Citation: Yu-Quan FENG, Zhi-Guo ZHONG, Jing LI. Synthesis, Structure, Fluorescence and Magnetic Properties of a New Binuclear Cobalt(Ⅱ) Complex Containing Three Kinds of Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1070-1076. doi: 10.14102/j.cnki.0254-5861.2011-2659 shu

Synthesis, Structure, Fluorescence and Magnetic Properties of a New Binuclear Cobalt(Ⅱ) Complex Containing Three Kinds of Ligands

College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China

Corresponding author: Yu-Quan FENG, yqfeng2008@126.com
Received Date: 6 November 2019
Accepted Date: 19 January 2020

Fund Project: the National Natural Science Foundation of China 21601095

Figures(5)

A new binuclear cobalt(Ⅱ) complex, [Co₂(C₁₀H₆NO₂)₂(C₁₂H₈N₂)₂(N₃)₂]·H₂O (1, C₁₀H₆NO₂^-: isoquinoline-1-carboxylate, C₁₂H₈N₂: 1, 10-phenanthroline (phen); N₃^-: azide), has been synthesized though a mixed-solvothermal method using the pentanol and distilled water as solvent. The complex was characterized by elemental analysis, IR spectrum and single-crystal X-ray diffraction. It crystallizes in triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with Z = 2, a = 1.777(5), b = 11.815(5), c = 17.141(7) Å, α = 74.496(6)°, β = 70.537(6)°, γ = 67.861(6)°, V = 2055.4(14) Å³, M_r = 922.66, D_c = 1.491 g/cm³, λ = 0.71073 Å, μ = 0.870 mm^-1, F(000) = 942, R = 0.0455 and wR = 0.1147 for 4960 observed reflections with I > 2σ(I) and S = 1.129. Its molecular structure is constructed by two Co²⁺ cations, two chelating phen ligands, two chelating isoquinoline-1-carboxylate ligands, two bridging linear azide anions and two uncoordinated half-occupied water molecules. The 3-D supramolecular network results from the multiple hydrogen bonds and π-π stacking interactions among three types of ligands. More importantly, its thermal stability, luminescent properties and magnetic properties have also been studied in detail.
- binuclear cobalt(Ⅱ) complex,
- thermal stability,
- fluorescence decay,
- magnetic properties
1. [1]
  Xu, J.; Su, W. P.; Hong, M. C. A series of lanthanide secondary building units based metal-organic frameworks constructed by organic pyridine-2, 6-dicarboxylate and inorganic sulfate. Cryst. Growth Des. 2011, 11, 337–346. doi: 10.1021/cg101343k
2. [2]
  Zhao, Y. C.; Yao, L. S.; Li, J. Y.; Yu, Y. H.; Hou, G. F.; Gao, J. S. Two cobalt(Ⅱ) coordination polymers based on tetrazylphosphonate and tetrazylphosphonic acid ligands. Chin. J. Struct. Chem. 2017, 36, 453–462.
3. [3]
  Mckinlay, A. C.; Morris, R. E.; Horcajada, P.; Férey, G.; Gref, R.; Couvreur, P.; Serre, C. BioMOFs: metal-organic frameworks for biological and medical applications. Angew. Chem., Int. Ed. 2010, 49, 6260–6266. doi: 10.1002/anie.201000048
4. [4]
  Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 1001–1033. doi: 10.1021/cr200139g
5. [5]
  Zhang, T.; Xue, L. P. Ionothermal synthesis, crystal structure and photocatalytic property of a new cobalt coordination polymer. Chin. J. Struct. Chem. 2015, 34, 417–422.
6. [6]
  Fu, L. H.; Li, X. M.; Liu, B.; Zhou, S. Two new Mn(Ⅱ)/Co(Ⅱ) complexes assembled by 2, 5-dihydroxy-1, 4-benzenedicarboxylic acid and phenanthroline or derivative. Chin. J. Struct. Chem. 2019, 38, 1549–1556.
7. [7]
  Feng, X.; Feng, Y. Q.; Chen, J. J.; Ng, S. W.; Wang, L. Y.; Guo, J. Z. Reticular three-dimensional 3d-4f frameworks constructed through substituted imidazole dicarboxylate: syntheses, luminescence and magnetic properties study. Dalton Trans. 2015, 44, 804–816. doi: 10.1039/C4DT02047B
8. [8]
  Zhao, J. S.; Jin, P.; Xi, N.; Wei, D. D.; Li, J.; Deng, W.; Hu, C. H.; He, D. Design, synthesis and crystal structure of the antitumor agent N1-(2-(4-methoxy-2-nitrophenoxy)-2-dimethyl acyloxymethyl)-5-fluorouracil. Chin. J. Struct. Chem. 2017, 36, 937–942.
9. [9]
  Zhang, W.; Qi, S. G.; Feng, Y. Q. A novel alkaline earth strontium(Ⅱ) coordination polymer: poly[hexaaquatetrakis(μ₅-pyridine-2, 6-dicarboxylato) bis(μ₄-pyridine-2, 6-dicarboxylato)(μ₇-sulfato) heptastrontium(Ⅱ)]. Acta Cryst. C 2014, 70, 584–587. doi: 10.1107/S205322961401002X
10. [10]
  Feng, Y. Q.; Fan, H. T.; Zhong, Z. G.; Wang, H. W.; Qiu, D. F. Cd₃(MoO₄)(TeO₃)₂: a polar 3D compound containing d¹⁰-d⁰ scalp effect cations. Inorg. Chem. 2016, 55, 11987−11992.
11. [11]
  Feng, Y. Q.; Zhong, Z. G.; Wang, H. W.; Fan, H. T.; Bi, D. Q.; Wang, L.; Xing, Z. Z.; Qiu, D. F. A novel open-framework copper borovanadate with enhanced catalytic performance for oxidation of benzylic C–H bond. Chem. Eur. J. 2017, 23, 9962−996. doi: 10.1002/chem.201702207
12. [12]
  Feng, Y. Q.; Li, M.; Fan, H. T.; Huang, Q. Z.; Qiu, D. F.; Shi, H. Z. A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels. Dalton Trans. 2015, 44, 894−897. doi: 10.1039/C4DT02840F
13. [13]
  Feng, Y. Q.; Li, Z. K.; Zhong, Z. G.; Wang, H. W.; Qiu, D. F. CsBP₂O₆(OH)₂: a second-order NLO material with unique borophosphate anionic partial structure and strong SHG effect. Dalton Trans. 2020, DOI: 10.1039/C9DT04358F.
14. [14]
  Feng, Y. Q.; Chen, S. Y.; Wang, L.; Xing, Z. Z. Ionothermal synthesis, structure and luminescent properties of a new 2-D bismuth(Ⅲ) coordination polymer with (6, 5)-connected yopological sheet. Chin. J. Struct. Chem. 2018, 37, 1656–1662.
15. [15]
  Kong, L. T.; Bi, J. H.; Hu, N. L. Hydrothermal synthesis and characterization of diazido bis(1, 10-phenanthroline) cobalt(Ⅱ) complex: [Co(N₃)₂(phen)₂]. J. Shangqiu Teach. Coll. 2008, 24, 73−75.
16. [16]
  Sheldrick, G. M. SADABS. Program of Empirical Absorption Correction for Area Detector Data. University of Göttingen: Göttingen, Germany 1996.
17. [17]
  Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009, 42, 339−341.
18. [18]
  O΄Keeffe, M.; Brese, N. E. Bond-valence parameters for anion-anion bonds in solids. Acta Cryst. B48 1992, 152–154.
19. [19]
  Ray, U.; Chand, B.; Mostafa, G.; Cheng, J.; Lu, T. H.; Sinha, C. Mono- and binuclear cobalt(Ⅱ)-azido complexes of arylazoimidazole: synthesis, spectral characterization, electrochemistry and crystal structure. Polyhedron 2003, 22, 2587–2594. doi: 10.1016/S0277-5387(03)00347-4
20. [20]
  Zhang, W.; Feng, Y. Q. A novel dinuclear bismuth(Ⅲ) coordination compound: bis(μ-pyridine-2, 6-dicarboxylato)-κ⁴O₂, N, O₆: O₆΄;κ⁴O₂: O₂΄, N, O₆-bis[(azido-κN)(1, 10-phenanthroline-κ²N, N΄)bismuth(Ⅲ)] tetrahydrate. Acta Cryst. C 2014, 70, 562–565.
21. [21]
  Feng, Y. Q.; Jiang, L. T.; Xing, Z. Z.; Wang, L. Crystal structure and luminescence of a new dinuclear yttrium(Ⅲ) coordination polymer with 1-D wave-like infinite chains. Chin. J. Struct. Chem. 2018, 37, 825–831.
22. [22]
  Wang, Y. Q.; Sun, Q.; Gao, E. Q. Novel three-dimensional framework based on Co(Ⅱ)-azide chains and a tetrapyridyl ligand. Inorg. Chem. Commun. 2011, 15, 8–11.
23. [23]
  Feng, X.; Chen, J. L.; Bai, R. F.; Wang, L. Y.; Wei, J. T.; Chen, X. X. Two unique cobalt-organic frameworks based on substituted imidazole-dicarboxylate and dipyridyl-type ancillary ligands: crystal structures and magnetic properties. Inorg. Chem. Comm. 2016, 66, 41–46.
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
3. [3]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
4. [4]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
5. [5]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
6. [6]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
7. [7]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
8. [8]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
9. [9]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
10. [10]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933
11. [11]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
12. [12]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
13. [13]
  Xiaoyu Chen , Jiahao Hu , Jingyi Lin , Haiyang Huang , Changqing Ye , Hongli Bao . Biisoindolylidene solvatochromic fluorophores: Synthesis and photophysical properties. Chinese Chemical Letters, 2025, 36(2): 109923-. doi: 10.1016/j.cclet.2024.109923
14. [14]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
15. [15]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
16. [16]
  Zhiqing Ge , Zuxiong Pan , Shuo Yan , Baoying Zhang , Xiangyu Shen , Mozhen Wang , Xuewu Ge . Novel high-temperature thermochromic polydiacetylene material and its application as thermal indicator. Chinese Chemical Letters, 2024, 35(11): 109850-. doi: 10.1016/j.cclet.2024.109850
17. [17]
  Shuai Liang , Wen-Jing Jiang , Ji-Xiang Hu . Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100430-100430. doi: 10.1016/j.cjsc.2024.100430
18. [18]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
19. [19]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
20. [20]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(287)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142