Citation: Hong-Hui TAN, Xiao-Long LV, Jiang-Long LIU, Yu-Fang CHENG, Qing-Lin ZHOU, Yi-Ting LIN, Wei MENG. A 2D Layer Copper(Ⅱ) Coordination Polymer with 3-Nitrophthalic Acid: Synthesis, Crystal Structure and Copper 3-Nitrophthalate Metal-organic Framework-graphene Oxide Nanocomposite[J]. Chinese Journal of Structural Chemistry, ;2021, 40(4): 459-464. doi: 10.14102/j.cnki.0254-5861.2011-2970 shu

A 2D Layer Copper(Ⅱ) Coordination Polymer with 3-Nitrophthalic Acid: Synthesis, Crystal Structure and Copper 3-Nitrophthalate Metal-organic Framework-graphene Oxide Nanocomposite

Department of Materials & Chemistry Engineering, Hunan City University, Yiyang 413000, China

Corresponding author: Wei MENG, mengw198503@163.com
Received Date: 28 August 2020
Accepted Date: 29 September 2020

Fund Project: the National Natural Science Foundation of China 22001064the Natural Science Foundation of Hunan Province 2020JJ4155the 2020 Hunan Province College Students' Innovation Entrepreneurship Training Program 3373the Scientific Research Project of Hunan Province Department of Education 20B105

Figures(4)

A 2D layer Cu(Ⅱ) coordination polymer [Cu(npth)(H₂O)]_n (1) was crystallized from a mixture of 3-nitrophthalic acid and Cu(OAc)₂·H₂O in water under room temperature and structurally characterized by single-crystal X-ray diffraction, FT-IR and TGA. Compound 1 was applied to make a nanocomposite with graphene oxide (GO). A highly dispersible and stable nanocomposite of Cu(npth)-GO was successfully synthesized by a simple ultrasonication method. SEM, TEM, UV-vis, FT-IR and TGA were used to characterize the morphology and structure of the prepared composite. In accordance with the characterization results, we suspected that the binding mechanism of Cu(npth) and GO was assigned to be the cooperative interaction of Cu–O coordination, π-π stacking and hydrogen bonding.
- copper 3-nitrophthalate metal-organic framework,
- crystal structure,
- graphene oxide,
- nanocomposite
1. [1]
  Liu, X.; Wang, X.; Kapteijn, F. Water and metal-organic frameworks: from interaction toward utilization. Chem. Rev. 2020, 10.1021/acs. chemrev. 9b00746. doi: 10.1021/acs.chemrev.9b00746
2. [2]
  Jiang, Y.; Tan, P.; Qi, S. C.; Liu, X. Q.; Yan, J. H.; Fan, F.; Sun, L. B. Metal-organic frameworks with target-specific active sites switched by photoresponsive motifs: efficient adsorbents for tailorable CO₂ capture. Angew. Chem., Int. Ed. 2019, 58, 6457–6457. doi: 10.1002/anie.201903069
3. [3]
  Wan, X. Y.; Zhang, G. L.; Cheng, L.; Jiang, F. L.; Hong, M. C. Metal-induced coordination networks using a C2v-based hexacarboxylate ligand: syntheses, structures and properties. Chin. J. Struct. Chem. 2019, 38, 1370–1379.
4. [4]
  Mchugh, L. N.; Terracina, A.; Wheatley, P. S.; Buscarino, G.; Smith, M. W.; Morris, R. E. Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams. Angew. Chem., Int. Ed. 2019, 58, 11747–11751. doi: 10.1002/anie.201905779
5. [5]
  Xiao, J. D.; Jiang, H. L. Metal-organic frameworks for photocatalysis and photothermal catalysis. Acc. Chem. Res. 2019, 52, 2, 356–366. doi: 10.1021/acs.accounts.8b00521
6. [6]
  Sengupta, A.; Datta, S.; Su, C. L.; Herng, T. S.; Ding, J.; Jittal, J. J.; Loh, K. P. Tunable electrical conductivity and magnetic property of the two dimensional metal organic framework [Cu(TPyP)Cu₂(O₂CCH₃)₄]. ACS Appl. Mater. Interfaces 2016, 8, 16154–16159. doi: 10.1021/acsami.6b03073
7. [7]
  Wang, K.; Huang, X. K.; Zhu, L.; Chen, Z. L.; Liang, F. P. A chain cadmium(Ⅱ) coordination polymer with diacylhydrazide: synthesis, crystal structure and luminescent property. Chin. J. Struct. Chem. 2016, 35, 1912–1919.
8. [8]
  Chen, L. Y.; Li, D. Z.; Wang, Y. X.; Duan, C. Y. Highly efficient solar steam generation of supported metal-organic framework membranes by a photoinduced electron transfer process. Nanoscale 2019, 11121–11127.
9. [9]
  Qu, F.; Li, X. N.; Lv, X. X.; You, J. M.; Han, W. L. Highly selective metal-organic framework-based sensor for protamine through photoinduced electron transfer. J. Mater. Sci. 2019, 54, 3144–3155. doi: 10.1007/s10853-018-3041-6
10. [10]
  Xiao, Y. H.; Gu, Z. G.; Zhang, J. Surface-coordinated metal-organic framework thin films (SURMOFs) for electrocatalytic applications. Nanoscale 2020, 12, 12712–12730. doi: 10.1039/D0NR03115A
11. [11]
  Tang, J.; Salunkhe, R. R.; Liu, J.; Torad, N. L.; Imura, M.; Furukawa, S.; Yamauchi, Y. Thermal conversion of core-shell metal-organic frameworks: a new method for selectively functionalized nanoporous hybrid carbon. J. Am. Chem. Soc. 2015, 137, 1572–1580. doi: 10.1021/ja511539a
12. [12]
  Lu, C.; Ben, T.; Xu, S.; Qiu, S. Electrochemical synthesis of a microporous conductive polymer based on a metal-organic framework thin film. Angew. Chem., Int. Ed. 2014, 53, 6454–6458. doi: 10.1002/anie.201402950
13. [13]
  Li, S. Z.; Yang, K.; Tan, C. L.; Huang, X.; Huang, W.; Zhang, H. Preparation and applications of novel composites composed of metal-organic frameworks and two-dimensional materials. Chem. Commun. 2016, 52, 1555–1562. doi: 10.1039/C5CC09127F
14. [14]
  Costa, P.; Gonçalves, S.; Mora, H.; Carabineiro, S. A. C.; Viana, J. C.; Mendez, S. L. Highly sensitive piezoresistive graphene-based stretchable composites for sensing applications. ACS Appl. Mater. Interfaces 2019, 11, 46286–46295. doi: 10.1021/acsami.9b19294
15. [15]
  Wang, X.; Wang, Q. X.; Wang, Q. H.; Gao, F.; Yang, Y. Z.; Guo, H. X. College of highly dispersible and stable copper terephthalate metal-organic framework-graphene oxide nanocomposite for an electrochemical sensing application. ACS Appl. Mater. Interfaces 2014, 6, 11573–11580. doi: 10.1021/am5019918
16. [16]
  Liu, J. W.; Zhang, Y.; Chen, X. W.; Wang, J. H. Graphene oxide-rare earth metal-organic framework composites for the selective isolation of hemoglobin. ACS Appl. Mater. Interfaces 2014, 6, 10196–10204. doi: 10.1021/am503298v
17. [17]
  Yang, J.; Zhao, F. Q.; Zeng, B. Z. One-step synthesis of a copper-based metal-organic framework-graphene nanocomposite with enhanced electrocatalytic activity. RSC Adv. 2015, 5, 22060–22065. doi: 10.1039/C4RA16950F
18. [18]
  Xiao, Y.; Guo, B.; Zhang, J.; Hu, C.; Ma, R. G.; Wang, D. Y.; Wang, J. C. Bimetallic MOFs@Graphene oxide composites as efficient bifunctional oxygen electrocatalysts in rechargeable Zn-Air batteries. Dalton Trans. 2020, 49, 5730–5735. doi: 10.1039/D0DT00976H
19. [19]
  Meng, W.; Xu, F.; Xu, W. J. An anionic heptacopper(Ⅱ) oxo-cluster {Cu₇^Ⅱ} with an S = 7/2 ground state. Inorg. Chem. 2016, 55, 540–542. doi: 10.1021/acs.inorgchem.5b02206
20. [20]
  Meng, W.; Ye, H. F.; Liu, S.; Xu, F.; Xu, W. J. Emergence of complex chiral coordination clusters {Cu₄₈^ⅡNa₁₂} by using multiple ligands under oxidizing conditions. Dalton Trans. 2019, 48, 3204–3208. doi: 10.1039/C9DT00209J
21. [21]
  Sheldrick, G. M. SHELXL97, Program for Crystal Structure Refinement. University of Göttingen: Göttingen, Germany 1997.
22. [22]
  William, S.; Hummers, J.; Richard, E. Preparation of graphitic oxide. J. Am. Chem. Soc. 1958, 80, 1339–1342.
23. [23]
  Li, D.; Muller, M. B.; Gilje, S.; Kaner, R. B.; Wallace, G. G. Processable aqueous dispersions of graphene nanosheets. Nat. Nanotechnol. 2008, 3, 101–105. doi: 10.1038/nnano.2007.451
24. [24]
  Wang, H.; Hao, Q.; Yang, X.; Lu, L.; Wang, X. Graphene oxide doped polyaniline for supercapacitors. Electrochem. Commun. 2009, 11, 1158–1161. doi: 10.1016/j.elecom.2009.03.036
1. [1]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
2. [2]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
3. [3]
  Zhihui ZONG , Zijie ZHAO , Lei HUANG , Zhicheng PAN , Shan WANG , Lili LIANG , Huaqing LIU , Enli ZHANG . Synthesis, crystal structures, and antitumor activity of two metal complexes of imidazolyl acylhydrazones. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 1048-1062. doi: 10.11862/CJIC.20250330
4. [4]
  Ran ZHUANG , Xinru WANG , Ruwei SHEN , Dunru ZHU . Syntheses, crystal structures and Hirshfeld surface analyses of three 3-pyridazinyl-substituted triaryltriazoles and their Cu(Ⅱ) complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1712-1722. doi: 10.11862/CJIC.20260136
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
9. [9]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
10. [10]
  Xuetian WANG , Jijiang WANG , Long TANG , Erlin YUE , Xiao WANG , Yuqi ZHANG . A three-dimensional zinc(Ⅱ) metal-organic framework based on nitrogen-containing ligands for the detection of 2,4-dinitrophenylhydrazine and tetracycline. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 861-871. doi: 10.11862/CJIC.20250294
11. [11]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
12. [12]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
13. [13]
  Yingyue ZHANG , Liuqing KANG , Yating YANG , Xiaofen GUAN , Wenmin WANG . Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1867-1877. doi: 10.11862/CJIC.20250100
14. [14]
  Wenya DING , Fangfei XU , Jiayu GU , Xinran CHEN , Kai CHEN . Synthesis and crystal structure of three cucurbit[6]uril-cadmium supramolecular assemblies. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 808-816. doi: 10.11862/CJIC.20260012
15. [15]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
16. [16]
  Jiarong ZHU , Xiaohua ZHANG , Xinting XIONG , Xuliang NIE , Xiuying SONG , Miaomiao ZHANG , Dayong PENG , Xiuguang YI . Crystal structure, Hirshfeld surface analysis, and antifungal activity of five complexes based on 2,5-bis(carboxymethoxy)terephthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2358-2370. doi: 10.11862/CJIC.20250150
17. [17]
  Jing FENG , Renshu WANG , Hu WANG , Hailong LIU . Co(Ⅱ) and Ni(Ⅱ) complexes of 3,3-diphenylpropionic acid and 2,2′-dipyridylamine: Structures and biological activities. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 617-631. doi: 10.11862/CJIC.20250265
18. [18]
  Jiaojiao CHEN , Gaiyan GUO , Hua YANG , Shuo LIU , Lulu DONG , Xiaoli CHEN , Huali CUI , Jijiang WANG . Syntheses, structures, fluorescence properties, and applications of two Cd-based metal-organic framework materials based on polycarboxylic acids. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1763-1778. doi: 10.11862/CJIC.20250359
19. [19]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
20. [20]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1834)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142