Citation: Ming-Yue BI, Yi-Hang WEN, Hai-Xia ZHANG, Jian ZHANG. Syntheses, Crystal Structures and Properties of Two New Zn Based Boron Imidazolate Frameworks[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 865-870. doi: 10.14102/j.cnki.0254-5861.2011-3068 shu

Syntheses, Crystal Structures and Properties of Two New Zn Based Boron Imidazolate Frameworks

Ming-Yue BI ^{a, b} ,
Yi-Hang WEN ^a,, ,
Hai-Xia ZHANG ^b ,
Jian ZHANG ^b

a.
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Yi-Hang WEN, wyh@zjnu.cn
Received Date: 13 December 2020
Accepted Date: 21 February 2021

Fund Project: the National Key Research and Development Program of China 2018YFA0208600

Figures(6)

Two new boron imidazolate frameworks (BIFs), Zn₂[HBH(2-mim)₃]₂(1, 2-PEA)₂(EG)₂ (BIF-120, EG = ethylene glycol) and Zn[BH(2-mim)₃](1, 2-HPEA) (BIF-121), were successfully synthesized by mixing the KBH(2-mim)₃ ligand and the semirigid aromatic dicarboxylate ligand 1, 2-benzenediacetic acid (1, 2-H₂PEA) under solvothermal conditions. In this paper, the two samples were structurally characterized by single-crystal X-ray diffraction and tested by infrared spectroscopy (IR), UV-visible spectroscopy (UV-Vis), thermogravimetric analysis TGA and X-ray powder diffractions. In addition, the solid-state luminescent properties of these crystals were also investigated.
- boron imidazolate frameworks,
- crystal structure,
- X-ray crystallography,
- luminescent
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