Citation: Jun-Yi LI, Xiang CHEN, Qiang-Qiang JIA, Hong-Fei LU, Shao-Jun ZHENG, Li-Zhuang CHEN. A Novel Organic-inorganic Hybrid Phase Transition Compound with Switchable Dielectric Property[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 889-894. doi: 10.14102/j.cnki.0254-5861.2011-2517 shu

A Novel Organic-inorganic Hybrid Phase Transition Compound with Switchable Dielectric Property

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Li-Zhuang CHEN, clz1977@sina.com
Received Date: 3 July 2019
Accepted Date: 14 October 2019

Figures(6)

A novel organic-inorganic hybrid phase transition compound [(C₃H₇)₂dabco]CoBr₄ with switchable dielectric property is synthesized, and the phase transition behavior was measured by DSC measurements. The DSC curves display a pair of endothermic and exothermic peaks at 230 and 212 K, confirming a reversible first-order phase transition by the calculation of entropy change and the 18 K thermal hysteresis. The structural change from P4₂/m at room-temperature to P4₂ at 100 K accompanied by a deletion of mirror plane m was determined by variable temperature single-crystal X-ray diffractions. Furthermore, switchable step-like dielectric anomalies can be observed around 230 K by the real part of dielectric constant curves. The 10-fold difference of ε' between high ε' and low ε' states make compound 1 a potential candidate for sensor and detection devices at appropriate temperature and frequencies.
- phase transition,
- switchable dielectric
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