Citation: Li YAN, Wei LIU, Mi-Jia WANG, Yue XU, Ke-Zhuo SHI. Synthesis, Characterization, Oxygen Respiratory, Antibacterial Activity, and Photoluminescent Property Studies of One Novel Complex with Schiff-base Ligand[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 895-900. doi: 10.14102/j.cnki.0254-5861.2011-2585 shu

Synthesis, Characterization, Oxygen Respiratory, Antibacterial Activity, and Photoluminescent Property Studies of One Novel Complex with Schiff-base Ligand

Li YAN ^a,, ,
Wei LIU ^b ,
Mi-Jia WANG ^a ,
Yue XU ^a ,
Ke-Zhuo SHI ^a

a.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China
b.
College of Computer Science, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: Li YAN, yanli820618@163.com
Received Date: 28 August 2019
Accepted Date: 17 December 2019

Fund Project: the National Natural Science Foundation of China 21878120

Figures(6)

We have synthesized one novel Schiff-base ligand by modifying the aromatic aldehyde: H₂L¹ (H₂L¹ = N, N'-bis(2-oxy-acetate-3-methoxyl)benzylpropylene-ethanediamine). [Co(Ⅱ)L¹]₂·2EtOH (1) was prepared by the reaction between H₂L¹ and CoCl₂·6H₂O in the solvent of C₂H₅OH. The title compound was structurally characterized by elemental analysis, IR, H NMR and single-crystal X-ray diffraction. Complex 1 crystallizes in monoclinic, space group C2/c with a = 29.472(3), b = 13.4842(13), c = 15.1848(15) Å, β = 115.626(1)°, V = 5441.0(9) Å³, C₂₈H₂₂CoN₂O_8.50, M_r = 581.41, D_c = 1.420 g/cm³, μ(MoKα) = 0.685 mm^-1, F(000) = 2392, Z = 8, the final R = 0.0541 and wR = 0.1565 (I > 2σ(I)). The Co(Ⅱ) atom is hexa-coordinated, furnishing a triangular prism geometry. It is interesting that the H-bond intersections formed a one-dimensional chain structure. In this paper, we research the synthesis, characterization, oxygen respiratory, antibacterial activity, and photoluminescent property of complex 1.
- Schiff-base,
- HNMR,
- oxygen respiratory,
- antibacterial activity,
- photoluminescent property
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