, magnetic analysis indicates that antiferromagnetic interaction exists among Co(Ⅱ) ions in complexes 1 and 2.
- Co(Ⅱ),
- 1-(3, 5-dicarboxybenzyl)-3, 5-pyrazole dicarboxylic acid,
- magnetic properties
1. [1]
  Rouffet, M.; de Oliveira, C. A. F.; Udi, Y.; Agrawal, A.; Sagi, I.; McCammon, J. A.; Cohen, S. M. From sensors to silencers: quinoline- and benzimidazole-sulfonamides as inhibitors for zinc proteases. J. Am. Chem. Soc. 2010, 132, 8232–8233. doi: 10.1021/ja101088j
2. [2]
  Liu, H. Y.; Wu, H.; Ma, J. F.; Liu, Y. Y.; Liu, B.; Yang, J. Syntheses, structures, and photoluminescence of zinc(Ⅱ) coordination polymers based on carboxylates and flexible bis-[(pyridyl)-benzimidazole] ligands. Cryst. Growth Des. 2010, 10, 4795–4805. doi: 10.1021/cg100688z
3. [3]
  Xue, F.; Kumar, P.; Xu, W. Q.; Mkhoyan, K. A.; Tsapatsis, M. Direct synthesis of 7 nm-thick zinc(Ⅱ)-benzimidazole-acetate metal-organic framework nanosheets. Chem. Mater. 2018, 30, 69–73. doi: 10.1021/acs.chemmater.7b04083
4. [4]
  Yang, F.; Xu, G.; Dou, Y. B.; Wang, B.; Zhang, H.; Wu, H.; Zhou, W.; Li, J. R.; Chen, B. L. A flexible metal-organic framework with a high density of sulfonic acid sites for proton conduction. Nat. Energy 2017, 2, 877−883. doi: 10.1038/s41560-017-0018-7
5. [5]
  Wang, Y. L.; Han, C. B.; Zhang, Y. Q.; Liu, Q. Y.; Liu, C. M.; Yin, S. G. Fine-tuning ligand to modulate the magnetic anisotropy in a carboxylate-bridged Dy2 single-molecule magnets system. Inorg. Chem. 2016, 55, 5578–5584. doi: 10.1021/acs.inorgchem.6b00653
6. [6]
  Horike, S.; Umeyama, D.; Kitagawa, S. Ion conductivity and transport by porous coordination polymers and metal-organic frameworks. \ Chem. Res. 2013, 46, 2376–2384. doi: 10.1021/ar300291s
7. [7]
  Zhao, M.; Ou, S.; Wu, C. D. Porous metal-organic frameworks for heterogeneous biomimetic catalysis. Chem. Res. 2014, 47, 1199–1207. doi: 10.1021/ar400265x
8. [8]
  Kitagawa, S.; Kitaura, R.; Noro, R. Functional porous coordination polymers. Angew. Chem. Int. Ed. 2004, 43, 2334–2375. doi: 10.1002/anie.200300610
9. [9]
  He, Y. B.; Zhou, W.; Qian, G. D.; Chen, B. L. Methane storage in metal-organic frameworks. Chem. Soc. Rev. 2014, 43, 5657−5678. doi: 10.1039/C4CS00032C
10. [10]
  Lustig, W. P.; Mukherjee, S.; Rudd, N. D.; Desai, A. V.; Li, J.; Ghosh, S. K. Metal-organic frameworks: functional luminescent and photonic materials for sensing applications. Chem. Soc. Rev. 2017, 46, 3242–3285. doi: 10.1039/C6CS00930A
11. [11]
  Lin, Z. T.; Wang, Y. L.; Liu, Q. Y. Crystal structure and luminescence of a Cd(Ⅱ) complex based on the 3, 3΄, 5, 5΄-tetrafluorobiphenyl-4, 4΄-dicarboxylate and adenine ligands. Chin. J. Struct. Chem. 2020, 11, 2041−2045.
12. [12]
  Zhang, N.; Guo, Y. H.; Yu, Y. Z.; Wang, Z.; Niu, Y. S.; Wu, X. L. Solvothermal synthesis, crystal Structure and luminescence property of a 1D silver(Ⅰ) coordination polymer. Chin. J. Struct. Chem. 2020, 11, 2009−2015.
13. [13]
  Verma, P.; Singh, U. P.; Butcher, R. Luminescent metal organic frameworks for sensing and gas adsorption studies. CrystEngComm. 2019, 21, 5470–5481. doi: 10.1039/C9CE00732F
14. [14]
  Wang, J. J.; Cao, Z.; Wang, X.; Tang, L.; Hou, X. Y.; Ju, P.; Ren, Y. X.; Chen, X. L.; Zhang, Y. Q. A novel 3D Cd(Ⅱ) coordination polymer generated via in situ ligand synthesis involving C–O esterbond formation. RSC Adv. 2019, 9, 307–312 doi: 10.1039/C8RA06112B
15. [15]
  Liu, C. B.; Li, Q.; Wang, X.; Che, G. B.; Zhang, X. J. A series of lanthanide(Ⅲ) coordination polymers derived via in situ hydrothermal decarboxylation of quinoline-2, 3-dicarboxylic acid. Inorg. Chem. Commun. 2014, 39, 56–60. doi: 10.1016/j.inoche.2013.10.050
16. [16]
  Yang, A. H.; Zou, J. Y.; Wang, W. M.; Shi, X. Y.; Gao, H. L.; Cui, J. Z.; Zhao, B. Two three-dimensional lanthanide frameworks exhibiting luminescence increases upon dehydration and novel water layer involving in situ decarboxylation. Inorg. Chem. 2014, 53, 7092–7100. doi: 10.1021/ic402803s
17. [17]
  Sheldrick, G. M. SHELXS-2014/7 and SHELXL-2014/7 program for solution and refinement of crystal structures. Institute for Inorganic Chemistry. University of Göttingen, Göttingen, Germany 2014.
18. [18]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Cryst. 2015, C71, 3–8.
19. [19]
  Ishida, T.; Kawakami, T.; Mitsubori, S.; Nogami, T.; Yamaguchi, K.; Iwamura, H. Antiferromagnetic coupling of transition metal spins across pyrimidine and pyrazine bridges in dinuclear manganese(Ⅱ), cobalt(Ⅱ), nickel(Ⅱ) and copper(Ⅱ) 1, 1, 1, 5, 5, 5-hexafluoropentane-2, 4-dionate complexes. J. Chem. Soc. Dalton Trans. 2002, 3177–3186.
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