Citation: Chuang LI, Yong-Ke HE, Na SHAO, Gang XIONG, Shuang-Yan WU, Li-Xin YOU, Ya-Guang SUN. Syntheses, Structures and Photoluminescence of Novel Lanthanide-organic Frameworks Based on 1, 4-Bis(3, 5-dicarboxylic pyrazol-1-ylmethyl) Benzene[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 960-966. doi: 10.14102/j.cnki.0254-5861.2011-2537 shu

Syntheses, Structures and Photoluminescence of Novel Lanthanide-organic Frameworks Based on 1, 4-Bis(3, 5-dicarboxylic pyrazol-1-ylmethyl) Benzene

The Key Laboratory of Inorganic Molecule-based Chemistry of Liaoning Province, College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: Yong-Ke HE, yk-h@163.com Ya-Guang SUN, sunyaguang@syuct.edu.cn
Received Date: 17 July 2019
Accepted Date: 28 October 2019

Fund Project: the National Natural Science Foundation of China 21701116the National Natural Science Foundation of China 21671139the National Natural Science Foundation of China 21501122the Doctor Scientiﬁc Research Foundation of Liaoning Province 201601201the Doctor Scientiﬁc Research Foundation of Liaoning Province 201601193Program for Liaoning Innovative Research Team in University 2018012

Figures(4)

Two isomorphic 3D lanthanide metal-organic frameworks, {[Tb(L)_0.5(OX)_0.5(H₂O)₂DMF]^.DMF}_n (1) and {[Dy(L)_0.5(OX)_0.5(H₂O)₂DMF]^.DMF}_n (2), have been prepared under solvothermal conditions based on 1, 4-bis(3, 5-dicarboxylicpyrazol-1-ylmethyl) benzene (H₄L), oxalis acid (H₂OX) and lanthanide ions. Compound 1 crystallizes in monoclinic system, space group P2₁/c with a = 9.418(15), b = 15.23(2), c = 14.47(2) Å, β = 100.07(3)°, V = 2044(5) Å³, Z = 4, M_r = 590.3 g/mol, D_c = 1.919 g/cm³, μ = 3.524 mm^-1, F(000) = 1168, R = 0.0893 and wR = 0.1902 for 3486 observed reflections (I > 2σ(I)). In compound 1, the central terbium(Ⅲ) ions are coordinated with eight atoms, and two neighboring terbium(Ⅲ) ions are linked together by one bridging oxalic acid group to give rise to a [Tb₂(OX)(L)₄] unit. Each [Tb₂(OX)(L)₄] unit connects to the surrounding six identical ones by the oxygen atoms bridging to lead to a 3D framework. Compound 1 exhibits strong luminescent emissions at the solid state owing to the antenna effect of the ligand.
- lanthanide-organic frameworks,
- luminescent emission,
- antenna effect
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