Citation: Yan XU, Xin-Xing LI, Hong-Xia WANG, Hao-Ran LIU, Meng-Qi CHEN, Qiang DOU. Synthesis, Crystal Structure and Luminescence of One-dimensional Homochiral Terbium(Ⅲ) Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1044-1050. doi: 10.14102/j.cnki.0254-5861.2011-2550 shu

Synthesis, Crystal Structure and Luminescence of One-dimensional Homochiral Terbium(Ⅲ) Coordination Polymers

Yan XU ^{a, b,,} ,
Xin-Xing LI ^{a, b} ,
Hong-Xia WANG ^{a, b} ,
Hao-Ran LIU ^a ,
Meng-Qi CHEN ^a ,
Qiang DOU ^a

a.
Department of Materials Science and Engineering, Suqian College, Suqian 223800, China
b.
Industrial Research Institute, Suqian College, Suqian 223800, China

Corresponding author: Yan XU, xuyan0511@126.com
Received Date: 26 July 2019
Accepted Date: 30 October 2019

Fund Project: Jiangsu Higher Education Institutions of China 18KJB150030

Figures(6)

Enantiomerically pure lanthanide(Ⅲ)-based phosphonates are successfully synthesized by using (R)- or (S)-(1-phenylethylamino)-methylphosphonate acid (pempH₂), namely, R- or S-[Tb₃(pempH₂)₂(pempH)₇]- Cl₂·H₂O (R-Tb or S-Tb), crystallizing in chiral space group P2₁2₁2₁. Compound R-Tb shows a one-dimensional homochiral triple-stranded helical chain structure where the Tb(Ⅲ) atoms are bridged by O-P-O units and μ₃-O(P) bridge. The thermal analysis, photoluminescence as well as optically active properties of compounds R-Tb and S-Tb have also been investigated.
- terbium(Ⅲ),
- crystal structure,
- luminescence,
- homochiral
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