Citation: Yu-Jing NIE, Yan-Hua DENG, Hong-Xu GUO, Shao-Ming YING. Synthesis, Characterization and Adsorption Properties for Al-based Metal-organic Framework[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1029-1034. doi: 10.14102/j.cnki.0254-5861.2011-2576 shu

Synthesis, Characterization and Adsorption Properties for Al-based Metal-organic Framework

a.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou 363000, China
b.
Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry, College of Chemistry and Materials, Ningde Normal University, Ningde 352100, China

Corresponding author: Yu-Jing NIE, nieyujing@sina.com Shao-Ming YING, ysm@ndnu.edu.cn
Received Date: 21 August 2019
Accepted Date: 5 December 2019

Fund Project: the Natural Science Foundation of Fujian Province 2017J01420the Natural Science Foundation of Fujian Province 2018H0030Education Bureau of Fujian Province JZ160453Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry FJKL_FBCM201902

Figures(6)

Al-BTC MOFs were prepared in a facile manner via a solvothermal reaction and characterized using FT-IR, XRD, and SEM. The compound was then evaluated as an adsorbent to remove Congo red (CR) from an aqueous solution. The adsorption kinetics was evaluated using the pseudo-first-order and pseudo-second-order, and it was found that the adsorption of CR onto the MOFs was well described by the pseudo-second-order equation. The as-prepared MOFs adsorbent seems to be a promising material in practice for dyes removal from aqueous solution.
- Al-based metal-organic framework,
- characterization,
- adsorption properties,
- Congo red
1. [1]
  Zhu, T.; Chen, J. S.; Lou, X. W. Highly efficient removal of organic dyes from waste water using hierarchical NiO spheres with high surface area. J. Phys. Chem. C 2012, 116, 6873-6878. doi: 10.1021/jp300224s
2. [2]
  Bulut, E.; Özacar, M.; Şengil, İ. A. Equilibrium and kinetic data and process design for adsorption of Congo red onto bentonite. J. Hazard. Mater. 2008, 154, 613-622. doi: 10.1016/j.jhazmat.2007.10.071
3. [3]
  Khan, N. A.; Hasan, Z.; Jhung, S. H. Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J. Hazard. Mater. 2013, 244–245, 444-456.
4. [4]
  Guo, H. X.; Niu, B. T.; Wu, X. M.; Zhang, Y.; Ying, S. M. Effective removal of 2, 4, 6-trinitrophenol over hexagonal metal-organic framework NH2-MIL-88B(Fe). Appl. Organometal Chem. 2019, 33, 4580-11. doi: 10.1002/aoc.4580
5. [5]
  Wu, Y. W.; Wu, X. M.; Niu, B. T.; Zeng, Y. P.; Zhu, M. H.; Guo, H. X. Facile fabrication of Ag2(bdc)@Ag nano-composites with strong green emission and their response to sulfide anion in aqueous medium. Sens. Actuators B 2018, 255, 3163-3169. doi: 10.1016/j.snb.2017.09.141
6. [6]
  Wang, D. F.; Ke, Y. C.; Guo, D.; Guo, H. X.; Chen, J. H.; Weng, W. Facile fabrication of cauliflower-like MIL-100 (Cr) and its simultaneous determination of Cd2+, Pb2+, Cu2+ and Hg2+ from aqueous solution. Sens. Actuators B 2015, 216, 504-510. doi: 10.1016/j.snb.2015.04.054
7. [7]
  Guo, H. X.; Guo, D.; Zheng, Z. S.; Weng, W.; Chen, J. H. Visible-light photocatalytic activity of Ag@MIL-125 (Ti) microspheres. Appl. Organomet. Chem. 2015, 29, 618-623. doi: 10.1002/aoc.3341
8. [8]
  Haque, E.; Lee, J. E.; Jang, I. T.; Hwang, Y. K.; Chang, J. S.; Jegal, J.; Jhung, S. H. Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates. J. Hazard. Mater. 2010, 181, 535-542. doi: 10.1016/j.jhazmat.2010.05.047
9. [9]
  Haque, E.; Jun, J. W.; Jhung, S. H. Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235). J. Hazard. Mater. 2011, 185, 507-511. doi: 10.1016/j.jhazmat.2010.09.035
10. [10]
  Huo, S. H.; Yan, X. P. Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution. J. Mater. Chem. 2012, 22, 7449-7455. doi: 10.1039/c2jm16513a
11. [11]
  Patil, D. V.; Rallapalli, P. B. S.; Dangi, G. P.; Tayade, R. J.; Somani, R. S.; Bajaj, H. C. MIL-53(Al): an efficient adsorbent for the removal of nitrobenzene from aqueous solutions. Ind. Eng. Chem. Res. 2011, 50, 10516-10524. doi: 10.1021/ie200429f
12. [12]
  Li, L.; Xiang, S. L.; Cao, S. Q.; Zhang, J. Y.; Ouyang, G. F.; Chen, L. P.; Su, C. Y. A synthetic route to ultralight hierarchically micro/mesoporous Al(Ⅲ)-carboxylate metal-organic aerogels. Nat. Commun. 2013, 4, 1774-1782. doi: 10.1038/ncomms2757
13. [13]
  Volkringer, C.; Popov, D.; Loiseau, T.; Ferey, G.; Burghammer, M.; Riekel, C.; Haouas, M.; Taulelle, F. Synthesis, single-crystal X-ray microdiffraction, and NMR characterizations of the giant pore metal-organic framework aluminum trimesate MIL-100. Chem. Mater. 2009, 21, 5695-5696. doi: 10.1021/cm901983a
14. [14]
  Loiseau, T.; Lecroq, L.; Volkringer, C.; Marrot, J.; Ferey, G.; Haouas, M.; Taulelle, F.; Bourrelly, S.; Llewellyn, P.; Latroche. M. MIL-96, a porous aluminum trimesate 3D structure constructed from a hexagonal network of 18-membered rings and μ3-oxo-centered trinuclear units. J. Am. Chem. Soc. 2006, 128, 10223-10230. doi: 10.1021/ja0621086
15. [15]
  Wang, L.; Li, J.; Wang, Y.; Zhao, L.; Jiang, Q. Adsorption capability for Congo red on nanocrystalline MFe2O4 (M = Mn, Fe, Co, Ni) spinel ferrites. Chem. Eng. J. 2012, 72, 181-182.
16. [16]
  Hameed, B. H.; Rahman, A. A. Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material. J. Hazard. Mater. 2008, 160, 576-581. doi: 10.1016/j.jhazmat.2008.03.028
17. [17]
  Auta, M.; Hameed, B. H. Chitosan-clay composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue. Chem. Eng. J. 2014, 237, 352-361. doi: 10.1016/j.cej.2013.09.066
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