Citation: Xiao-Yang ZHAO. Ionothermal Synthesis, Structure, Thermal Properties and Magnetic Behaviors of a Novel Dinuclear Copper(Ⅱ) Coordination Compound[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 978-982. doi: 10.14102/j.cnki.0254-5861.2011-2579 shu

Ionothermal Synthesis, Structure, Thermal Properties and Magnetic Behaviors of a Novel Dinuclear Copper(Ⅱ) Coordination Compound

  • Corresponding author: Xiao-Yang ZHAO, zhaoxyhnpi@126.com
  • Received Date: 23 August 2019
    Accepted Date: 25 November 2019

Figures(4)

  • A novel dinuclear copper(Ⅱ) coordination compound, [Cu(Hpdc)(phen)Cl][Cu(pdc)(phen)]·4H2O (1, H2pdc = pyridine-2, 6-dicarboxylic acid, phen = 1, 10-phenanthroline), has been obtained by an ionothermal method using the ionic liquid 3-butyl-1-methylimidazolium bromide ([Bmim]Br) as solvent, and fully characterized by elemental analyses, energy-dispersive X-ray spectroscopy (EDX), IR and single-crystal X-ray diffraction. 1 belongs to the triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 11.406(4), b = 11.801(5), c = 16.093(6) Å, α = 106.124(6)°, β = 113.480(7)°, γ = 93.853(7)°, Z = 2, V = 1942.3(13) Å3, Dc = 1.570 g∙cm-3, F(000) = 928, μ = 1.235 mm-1, the final R = 0.0588, wR = 0.1369 and S = 1.013. The compound exhibits a two-dimensional layered structure constructed by [Cu(Hpdc)(phen)Cl] and [Cu(pdc)(phen)] fragments via the hydrogen bonds and π-π stacking interactions. In addition, its thermal properties and magnetic behaviors were also studied in detail. The magnetic properties revealed that there is a ferromagnetic interaction between Cu···Cu in 1.
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    1. [1]

      Wei, X. H.; Yang, L. Y.; Liao, S. Y.; Zhang, M.; Tian, J. L.; Du, P. Y.; Gu, W.; Liu, X. A series of rare earth complexes with novel non-interpenetrating 3D networks: synthesis, structures, magnetic and optical properties. Dalton Trans. 2014, 43, 5793–5800.  doi: 10.1039/c3dt53112k

    2. [2]

      Feng, Y. Q.; Jiang, L. T.; Xing, Z. Z.; Wang, L. Mixed-solvothermal synthesis, crystal structure and luminescence of a new dinuclear yttrium(Ⅲ) coordination polymer with 1-D wave-like infinite chains. Chin. J. Struct. Chem. 2018, 37, 825–831.

    3. [3]

      Hawxwell, S. M.; Adams, H.; Brammer, L. Two-dimensional metal-organic frameworks containing linear di­carboxylates. Acta Cryst. 2006, B62, 808–814.

    4. [4]

      Thirumurugan, A.; Natarajan, S. Assembly of a secondary building unit (SBU) into two-and three-dimensional structures in lanthanide benzenedicarboxylates. Cryst. Growth Des. 2006, 6, 983–988.  doi: 10.1021/cg050580h

    5. [5]

      Zhou, Q.; Zhang, Z. J.; Wang, F. F.; Han L.; Zhu, C. B.; Li, H. P.; Yang, Y. Synthesis and characterization of aryl acylguanidines and their copper(Ⅱ) complexes. Chin. J. Struct. Chem. 2019, 38, 1283─1296.

    6. [6]

      Wang, D.; Wu, S. Y.; Li, H. P.; Yang, Y.; Roesky, H. W. Synthesis and characterization of copper complexes with the N-(2, 6-diisopropylphenyl)-N΄-acylthiourea ligands. Eur. J. Inorg. Chem. 2017, 36, 1406–1413.

    7. [7]

      Thomas, S. P.; Shashiprabha, K.; Vinutha, K. R.; Nayak, S. P.; Nagarajan, K.; Row, T. N. G. Tautomeric preference and conformation locking in fenobam, thiofenobam, and their analogues: the decisive role of hydrogen bond hierarchy. Cryst. Growth & Des. 2014, 14, 3758–3766.

    8. [8]

      Feng, Y. Q.; Chen, S. Y.; Wang, L.; Xing, Z. Z. Ionothermal synthesis, structure and luminescent properties of a new 2-D bismuth(Ⅲ) coordination polymer with (6, 5)-connected topological sheet. Chin. J. Struct. Chem. 2018, 37, 1656–1662.

    9. [9]

      Rong, C.; Lin, J. D.; Fang, W. H. In situ ionothermal synthesis and characterization of a novel cuprous halide complex. Chin. J. Struct. Chem. 2017, 36, 689–695.

    10. [10]

      Sheldrick, G. M. SADABS. Program of Empirical Absorption Correction forArea Detector Data. University of Göttingen: Göttingen, Germany 1996.

    11. [11]

      Sheldrick, G. M. SHELX-97, Program for Crystal Structure Analysis. University of Göttingen: Göttingen, Germany 1997.

    12. [12]

      Feng, Y. Q.; Fan, H. T.; Zhong, Z. G.; Wang, H. W.; Qiu, D. F. Cd3(MoO4)(TeO3)2: a polar 3D compound containing d10-d0 scalp effect cations. Inorg. Chem. 2016, 55, 11987−11992.

    13. [13]

      Feng, Y. Q.; Zhao, Q.; Bi, D. Q. Solvothermal synthesis, structure and the second-order NLO properties of a novel non-metal 3-D borophosphate: (NH4)2[B2P2O8(OH)2]. Chin. J. Struct. Chem. 2019, 38, 1909–1915.

    14. [14]

      Murtaza, G.; Badshah, A.; Said, M.; Khan, H.; Khan, A.; Khan, S.; Siddiq, S.; Choudhary, M. I.; Boudreau, J.; Fontaine, F. G. Urease inhibition and anti-leishmanial assay of substituted benzoylguanidines and their copper(Ⅱ) complexes. Dalton Trans. 2011, 40, 9202–9011.

    15. [15]

      Feng, Y. Q.; Zhong, Z. G.; Wang, H. W.; Fan, H. T.; Bi, D. Q.; Wang, L.; Xing, Z. Z.; Qiu, D. F. A novel open-framework copper borovanadate with enhanced catalytic performance for oxidation of benzylic C–H bond. Chem. Eur. J. 2017, 23, 9962−9967.

    16. [16]

      Feng, Y. Q.; Li, M.; Fan, H. T.; Huang, Q. Z.; Qiu, D. F.; Shi, H. Z. A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels. Dalton Trans. 2015, 44, 894-897.

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