Citation: Ye-Kun LIU, Xin-Hui ZHOU. Synthesis, Structure and Property of a Metal-organic Framework Based on 9-(2, 6-Dicarboxy-pyridin-4-yl)-9H-carbazole-3, 6-dicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 559-566. doi: 10.14102/j.cnki.0254-5861.2011-2586 shu

Synthesis, Structure and Property of a Metal-organic Framework Based on 9-(2, 6-Dicarboxy-pyridin-4-yl)-9H-carbazole-3, 6-dicarboxylic Acid

Ye-Kun LIU ^a ,
Xin-Hui ZHOU ^b,,

a.
Queen Mary University of London Engineering School, Northwestern Polytechnical University, Xi'an 710072, China
b.
Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: Xin-Hui ZHOU, iamxhzhou@njupt.edu.cn
Received Date: 29 August 2019
Accepted Date: 26 November 2019

Fund Project: the National Natural Science Foundation of China 21973047

Figures(4)

A new terbium(Ⅲ) metal-organic framework [Tb(HL)(H₂O)] (TbL) based on a new synthetic ligand 9-(2, 6-dicarboxy-pyridin-4-yl)-9H-carbazole-3, 6-dicarboxylic acid (H₄L) has been synthesized under solvothermal conditions. Its structure was determined by single-crystal X-ray diffraction analysis, and further characterized by powder X-ray diffraction analysis and IR spectra. The title complex crystallizes in trigonal space group P3₂12 with a = b = 13.6491(11), c = 32.345(3) Å, γ = 120°, V = 5218.5(10) Å³, C₄₂H₂₀N₄O₁₇Tb₂, M_r = 1170.46, D_c = 1.117 g/cm³, μ(MoKα) = 2.065 mm^-1, F(000) = 1698, GOF = 1.054, Z = 3, the final R = 0.0384 and wR = 0.0771 for 5223 observed reflections (I > 2σ(I)). In TbL, the tri-bridged binuclear Tb₂ units are bibridged by two carbazole-3, 6-dicarboxylate moieties to lead to the homochiral parallel arranged helical chains, which are further connected by 2, 6-pyridinedicarboxylate moieties to produce the chiral neutral 3D framework. There are there kinds of 1D channels in the framework with the channel space occupying 53.3% of the total volume. TbL exhibits intense characteristic green emission of Tb³⁺ ions.
- metal-organic frameworks (MOFs),
- terbium(Ⅲ),
- carbazole,
- photoluminescence
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