Citation: Yu LI, Yong-Xuan CHEN, Zhen-Yu ZHAO, Xun-Zhong ZOU, An-Sheng FENG. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Three Ni(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Coordination Polymers Based on an Ether-bridged Tetracarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 967-977. doi: 10.14102/j.cnki.0254-5861.2011-2541 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Three Ni(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Coordination Polymers Based on an Ether-bridged Tetracarboxylic Acid

a.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
b.
School of Intelligent Manufacturing and Equipment, Shenzhen Institute of Information Technology, Shenzhen 518172, China

Corresponding author: Yu LI, liyuletter@163.com Zhen-Yu ZHAO, yxpzzy01@163.com
Received Date: 20 July 2019
Accepted Date: 29 October 2019

Fund Project: Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme 2015Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme 2018the Pearl River Scholar Foundation of Guangdong Industry Polytechnic RC2015-001the Opening Foundation of MOE Key Laboratory of Bioinorganic and Synthetic Chemistry 2016Innovation Team Project on University of Guangdong Province 2017GKCXTD001Science and Technology Planning Project of Guangzhou 201904010381the Science and Technology Innovation Project of Guangdong University Student pdjh2019b0690Shenzhen Science and Technology Plan Project JCYJ20170817112445033Shenzhen Science and Technology Plan Project GGFW2017041209483817

Figures(14)

Two 1D and one 3D coordination polymers, namely [Ni₂(μ₃-deta)(H₂biim)₃(H₂O)₂]_n (1), {[Zn₂(μ₄-deta)(phen)₂(H₂O)]·H₂O}_n (2) and [Cd₂(μ₆-deta)(phen)₂(H₂O)]_n (3), have been constructed hydrothermally using H₄deta (H₄deta = 2, 3, 3΄, 4΄-diphenyl ether tetracarboxylic acid), H₂biim (H₂biim = 2, 2΄-biimidazole), phen (phen = 1, 10-phenanthroline), and nickel, zinc or cadmium chlorides at 160 ℃. The products were isolated as stable crystalline solids and characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA) and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the triclinic system, space group P\begin{document}$ \overline 1 $\end{document}. Compounds 1 and 2 disclose a 1D chain structure. Compound 3 features a 3D framework. The structural diversity of compounds 1~3 is driven by the metal(Ⅱ) node and the type of supporting ligand. Magnetic studies for compound 1 demonstrate an antiferromagnetic coupling between the adjacent Ni(Ⅱ) centers. The luminescence behavior of compounds 2 and 3 was also investigated.
- coordination polymer,
- tetracarboxylic acid,
- magnetic properties,
- luminescent properties
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