Citation: Mei ZHU, Wei-Nan XIE, Mai-E YANG, Feng-Zhen HUA, Guo-Ning ZHANG, Yu-Cheng WANG, Hong ZHAO. One Novel Tetranuclear Copper Cluster by 2-(1H-Pyrazol-3-yl)pyridine: Synthesis, Structure and Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 949-954. doi: 10.14102/j.cnki.0254-5861.2011-2523 shu

One Novel Tetranuclear Copper Cluster by 2-(1H-Pyrazol-3-yl)pyridine: Synthesis, Structure and Properties

  • Corresponding author: Yu-Cheng WANG, wangyucheng@imb.pumc.edu.cn
  • Received Date: 8 July 2019
    Accepted Date: 26 November 2019

    Fund Project: the Jiangsu Ainaji Neoenergy Science & Technology Co., Ltd. 8507040091the Fundamental Research Funds for the Central Universities 3207045420the National Natural Science Foundation of China 81703366

Figures(6)

  • A novel tetranuclear copper cluster [Cu4(μ-L)6Cl2] was constructed by 2-(1H-pyrazol-3-yl) pyridine (HL) under hydrothermal conditions, and structurally concluded by single-crystal X-ray diffractions, elemental analyses and IR spectra. The title complex 1 was of triclinic system, space group P\begin{document}$ \overline 1 $\end{document}, C24H18ClCu2N9, Mr = 595.01, a = 9.6497(13), b = 11.4133(7), c = 13.0919(15) Å, α = 99.166(7), β = 108.707(11), γ = 111.974(9)o, V = 1200.7(2) Å3, Z = 2, Dc = 1.997 g/cm3, F(000) = 706, μ(Mo) = 3.203 mm-1, Rint = 0.0404, R = 0.0536 and wR = 0.1490 for 4890 observed reflections with I > (I). In this structure, complex 1 was the unimolecule with unprecedented tetranuclear cluster, which was expanded into a 2D network by wide-ranging C–H···Cl intermolecular hydrogen bonds and further exhibited a 3D supramolecular architecture based on π-π stacking interactions. In addition, the complex was thermally stable up to 300 ℃ and the solid state fluorescent property of 1 was examined and compared with the ligand.
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