Citation: Wei LI, Chang-Hong LI, Yu-Lin LI, Yun-Fei KUANG. Solvothermal Synthesis, Crystal Structure and Characterization of a New Binuclear Nickel(Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 878-884. doi: 10.14102/j.cnki.0254-5861.2011-3070 shu

Solvothermal Synthesis, Crystal Structure and Characterization of a New Binuclear Nickel(Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid

Wei LI ^a,, ,
Chang-Hong LI ^b,, ,
Yu-Lin LI ^a ,
Yun-Fei KUANG ^a

a.
School of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
b.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Corresponding author: Wei LI, li_weihnxy@163.com Chang-Hong LI, lichanghong4444@126.com
Received Date: 16 December 2020
Accepted Date: 5 January 2021

Fund Project: Natural Science Foundation of Hunan Province 2019JJ60021Industry and Research Key Project of Hengyang City 2019jhzx1093

Figures(7)

A new binuclear nickel(Ⅱ) complex [Ni₂(MBBA)₂(HPT)₂(H₂O)₂]·2H₂O (1) was synthesized with nickel hydroxide, 2-(4-methylbenzoyl)benzoic acid (HMBBA) and 3-(pyridin-2-yl)-1H-1, 2, 4-triazole (HPT). It crystallizes in the monoclinic space group P2₁/n with a = 14.5902(13), b = 8.8191(6), c = 17.6120(14) Å, β = 110.830(9)º, V = 2118.0(3) Å³, M_r = 958.26, D_c = 1.503 g/cm³, Z = 2, μ(MoKa) = 0.959, F(000) = 992, the final GOOF = 1.001, R = 0.0353 and wR = 0.09864. Each central Ni(Ⅱ) ion is coordinated by two oxygen and three nitrogen atoms, forming a distorted square pyramidal geometry. The XRD, TG, spectrum analysis and magnetic properties of 1 were studied.
- binuclear nickel(Ⅱ) complex,
- spectrum analysis,
- thermal stability,
- magnetic property
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