Citation: Ling-Yun XIN, Xiao-Ling LI, Wei-Dong YIN, Guang-Zhen LIU. Two Carboxylato-bridged Binuclear Cobalt(Ⅱ) Complexes Pillared Coligands: Synthesis, Structures and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 933-941. doi: 10.14102/j.cnki.0254-5861.2011-2503 shu

Two Carboxylato-bridged Binuclear Cobalt(Ⅱ) Complexes Pillared Coligands: Synthesis, Structures and Magnetic Properties

a.
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China
b.
School of Food and Drug, Luoyang Normal University, Luoyang, Henan 471934, China

Corresponding author: Guang-Zhen LIU, gzliuly@126.com
Received Date: 20 June 2019
Accepted Date: 12 October 2019

Fund Project: the National Natural Science Foundation of China 21571093Colleges and Universities Key Scientific Research Project of Henan Province 18B150016

Figures(6)

By adopting mixed-ligand strategy, two Co(Ⅱ) coordination polymers, [Co(phda)(itmb)(H₂O)₂]_n (1) and [Co(phda)(Hpytz)]_n (2) (H₂phda = 1, 2-phenylenediacetate, itmb = 1-(imidazo-1-ly)-4-(1, 2, 4-triazol-1-yl methyl) benzene and Hpytz = 3, 5-di(4-pyridyl)-1, 2, 4-triazolate), were hydrothermally synthesized and then characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. The single-crystal X-ray diffraction reveals that two complexes feature carboxylato-bridged binuclear subunits extended further by the nitrogen-rich coligands to form different structures. Complex 1 containing phda-bridged binuclear cobalt is developed by itmb coligand to 1D double-stranded chain, whereas complex 2 exhibits 2D open bilayers, which result from the ribbon-like carboxylate chains pillared Hpytz coligands. In addition, the magnetic susceptibilities of both compounds were measured over the temperature range of 3~300 K, and the data were analyzed well using MagSaki software. The best fitting parameters were κ = 0.98, λ = −100 cm^-1, ∆ = 588 cm^-1 and J = 0.6 cm^-1 for complex 1 and κ = 0.86, λ = −110 cm^-1, ∆ = 756.8 cm^-1 and J = −1.25 cm^-1 for complex 2. The results indicate the existence of weaker ferromagnetic interaction for complex 1 and antiferromagnetic interaction for complex 2 between the metal centers in the dinuclear metal units.
- mixed-ligand,
- complexes,
- synthesis,
- structures,
- magnetic properties
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