Citation: Xiao-Yang ZHAO. Ionothermal Synthesis, Structure, Thermal Properties and Magnetic Behaviors of a Novel Dinuclear Copper(Ⅱ) Coordination Compound[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 978-982. doi: 10.14102/j.cnki.0254-5861.2011-2579 shu

Ionothermal Synthesis, Structure, Thermal Properties and Magnetic Behaviors of a Novel Dinuclear Copper(Ⅱ) Coordination Compound

Xiao-Yang ZHAO ^,

Department of Environmental Engineering, Henan Polytechnic Institute, Nanyang 473009, China

Corresponding author: Xiao-Yang ZHAO, zhaoxyhnpi@126.com
Received Date: 23 August 2019
Accepted Date: 25 November 2019

Figures(4)

A novel dinuclear copper(Ⅱ) coordination compound, [Cu^Ⅱ(Hpdc)(phen)Cl][Cu^Ⅱ(pdc)(phen)]·4H₂O (1, H₂pdc = pyridine-2, 6-dicarboxylic acid, phen = 1, 10-phenanthroline), has been obtained by an ionothermal method using the ionic liquid 3-butyl-1-methylimidazolium bromide ([Bmim]Br) as solvent, and fully characterized by elemental analyses, energy-dispersive X-ray spectroscopy (EDX), IR and single-crystal X-ray diffraction. 1 belongs to the triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 11.406(4), b = 11.801(5), c = 16.093(6) Å, α = 106.124(6)°, β = 113.480(7)°, γ = 93.853(7)°, Z = 2, V = 1942.3(13) Å³, D_c = 1.570 g∙cm^-3, F(000) = 928, μ = 1.235 mm^-1, the final R = 0.0588, wR = 0.1369 and S = 1.013. The compound exhibits a two-dimensional layered structure constructed by [Cu^Ⅱ(Hpdc)(phen)Cl] and [Cu^Ⅱ(pdc)(phen)] fragments via the hydrogen bonds and π-π stacking interactions. In addition, its thermal properties and magnetic behaviors were also studied in detail. The magnetic properties revealed that there is a ferromagnetic interaction between Cu···Cu in 1.
- ionothermal,
- dinuclear,
- π-π stacking interactions,
- thermal properties,
- magnetic behaviors
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