Citation: Zai-Gang LUO, Qian-Nan LIU, Rui LI, Xue-Mei XU. Synthesis, Crystal Structure and Thermal Property of Dimethyl Phenanthrene-9,10-dicarboxylate[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 908-912. doi: 10.14102/j.cnki.0254-5861.2011-2597 shu

Synthesis, Crystal Structure and Thermal Property of Dimethyl Phenanthrene-9,10-dicarboxylate

College of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China

Corresponding author: Zai-Gang LUO, luozi139@163.com
Received Date: 10 September 2019
Accepted Date: 18 December 2019

Fund Project: the Natural Science Research Projects in Colleges and Universities of Anhui Province KJ2019A0116Natural Science Foundation of Anhui Province 1608085MB38

Figures(4)

The target compound (C₁₈H₁₄O₄) was synthesized and structurally determined by single-crystal X-ray diffraction. The crystal is of monoclinic system, space group P2₁/n with a = 7.9383(6), b = 19.5083(13), c = 9.4189(7) Å, β = 98.981(2)°, C₁₈H₁₄O₄, M_r = 294.29, D_c = 1.357 g/cm³, V = 1440.75(18) Å³, Z = 4, F(000) = 616, µ(MoKa) = 0.096 mm^-1, T = 293(2) K, 3320 independent reflections with 1845 observed ones (I > 2σ(I)), R = 0.0529 and wR = 0.1082 with GOF = 1.015 (R = 0.1202 and wR = 0.1278 for all data). The phenanthrene skeleton is coplanar. The overall crystal packing revealed that it has reverse staggered parallel and stratified arrangement. And a one-dimensional interaction model was formed by two kinds of π-π interactions between the two adjacent molecules at upper and lower levels. The decomposition mechanism of compound 3 is complex.
- phenanthrene,
- synthesis,
- crystal structure,
- thermal property
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