Citation: Xiao-Yang ZHAO. Ionothermal Synthesis, Structure, Thermal Properties and Magnetic Behaviors of a Novel Dinuclear Copper(Ⅱ) Coordination Compound[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 978-982. doi: 10.14102/j.cnki.0254-5861.2011-2579 shu

Ionothermal Synthesis, Structure, Thermal Properties and Magnetic Behaviors of a Novel Dinuclear Copper(Ⅱ) Coordination Compound

Xiao-Yang ZHAO ^,

Department of Environmental Engineering, Henan Polytechnic Institute, Nanyang 473009, China

Corresponding author: Xiao-Yang ZHAO, zhaoxyhnpi@126.com
Received Date: 23 August 2019
Accepted Date: 25 November 2019

Figures(4)

A novel dinuclear copper(Ⅱ) coordination compound, [Cu^Ⅱ(Hpdc)(phen)Cl][Cu^Ⅱ(pdc)(phen)]·4H₂O (1, H₂pdc = pyridine-2, 6-dicarboxylic acid, phen = 1, 10-phenanthroline), has been obtained by an ionothermal method using the ionic liquid 3-butyl-1-methylimidazolium bromide ([Bmim]Br) as solvent, and fully characterized by elemental analyses, energy-dispersive X-ray spectroscopy (EDX), IR and single-crystal X-ray diffraction. 1 belongs to the triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 11.406(4), b = 11.801(5), c = 16.093(6) Å, α = 106.124(6)°, β = 113.480(7)°, γ = 93.853(7)°, Z = 2, V = 1942.3(13) Å³, D_c = 1.570 g∙cm^-3, F(000) = 928, μ = 1.235 mm^-1, the final R = 0.0588, wR = 0.1369 and S = 1.013. The compound exhibits a two-dimensional layered structure constructed by [Cu^Ⅱ(Hpdc)(phen)Cl] and [Cu^Ⅱ(pdc)(phen)] fragments via the hydrogen bonds and π-π stacking interactions. In addition, its thermal properties and magnetic behaviors were also studied in detail. The magnetic properties revealed that there is a ferromagnetic interaction between Cu···Cu in 1.
- ionothermal,
- dinuclear,
- π-π stacking interactions,
- thermal properties,
- magnetic behaviors
1. [1]
  Wei, X. H.; Yang, L. Y.; Liao, S. Y.; Zhang, M.; Tian, J. L.; Du, P. Y.; Gu, W.; Liu, X. A series of rare earth complexes with novel non-interpenetrating 3D networks: synthesis, structures, magnetic and optical properties. Dalton Trans. 2014, 43, 5793–5800. doi: 10.1039/c3dt53112k
2. [2]
  Feng, Y. Q.; Jiang, L. T.; Xing, Z. Z.; Wang, L. Mixed-solvothermal synthesis, crystal structure and luminescence of a new dinuclear yttrium(Ⅲ) coordination polymer with 1-D wave-like infinite chains. Chin. J. Struct. Chem. 2018, 37, 825–831.
3. [3]
  Hawxwell, S. M.; Adams, H.; Brammer, L. Two-dimensional metal-organic frameworks containing linear dicarboxylates. Acta Cryst. 2006, B62, 808–814.
4. [4]
  Thirumurugan, A.; Natarajan, S. Assembly of a secondary building unit (SBU) into two-and three-dimensional structures in lanthanide benzenedicarboxylates. Cryst. Growth Des. 2006, 6, 983–988. doi: 10.1021/cg050580h
5. [5]
  Zhou, Q.; Zhang, Z. J.; Wang, F. F.; Han L.; Zhu, C. B.; Li, H. P.; Yang, Y. Synthesis and characterization of aryl acylguanidines and their copper(Ⅱ) complexes. Chin. J. Struct. Chem. 2019, 38, 1283─1296.
6. [6]
  Wang, D.; Wu, S. Y.; Li, H. P.; Yang, Y.; Roesky, H. W. Synthesis and characterization of copper complexes with the N-(2, 6-diisopropylphenyl)-N΄-acylthiourea ligands. Eur. J. Inorg. Chem. 2017, 36, 1406–1413.
7. [7]
  Thomas, S. P.; Shashiprabha, K.; Vinutha, K. R.; Nayak, S. P.; Nagarajan, K.; Row, T. N. G. Tautomeric preference and conformation locking in fenobam, thiofenobam, and their analogues: the decisive role of hydrogen bond hierarchy. Cryst. Growth & Des. 2014, 14, 3758–3766.
8. [8]
  Feng, Y. Q.; Chen, S. Y.; Wang, L.; Xing, Z. Z. Ionothermal synthesis, structure and luminescent properties of a new 2-D bismuth(Ⅲ) coordination polymer with (6, 5)-connected topological sheet. Chin. J. Struct. Chem. 2018, 37, 1656–1662.
9. [9]
  Rong, C.; Lin, J. D.; Fang, W. H. In situ ionothermal synthesis and characterization of a novel cuprous halide complex. Chin. J. Struct. Chem. 2017, 36, 689–695.
10. [10]
  Sheldrick, G. M. SADABS. Program of Empirical Absorption Correction forArea Detector Data. University of Göttingen: Göttingen, Germany 1996.
11. [11]
  Sheldrick, G. M. SHELX-97, Program for Crystal Structure Analysis. University of Göttingen: Göttingen, Germany 1997.
12. [12]
  Feng, Y. Q.; Fan, H. T.; Zhong, Z. G.; Wang, H. W.; Qiu, D. F. Cd₃(MoO₄)(TeO₃)₂: a polar 3D compound containing d¹⁰-d⁰ scalp effect cations. Inorg. Chem. 2016, 55, 11987−11992.
13. [13]
  Feng, Y. Q.; Zhao, Q.; Bi, D. Q. Solvothermal synthesis, structure and the second-order NLO properties of a novel non-metal 3-D borophosphate: (NH₄)₂[B₂P₂O₈(OH)₂]. Chin. J. Struct. Chem. 2019, 38, 1909–1915.
14. [14]
  Murtaza, G.; Badshah, A.; Said, M.; Khan, H.; Khan, A.; Khan, S.; Siddiq, S.; Choudhary, M. I.; Boudreau, J.; Fontaine, F. G. Urease inhibition and anti-leishmanial assay of substituted benzoylguanidines and their copper(Ⅱ) complexes. Dalton Trans. 2011, 40, 9202–9011.
15. [15]
  Feng, Y. Q.; Zhong, Z. G.; Wang, H. W.; Fan, H. T.; Bi, D. Q.; Wang, L.; Xing, Z. Z.; Qiu, D. F. A novel open-framework copper borovanadate with enhanced catalytic performance for oxidation of benzylic C–H bond. Chem. Eur. J. 2017, 23, 9962−9967.
16. [16]
  Feng, Y. Q.; Li, M.; Fan, H. T.; Huang, Q. Z.; Qiu, D. F.; Shi, H. Z. A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels. Dalton Trans. 2015, 44, 894-897.
1. [1]
  Jiayao Li , Xinru Peng , Shiwei Yin , Changwei Wang , Yirong Mo . Metastability of π-π stacking between the closed-shell ions of like charges. Chinese Journal of Structural Chemistry, 2024, 43(5): 100213-100213. doi: 10.1016/j.cjsc.2023.100213
2. [2]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
3. [3]
  Jian Ji , Jie Yan , Honggen Peng . Modulation of dinuclear site by orbital coupling to boost catalytic performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360-100360. doi: 10.1016/j.cjsc.2024.100360
4. [4]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
5. [5]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
6. [6]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
7. [7]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
8. [8]
  Xiaoru LIU , Jinlian SHI , Yajia ZHENG , Shuangcun MO , Zhongxuan XU . Two Ni-based frameworks with helices and dinuclear units constructed from semi-rigid carboxylic acid and imidazole derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 797-808. doi: 10.11862/CJIC.20240328
9. [9]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
10. [10]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
11. [11]
  Mao-Fan Li , Ming‐Yu Guo , De-Xuan Liu , Xiao-Xian Chen , Wei-Jian Xu , Wei-Xiong Zhang . Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]. Chinese Chemical Letters, 2024, 35(12): 109507-. doi: 10.1016/j.cclet.2024.109507
12. [12]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
13. [13]
  Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329
14. [14]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
15. [15]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
16. [16]
  Deli Chen , Jiawen Li , Xudong Xu , Zhaocui Sun , Yun Yang , Minghui Xu , Hanqiao Liang , Junshan Yang , Hui Meng , Guoxu Ma , Jianhe Wei . Plant-microbial interactions inspired the discovery of novel sesquiterpenoid dimeric skeletons of hidden natural products from Hibiscus tiliaceus. Chinese Chemical Letters, 2024, 35(10): 109451-. doi: 10.1016/j.cclet.2023.109451
17. [17]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
18. [18]
  Hong-Rui Li , Xia Kang , Rui Gao , Miao-Miao Shi , Bo Bi , Ze-Yu Chen , Jun-Min Yan . Interfacial interactions of Cu/MnOOH enhance ammonia synthesis from electrochemical nitrate reduction. Chinese Chemical Letters, 2025, 36(2): 109958-. doi: 10.1016/j.cclet.2024.109958
19. [19]
  Xueru Zhao , Aopu Wang , Shimin Wang , Zhijie Song , Li Ma , Li Shao . Adsorption and visual detection of nitro explosives by pillar[n]arenes-based host–guest interactions. Chinese Chemical Letters, 2025, 36(4): 110205-. doi: 10.1016/j.cclet.2024.110205
20. [20]
  Yunxia Liu , Guandong Wu , Lin Li , Yiming Niu , Bingsen Zhang , Botao Qiao , Junhu Wang . Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions. Chinese Chemical Letters, 2025, 36(4): 110608-. doi: 10.1016/j.cclet.2024.110608

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(326)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142