Citation: Qiang-Qiang JIA, Min WAN, Liang TONG, Zheng XING, Guo-Xi WANG, Li-Zhuang CHEN. Syntheses, Crystal Structures and Properties of Two Coordination Polymers Based on Bisbenzimidazole[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 871-877. doi: 10.14102/j.cnki.0254-5861.2011-3060 shu

Syntheses, Crystal Structures and Properties of Two Coordination Polymers Based on Bisbenzimidazole

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Li-Zhuang CHEN, clz1977@sina.com
Received Date: 10 December 2020
Accepted Date: 12 March 2021

Fund Project: the National Natural Science Foundation of China NSFC21671084

Figures(8)

Two novel coordination polymers Bim(C=O)CuI]₂ (1) and [Bim(C=O)CdCl₂]₂ (2) based on the flexible ligand bis(1H-benzo[d]imidazol-2-yl)methane (Bim) were synthesized via volatilization method. They crystalize in monoclinic and triclinic crystal systems and adopt space group of P2₁/c and P\begin{document}$ \overline 1 $\end{document}, respectively. The compounds were characterized by elemental analysis, infrared spectroscopy and powder X-ray diffraction analysis. Interestingly, methylene (-CH₂-) in Bim was oxidized to carbonyl (C=O), which increases its extra-cyclic conjugation effect. For 1 and 2, their maximum emission wavelength of fluorescence around 440 and 475 nm indicates the potential as promising light-emissive materials. Meaningfully, Co²⁺ ion shows a quenching effect on the fluorescence of compound 1. Besides, both compounds possess remarkable structure stability.
- bisbenzimidazole ligand,
- crystal structure,
- fluorescence,
- methylene,
- carbonyl
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