Citation: Sa-Ying LI. Synthesis, Structures, and Fluorescence Property of a Novel Heterometallic Complex Constructed by Imidazole[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 942-948. doi: 10.14102/j.cnki.0254-5861.2011-2513 shu

Synthesis, Structures, and Fluorescence Property of a Novel Heterometallic Complex Constructed by Imidazole

Sa-Ying LI ^,

Department of Chemistry Chemical Engineering, Shaanxi Xueqian Normal University, Xi′an 710100, China

Corresponding author: Sa-Ying LI, lisayinglisaying@163.com
Received Date: 26 June 2019
Accepted Date: 22 October 2019

Fund Project: the Scientific Research Project of Education Department of Shaanxi Province 18JK0190

Figures(11)

A novel heterometallic complex constructed by imidazole ligand, CoZn(C₃N₂H₃)₄ (1), has been synthesized under hydrothermal conditions. Compound 1 was characterized by IR spectra, thermal analysis, powder X-ray diffraction and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveals that compound 1 is in the tetragonal system, space group I4₁cd with a = 23.4371(5), b = 23.4371(5), c = 12.4430(7) Å, V = 6834.9(4) Å³, Z = 16, C₁₂H₁₂CoN₈Zn, M_r = 392.60, D_c = 1.526 g/cm³, F(000) = 3152, μ = 2.381 mm^-1, R = 0.0323 and wR = 0.0789. The CoZn(C₃N₂H₃)₄ is one-dimensional heterometallic molecular chains, which are further extended into a 3D open framework. Moreover, the solid-state fluorescence property of the complex has also been investigated at room temperature.
- heterometallic complex,
- crystal structure,
- fluorescence property
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