Citation: Chong ZHAO, Wang-Gui YE, Ying-Kui LI, Xiao-Fei SHEN, Zhi-Jun CAO, Zhi-Quan CAO, Zi-Cheng WEN, Xuan-Yi YUAN, Chao-Yang MA, Yong-Ge CAO. Electromagnetic Properties of YIG Polycrystalline Ceramics Fabricated by Tape-casting Method[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 892-900. doi: 10.14102/j.cnki.0254-5861.2011-3034 shu

Electromagnetic Properties of YIG Polycrystalline Ceramics Fabricated by Tape-casting Method

Chong ZHAO ^a ,
Wang-Gui YE ^a ,
Ying-Kui LI ^b ,
Xiao-Fei SHEN ^b ,
Zhi-Jun CAO ^c ,
Zhi-Quan CAO ^d ,
Zi-Cheng WEN ^{b, e} ,
Xuan-Yi YUAN ^a ,
Chao-Yang MA ^b,, ,
Yong-Ge CAO ^{b, e,,}

a.
Department of Physics, Renmin University of China, Beijing 100872, China
b.
Songshan Lake Materials Laboratory, Dongguan 523808, China
c.
University of Virginia, Charlottesville, VA 22904, USA
d.
New York University, New York, NY 10003, USA
e.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Chao-Yang MA, machaoyang@sslab.org.cn Yong-Ge CAO, caoyongge@sslab.org.cn
Received Date: 9 November 2020
Accepted Date: 27 January 2021

Fund Project: the National Key R & D Program of China 2017YFB0403200the National Natural Science Foundation of China 51872327

Figures(7)

Pure phase Y₃Fe₅O₁₂ (YIG) ceramic was successfully produced by tape-casting forming process and one-step solid-state sintering method. The activation energy for densification was calculated to be 183.81 kJ/mol. Pure YIG ceramic with a relative density as high as 99.8% was fabricated. The existence of O vacancy and Fe²⁺ ions was determined by XPS and EPR spectra. The RT saturation magnetization was measured to be 28.2 emu/g, and the hysteresis loss was calculated to be smaller than 10 mJ/kg in the temperature range of 230~360 K and be as high as 238.8 mJ/kg at 30 K. The dielectric loss tangent tan\begin{document}$ {\delta }_{\varepsilon } $\end{document} was nearly zero at 6~7 GHz and 11~12 GHz. For complex permeability in the frequency range of 5~18 GHz, the magnetic loss tangent tan\begin{document}$ {\delta }_{\mu } $\end{document} fluctuated at around zero. Therefore, the low values of tan\begin{document}$ {\delta }_{\varepsilon } $\end{document} and tan\begin{document}$ {\delta }_{\mu } $\end{document} indicate that it is a low loss ceramic material.
- YIG ceramic,
- tape-casting,
- microwave,
- hysteresis loss,
- magnetodielectric ceramic
1. [1]
  Badahur, D. Current trends in applications of magnetic ceramic materials. B. Mater. Sci. 1992, 15, 431−439. doi: 10.1007/BF02745292
2. [2]
  Adam, J. D.; Davis, L. E.; Dionne, G. F.; Schloemann, E. F.; Stitzer, S. N. Ferrite devices and materials. IEEE T. Microw. Theory 2002, 50, 721−737. doi: 10.1109/22.989957
3. [3]
  Nan, C.; Bichurin, M. I.; Dong, S.; Viehland, D.; Srinivasan, G. Multiferroic magnetoelectric composites: historical perspective, status and future directions. J. App. Phys. 2008, 103, 031101−35. doi: 10.1063/1.2836410
4. [4]
  Huang, M.; Zhang, S. Y. Growth and characterization of rare-earth iron garnet single crystals modified by bismuth and ytterbium substituted for yttrium. J. Mater. Chem. Phys. 2002, 73, 314−317. doi: 10.1016/S0254-0584(01)00365-0
5. [5]
  Huang, M.; Xu, Z. C. Liquid phase epitaxy growth of bismuth-substituted yttrium iron garnet thin films for magneto-optical applications. Thin Solid Films 2004, 450, 324−328. doi: 10.1016/j.tsf.2003.11.190
6. [6]
  Deschanvres, J. L.; Langlet, M.; Bochu, B.; Joubert, J. C. Growth of Bi-substituted YIG thin films for magneto-optic applications. J. Magn. Magn. Mater. 1991, 101, 224−226. doi: 10.1016/0304-8853(91)90737-U
7. [7]
  Kimzuka, N.; Katsura, T. Standard free energy of formation of YFeO₃, Y₃Fe₅O₁₂ and a new compound YFe₂O₄ in the Fe₂O₃-Y₂O₃ system at 1200 ℃. J. Solid State Chem. 1975, 13, 176−181. doi: 10.1016/0022-4596(75)90116-4
8. [8]
  Sánchez-De Jesús, F.; Cortés, C. A.; Valenzuela, R.; Ammar, S.; Bolarín-Miró, A. M.; Bolarin-Miro, M. Synthesis of Y₃Fe₅O₁₂ (YIG) assisted by high-energy ball milling. Ceram. Int. 2012, 38, 5257−5263. doi: 10.1016/j.ceramint.2012.03.036
9. [9]
  Ali, W. F. F. W.; Othman, M.; Ain, M. F.; Abdullah, N. S.; Ahmad, Z. A. The investigation of the phenomenological YIG phase formation within 1000 ℃ to 1250 ℃: a kinetic approach. J. Am. Ceram. Soc. 2015, 99, 315−323.
10. [10]
  Buscaglia, V.; Caracciolo, F.; Bottino, C.; Leoni, M.; Nanni, P. Reaction diffusion in the Fe₂O₃-Y₂O₃ system. Acta Mater. 1997, 45, 1213−1224. doi: 10.1016/S1359-6454(96)00246-7
11. [11]
  Sztaniszláv, A.; Sterk, E.; Fetter, L.; Farkas-Jahnke, M.; Lábár, J. Investigation of garnet formation by sintering of Y₂O₃ and Fe₂O₃. J. Magn. Magn. Mater. 1984, 41, 75−78. doi: 10.1016/0304-8853(84)90141-0
12. [12]
  Ali, W. F. F. W.; Othman, M.; Ain, M. F.; Abdullah, N. S.; Ahmad, Z. A. The behavior of high frequency tunable dielectric resonator antenna (DRA) with the addition of excess Fe₂O₃ in Y₃Fe₅O₁₂ (YIG) formulation. J. Mater. Sci-Mater. El. 2014, 25, 560−572. doi: 10.1007/s10854-013-1624-1
13. [13]
  Ali, W. F. F. W.; Othman, M.; Ain, M. F.; Abdullah, N. S.; Ahmad, Z. A. Studies on the formation of yttrium iron garnet (YIG) through stoichiometry modification prepared by conventional solid-state method. J. Eur. Ceram. Soc. 2013, 33, 1317−1324. doi: 10.1016/j.jeurceramsoc.2012.12.016
14. [14]
  Li, X.; Zhou, J.; Deng, J.; Zheng, H.; Zheng, L.; Zheng, P.; Qin, H. Synthesis of dense, fine-grained YIG ceramic by two-step sintering. J. Electron. Mater. 2016, 45, 4973−4978. doi: 10.1007/s11664-016-4690-3
15. [15]
  Chen, F.; Li, Q.; Wang, X.; Ouyang, J.; Nie, Y.; Feng, Z.; Gong, R.; Chen, Y.; Harris, V. G. Crystal structure tailored microwave magnetodielectric in Yb_xY_3-xFe₅O₁₂ ceramic. J. Alloy. Compd. 2017, 726, 1030−1039. doi: 10.1016/j.jallcom.2017.08.040
16. [16]
  Lide, D. R. Vapor Pressure of the Metallic Elements. CRC Handbook of Chemistry and Physics. 84th Edition, online version. CRC Press. Boca Raton, Florida 2003, p309−313
17. [17]
  Ali, W. F. F. W.; Othman, M.; Ain, M. F.; Abdullah, N. S.; Ahmad, Z. A. Sintering and grain growth control of high dense YIG. Ceram. Int. 2016, 42, 13996−14005. doi: 10.1016/j.ceramint.2016.06.004
18. [18]
  Fechine, P. B. A.; Silva, E. N.; Menezes, A. S.; Derov, J.; Stewart, J. W.; Drehman, A. J.; Vasconcelos, I. F.; Ayala, A. P.; Cardoso, L. P.; Sombra, A. S. B. Synthesis, structure and vibrational properties of GdIG_x: YIG_1-x ferrimagnetic ceramic composite. J. Phys. Chem. Sol. 2009, 70, 202−209. doi: 10.1016/j.jpcs.2008.10.008
19. [19]
  Wu, H.; Liu, J.; Liang, H.; Zang, D. Sandwich-like Fe₃O₄/Fe₃S₄ composites for electromagnetic wave absorption. Chem. Eng. J. 2020, 393, 124743-1−13.
20. [20]
  Zou, J.; Wang, Z.; Yan, M.; Bi, H. Enhanced interfacial polarization relaxation effect on microwave absorption properties of submicron-sized hollow Fe₃O₄ hemispheres. J. Phys. D: Appl. Phys. 2014, 47, 275001−9. doi: 10.1088/0022-3727/47/27/275001
21. [21]
  Lan, D.; Qin, M.; Yang, R.; Chen, S.; Wu, H.; Fan, Y.; Fu, Q.; Zhang, F. Facile synthesis of hierarchical chrysanthemum-like copper cobaltate-copper oxide composites for enhanced microwave absorption performance. J. Colloid Interface Sci. 2019, 533, 481−491. doi: 10.1016/j.jcis.2018.08.108
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