Citation: Zhe AN, Jun-Jiang TENG. A 3D Supramolecular Cu(Ⅰ) Compound Obtained by in situ Hydrolysis, Deaminization, Reduction and Self-assemble Reaction[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1735-1739. doi: 10.14102/j.cnki.0254-5861.2011-2697 shu

A 3D Supramolecular Cu(Ⅰ) Compound Obtained by in situ Hydrolysis, Deaminization, Reduction and Self-assemble Reaction

Zhe AN ,
Jun-Jiang TENG ^,

School of Chemistry, Guangdong University of Petrochemical Technology, Maoming 525000, China

Corresponding author: Jun-Jiang TENG, junjiangteng@163.com
Received Date: 11 December 2019
Accepted Date: 4 March 2020

Fund Project:

Figures(3)

A new Cu(Ⅰ) coordination polymer, [Cu₄(MA)₂(HCA)₂]_n (1, MA = melamine, H₃CA = cyanuric acid), has been synthesized under hydrothermal conditions using CuCl₂·2H₂O and MA as the starting materials. Interestingly, cyanuric acid was obtained by the in situ hydrolysis and the deaminization of melamine, and the Cu(Ⅰ) ion was obtained by the in situ reduction of Cu(Ⅱ) ion during the self-assembly process. The crystal structure is of monoclinic, space group P_c with a = 3.539(3), b = 22.377(2), c = 15.844(1) Å, β = 90.723(1)º, V = 1254.6(2) Å³, C₁₂H₁₄Cu₄N₁₈O₆, M_r = 760.61, Z = 2, D_c = 2.013 g/cm³, F(000) = 752, μ = 3.426 mm^-1, R = 0.0479 and wR = 0.1243 for 3172 observed reflections (I > 2σ(I)). The crystal structural analysis revealed that the cooperation of coordinate-covalent bonds, intermolecular hydrogen bonds and π-π interactions give rise to a 3D supramolecular framework with 5-connected BN topology. Moreover, the thermal stability and luminescent property of 1 were also investigated.
- Cu(Ⅰ),
- solvothermal synthesis,
- supramolecular framework,
- luminescent property
1. [1]
  Li, X. N.; Wu, X. Y.; Zhao, W. W.; Yang, M. X.; Yu, R. M.; Lu, C. Z. Synthesis, crystal structure and photoluminescence of a dinulear copper complex. Chin. J. Struct. Chem. 2018, 37, 1645–1650.
2. [2]
  Wang, Y.; Wang, F. Synthesis, crystal structure and photoluminescence of a copper(Ⅰ)-iodide coordination polymer based on polyimidazolate ligand. Chin. J. Struct. Chem. 2019, 38, 1759–1763.
3. [3]
  Lee, J.; Farha, O. K.; Roberts, J.; Scheidt, K. A.; Nguyen, S. T.; Hupp, J. T. Metal-organic materials as catalyst. Chem. Soc. Rev. 2009, 38, 1450−1459. doi: 10.1039/b807080f
4. [4]
  Peng, R.; Li, M.; Li, D. Copper(Ⅰ) halides: a versatile family in coordination chemistry and crystal engineering. Coord. Chem. Rev. 2010, 254, 1–18. doi: 10.1016/j.ccr.2009.10.003
5. [5]
  Shi, Z. Z.; Qin, L.; Zheng, H. G. Two new Zn(Ⅱ)/Cu(Ⅱ) complexes based on bi- and tritopic 1,2,4-triazole derivatives with glutaric acid: syntheses, structures, luminescent and magnetic properties. Inorg. Chem. Commun. 2017, 79, 21−24. doi: 10.1016/j.inoche.2017.03.017
6. [6]
  Ye, R. P.; Zhang, X.; Qin, Y. Y.; Yao, Y. G. Combined influence of hydrogen bonds and pi-pi interactions on the assembly of five manganese coordination polymers with magnetic properties. CrystEngComm. 2017, 19, 1658–1668. doi: 10.1039/C7CE00004A
7. [7]
  Zhang, H. X.; Wang, F.; Kang, Y.; Zhang, J. Doubly interpenetrated hms-type metal organic framework formed by perfect face-to-face π···π stacking interactions. Inorg. Chem. Commun. 2010, 13, 1429–1431. doi: 10.1016/j.inoche.2010.08.008
8. [8]
  Zhang, X.; Huang, Y. Y.; Liu, Z. S.; Yao, Y. G. Distinct chain/layer structures in silver(Ⅰ) compounds: synthesis, structures, and photoluminescent properties. Z. Anorg. Allg. Chem. 2012, 638, 1042–1046. doi: 10.1002/zaac.201200025
9. [9]
  Zou, R.; Zhang, J.; Hu, S. Z.; Hu, F.; Zhang, H. Y.; Fu, Z. Y. Reversible mechanochromic and thermochromic luminescence switching via hydrogen-bond-directed assemblies in a zinc coordination complex. CrystEngComm. 2017, 19, 6259–6262. doi: 10.1039/C7CE01511A
10. [10]
  Chai, X. C.; Gao, X. N.; Li, H.; Zhang, H. H.; Han, Q. P. Two coordination novel polymers based on a flexible ligand N, N΄-diacetic acid imidazolium. Chin. J. Struct. Chem. 2017, 36, 463–470.
11. [11]
  Wang, L. H.; Liu, L. Z.; Yao, Z. Z.; Ye, Y. X.; Ma, X. L.; Chen, Q. H.; Zhang, Z. J.; Xiang, S. C. A Cd(Ⅱ) metal-organic framework based on semi-rigid ligand 3,5-(4-carboxybenzyloxy) benzoic acid with high stability by intramolecular hydrogen-bonding. Inorg. Chem. Comm. 2017, 80, 49–52. doi: 10.1016/j.inoche.2017.02.012
12. [12]
  Yin, P. X.; Zhang, J.; Li, Z. J.; Qin, Y. Y.; Cheng, J. K.; Zhang, L.; Lin, Q. P.; Yao, Y. G. Supramolecular isomerism and various chain/layer substructures in silver(Ⅰ) compounds: syntheses, structures, and luminescent properties. Cryst. Growth & Des. 2009, 9, 4884−4896.
13. [13]
  Zhang, X. L.; Ye, B. H.; Chen, X. M. Infinite water chains trapped in an organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds. Cryst. Growth Des. 2005, 5, 1609–1616. doi: 10.1021/cg050096e
14. [14]
  Liu, H. Y.; Ji, S. J.; Hao, Y. H. Z. Hydrogen bonds directed 2D → 3D interdigitated silver(Ⅰ) coordination polymer: synthesis, structure, and catalytic property. Z. Anorg. Allg. Chem. 2014, 640, 2595–1046. doi: 10.1002/zaac.201400309
15. [15]
  Paul, A. K.; Naveen, K.; Kumar, N.; Kanagaraj, R.; Vidya, V. M.; Rom, T. First example of a nonanuclear silver sulfate hybrid cluster: green approach for synthesis of lewis acid catalyst. Cryst. Growth Des. 2018, 18, 6411–6416. doi: 10.1021/acs.cgd.8b01258
16. [16]
  Zhang, L.; Zhang, J.; Yin, P. X.; Cheng, J. K.; Li, Z. J.; Yao, Y. G. A simultaneous hydrolysis, deaminization, and self-assembly reaction under hydrothermal conditions affording a novel hydrogen bonding network: NH₄[Cu(H₂CAC)₂]. Z. Anorg. Allg. Chem. 2006, 632, 1902–1905 doi: 10.1002/zaac.200600086
17. [17]
  Zhang, L.; Zhang, J.; Li, Z. J.; Cheng, J. K.; Yin, P. X.; Yao, Y. G. New coordination motifs of melamine directed by N−H···X (X = Cl or Br) hydrogen bonds. Inorg. Chem. 2007, 46, 5838–5840. doi: 10.1021/ic7005138
18. [18]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Cryst. C Struct. Chem. 2015, 71, 3–8. doi: 10.1107/S2053229614024218
19. [19]
  Ohi, H.; Tachi, Y.; Kunimoto, T.; Itoh, S. Structure and photoluminescence property of two-dimensional coordination polymer complexes involving Cu₆^IX₆ (X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1,3,5-triethylbenzene spacer. Dalton Trans. 2005, 3146–3147.
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