Citation: Mei ZHU, Wei-Nan XIE, Mai-E YANG, Feng-Zhen HUA, Guo-Ning ZHANG, Yu-Cheng WANG, Hong ZHAO. One Novel Tetranuclear Copper Cluster by 2-(1H-Pyrazol-3-yl)pyridine: Synthesis, Structure and Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 949-954. doi: 10.14102/j.cnki.0254-5861.2011-2523 shu

One Novel Tetranuclear Copper Cluster by 2-(1H-Pyrazol-3-yl)pyridine: Synthesis, Structure and Properties

a.
Institute of Medicinal Biotechnology, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100050, China
b.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: Yu-Cheng WANG, wangyucheng@imb.pumc.edu.cn
Received Date: 8 July 2019
Accepted Date: 26 November 2019

Fund Project: the Jiangsu Ainaji Neoenergy Science & Technology Co., Ltd. 8507040091the Fundamental Research Funds for the Central Universities 3207045420the National Natural Science Foundation of China 81703366

Figures(6)

A novel tetranuclear copper cluster [Cu₄(μ-L)₆Cl₂] was constructed by 2-(1H-pyrazol-3-yl) pyridine (HL) under hydrothermal conditions, and structurally concluded by single-crystal X-ray diffractions, elemental analyses and IR spectra. The title complex 1 was of triclinic system, space group P\begin{document}$ \overline 1 $\end{document}, C₂₄H₁₈ClCu₂N₉, M_r = 595.01, a = 9.6497(13), b = 11.4133(7), c = 13.0919(15) Å, α = 99.166(7), β = 108.707(11), γ = 111.974(9)^o, V = 1200.7(2) Å³, Z = 2, D_c = 1.997 g/cm³, F(000) = 706, μ(MoKα) = 3.203 mm^-1, R_int = 0.0404, R = 0.0536 and wR = 0.1490 for 4890 observed reflections with I > 2σ(I). In this structure, complex 1 was the unimolecule with unprecedented tetranuclear cluster, which was expanded into a 2D network by wide-ranging C–H···Cl intermolecular hydrogen bonds and further exhibited a 3D supramolecular architecture based on π-π stacking interactions. In addition, the complex was thermally stable up to 300 ℃ and the solid state fluorescent property of 1 was examined and compared with the ligand.
- 2-(1H-pyrazol-3-yl)pyridine,
- tetranuclear copper cluster,
- fluorescent property
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