Citation: Chao-Nan CUI, Han-Yu ZHANG, Zhi-Xun LUO, Feng PAN. Preparation and Reaction of Naked Metal Clusters for Catalysis and Genetic Materials[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 989-998. doi: 10.14102/j.cnki.0254-5861.2011-2886 shu

Preparation and Reaction of Naked Metal Clusters for Catalysis and Genetic Materials

Chao-Nan CUI ^{a, ②} ,
Han-Yu ZHANG ^{a, b, ②} ,
Zhi-Xun LUO ^{a, b,,} ,
Feng PAN ^c

a.
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
School of Advanced Materials, Peking University Shenzhen Graduate School, Shenzhen 518055, China

Corresponding author: Zhi-Xun LUO, zxluo@iccas.ac.cn
Received Date: 20 May 2020
Accepted Date: 3 June 2020

Fund Project: the National Natural Science Foundation of China 21802146the National Natural Science Foundation of China 21722308CAS Key Research Project of Frontier Science CAS Grant QYZDB-SSW-SLH024Frontier Cross Project of National Laboratory for Molecular Sciences 051Z011BZ3

Figures(2)

Metal clusters that contain a small number of atoms usually present unique properties with dramatic dependence on their sizes, geometric structures, and compositions. The studies of naked metal clusters are devoted to develop new catalysts and functional materials of atomic precision, and enable to improve the fundamental theory of structure chemistry and to understand the basic reactions and properties bridging the gap between atoms and bulk materials. In particular, some interesting superatom clusters have received reasonable research interest indicative of materials gene of clusters. Here in this review, we simply summarize the preparation, stability, and reactivity of naked metal clusters with a few examples displayed. Hopefully it serves as a modest spur to stimulate more interest of related investigations in this field.
- metal clusters,
- structure chemistry,
- superatom,
- cluster reactivity
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