Two Carboxylato-bridged Binuclear Cobalt(Ⅱ) Complexes Pillared Coligands: Synthesis, Structures and Magnetic Properties
- Corresponding author: Guang-Zhen LIU, gzliuly@126.com
Citation:
Ling-Yun XIN, Xiao-Ling LI, Wei-Dong YIN, Guang-Zhen LIU. Two Carboxylato-bridged Binuclear Cobalt(Ⅱ) Complexes Pillared Coligands: Synthesis, Structures and Magnetic Properties[J]. Chinese Journal of Structural Chemistry,
;2020, 39(5): 933-941.
doi:
10.14102/j.cnki.0254-5861.2011-2503
Kurmoo, M. Magnetic metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1353–1379.
doi: 10.1039/b804757j
Nandi, S.; Collins, S.; Chakraborty, D.; Banerjee, D.; Thallapally, P. K.; Woo, T. K.; Vaidhyanathan, R. Ultralow parasitic energy for postcombustion CO2 capture realized in a nickel isonicotinate metal-organic framework with excellent moisture stability. J. Am. Chem. Soc. 2017, 139, 1734–1737.
doi: 10.1021/jacs.6b10455
Liu, J. Q.; Wang, W. J.; Luo, Z. D.; Li, B. H.; Yuan, D. Q. Microporous metal-organic framework based on ligand-truncation strategy with high performance for gas adsorption and separation. Inorg. Chem. 2017, 56, 10215–10219.
doi: 10.1021/acs.inorgchem.7b00851
Lian, X.; Yan, B. Phosphonate MOFs composite as off-on fluorescent sensor for detecting purine metabolite uric acid and diagnosing hyperuricuria. Inorg. Chem. 2017, 56, 6802–6808.
doi: 10.1021/acs.inorgchem.6b03009
Zhao, Y.; Deng, D. S.; Ma, L. F.; Ji, B. M.; Wang, L. Y. A new copper-based metal-organic framework as a promising heterogeneous catalyst for chemo-and regio-selective enamination of b-ketoesters. Chem. Commun. 2013, 49, 10299–10301.
doi: 10.1039/c3cc45310c
Rocca, J. D.; Liu, D. M.; Lin, W. B. Nanoscale metal-organic frameworks for biomedical imaging and drug delivery. Acc. Chem. Res. 2011, 44, 957–968.
doi: 10.1021/ar200028a
Liu, S. J.; Han, S. D.; Zhao, J. P.; Xu, J.; Bu, X. H. In-situ synthesis of molecular magnetorefrigerant materials. Coord. Chem. Rev. 2019, 394, 39–52.
doi: 10.1016/j.ccr.2019.05.009
Maruyama, T.; Kikukawa, Y.; Sakiyama, H.; Katayama, M.; Inada, Y.; Hayashi, Y. A highly-flexible cyclic-decavanadate ligand for interconversion of dinuclear-and trinuclear cobalt(Ⅱ) and manganese(Ⅱ) cores. RSC Adv. 2017, 7, 37666–37674.
doi: 10.1039/C7RA05941H
Gadzikwa, T.; Farha, O. K.; Malliakas, C. D.; Kanatzidis, M. G.; Hupp, J. T.; Nguyen, S. T. Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry. J. Am. Chem. Soc. 2009, 131, 13613–13615.
doi: 10.1021/ja904189d
Zhuang, W. J.; Sun, H. L.; Xu, H. B.; Wang, Z. M.; Gao, S.; Jin, L. P. Reversible de-/resolvation and accompanied magnetism modulation in a framework of topologically ferrimagnetic [Co3(μ3-OH)2]n chains linked by a V-shaped ligand 4, 4΄-dicarboxybiphenyl sulfone. Chem. Commun. 2010, 46, 4339–4341.
doi: 10.1039/c002426k
Cheng, J. W.; Zheng, S. T.; Yang, G. Y. Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction. Dalton Trans. 2007, 4059–4066.
Liu, G. Z.; Li, S. H.; Wang, L. Y. Five M(Ⅱ) coordination polymers assembled from various polynuclear units spaced by semirigid carboxyphenylpropionate and N-donor coligand. CrystEngComm. 2012, 14, 880–889.
doi: 10.1039/C1CE05926B
Xin, L. Y.; Liu, G. Z.; Ma, L. F.; Li, G. L.; Wang, L. Y. Guest water-controlled reversible crystalline-to-amorphous transition and concomitant fluorescence shift in a polar open coordination polymer. Inorg. Chim. Acta 2016, 443, 64–68.
doi: 10.1016/j.ica.2015.12.022
Liu, T. F.; Lü, J.; Cao, R. Coordination polymers based on flexible ditopic carboxylate or nitrogen-donor ligands. CrystEngComm. 2010, 12, 660–670.
doi: 10.1039/B914145F
Liu, G. Z.; Li, X. D.; Xin, L. Y.; Li, X. L.; Wang, L. Y. J. Diverse assemblies of the (4, 4) grid layers exemplified in Zn(Ⅱ)/Co(Ⅱ) coordination polymers with dual linear ligands. J. Solid State Chem. 2013, 203, 106–113.
doi: 10.1016/j.jssc.2013.03.053
Ju, F. Y.; Li, Y. P.; Li, G. L.; Liu, G. Z.; Xin, L. Y.; Li, X. L. Zinc(Ⅱ) and cadmium(Ⅱ) coordination polymers with various polynuclears spaced by semirigid 4-carboxybenzeneacetate and nitrogen-rich co-ligands: syntheses, structures and properties. Chin. J. Inorg. Chem. 2016, 32, 1876–1884.
Huang, K. L.; Liu, X.; Li, J. K. Three-dimensional metal(Ⅱ)-organic coordination polymers from binuclear, trinuclear and polynuclear clusters bridged by p-benzenediacrylates: syntheses, topologies, photosensitive properties and hydrogen uptake. Cryst. Growth Des. 2010, 10, 1508–1515.
doi: 10.1021/cg900579s
Ju, F. Y.; Li, Y. P.; Li, G. L.; Liu, G. Z. Syntheses, crystal structures, and magnetic properties of cobalt(Ⅱ) cmplexes with 1, 1-cyclohexanediacetic acid. Chin. J. Struct. Chem. 2016, 35, 404–412.
Xin, L. Y.; Liu, G. Z.; Ma, L. F.; Zhang, X.; Wang, L. Y. Structural diversity and fluorescence regulation of three ZnⅡ coordination polymers assembled from mixed ligands tectons. Aust. J. Chem. 2015, 68, 758–765.
doi: 10.1071/CH14347
Xin, L. Y.; Liu, G. Z.; Wang, L. Y. New coordination polymers from 1D chain, 2D layer to 3D framework constructed from 1, 2-phenylene diacetic acid and 1, 3-bis(4-pyridyl)propane flexible ligands. J. Solid State Chem. 2011, 184, 1387–1392.
doi: 10.1016/j.jssc.2011.04.002
Xin, L. Y.; Liu, G. Z.; Li, X. L.; Wang, L. Y. Structural diversity for a series of metal(Ⅱ) complexes based on flexible 1, 2-phenylenediacetate and dipyridyl-type coligand. Cryst. Growth Des. 2012, 12, 147–157.
doi: 10.1021/cg200903k
Kang, W. C.; Li, Y. H.; Qin, Z. B.; Cui, G. H. Synthesis, structures and characterization of two cobalt(Ⅱ) coordination polymers with 2, 5‑dichloroterephthalic acid and fexible bis(benzimidazole) ligands. Transit. Metal Chem. 2018, 43, 563–570.
doi: 10.1007/s11243-018-0242-4
Kang, H. X.; Fu, Y. Q.; Xin, L. Y.; Li, G. L.; Ma, L. F.; Liu, G. Z. Two coordination polymers containing linear Co(Ⅱ)-trinuclear and Cu(Ⅱ)-chain assembled from 4-fluorocinnamic acid and N-donor ligand. Chin. J. Struct. Chem. 2016, 35, 286–292.
Pasán, J.; Sanchiz, J.; Fabelo, Ó.; Delgado, L. C.; Déniz, M.; Gallifa, P. D.; Benito, C. M.; Lloret, F.; Julve, M.; Pérez, C. R. Influence of the coligand in the magnetic properties of a series of copper(Ⅱ)-phenylmalonate complexes. CrystEngComm. 2014, 16, 8106–8118.
doi: 10.1039/C4CE00834K
Xin, L. Y.; Ju, F. Y.; Li, X. L.; Liu, G. Z. Thermal stabilities and crystal structures of two supramolecular microporous frameworks based on carboxylate-dipyridyl mix-ligands. Russ. J. Coord. Chem. 2017, 43, 55–62.
doi: 10.1134/S1070328417010080
Liu, G. Z.; Li, S. H.; Li, X. L.; Xin, L. Y.; Wang, L. Y. Three series of MOFs featuring various metal(Ⅱ)-carboxylate chains cross-linked by dipyridyl-typed coligands: synthesis, structure, and solvent-dependent luminescence. CrystEngComm. 2013, 15, 4571–4580.
doi: 10.1039/c3ce40109j
Li, X. L.; Liu, G. Z.; Xin, L. Y.; Wang, L. Y. Binuclear and tetranuclear Mn(Ⅱ) clusters in coordination polymers derived from semirigid tetracarboxylate and N‑donor ligands: syntheses, new topology structures and magnetism. J. Solid State Chem. 2017, 246, 252–257.
doi: 10.1016/j.jssc.2016.11.030
Liu, G. C.; Yu, H. X.; Lin, H. Y.; Wang, X. L.; Li, X. W. Spacers-induced structural diversity of cobalt coordination polymers based on "V"-type dipyridylamide and dicarboxylic ligands: fluorescent, magnetic and photocatalytic properties. Polyhedron 2017, 126, 205–213.
doi: 10.1016/j.poly.2017.01.022
Chen, Z. W.; Mi, X. N.; Lu, J.; Wang, S. N.; Li, Y. W.; Dou, J. M.; Li, D. C. From 2D-3D interpenetration to packing: N coligand-driven structural assembly and tuning of luminescent sensing activities towards Fe3+ and Cr2O72− ions. Dalton Trans. 2018, 47, 6240–6249.
doi: 10.1039/C8DT00909K
Sakiyama, H. Development of MagSaki software for magnetic analysis of dinuclear high-spin cobalt(Ⅱ) complexes in an axially distorted octahedral field. J. Chem. Soft. 2001, 7, 171–178.
doi: 10.2477/jchemsoft.7.171
Sheldrick, G. M. A Program for the Siemens Area Detector Absorption Correction. University of Göttingen, Germany 1997.
Spek, A. L. PLATON, A Multi-purpose Crystallographic Tool. Utrecht (Netherlands): Utrecht University 2001.
Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Gottingen, Göttingen, Germany 1997.
Sheldrick, G. M. SHELXL-97, Program for Refinement of Crystal Structures. University of Gottingen, Göttingen, Germany 1997.
Huang, F. P.; Tian, J. L.; Gu, W.; Liu, X.; Yan, S. P.; Liao, D. Z.; Cheng, P. Co(Ⅱ) coordination polymers: positional isomeric effect, structural and magnetic diversification. Cryst. Growth Des. 2010, 10, 1145–1154.
doi: 10.1021/cg901014r
Sakiyama, H.; Ito, R.; Kumagai, H.; Inoue, K.; Sakamoto, M.; Nishida, Y.; Yamasaki, M. Dinuclear cobalt(Ⅱ) complexes of an acyclic phenol-based dinucleating ligand with four methoxyethyl chelating arms first magnetic analyses in an axially distorted octahedral field. Eur. J. Inorg. Chem. 2001, 2027–2032.
Hossain, M. J.; Yamasaki, M.; Mikuriya, M.; Kuribayashi, A.; Sakiyama, H. Synthesis, structure, and magnetic properties of dinuclear cobalt(Ⅱ) complexes with a new phenol-based dinucleating ligand with four hydroxyethyl chelating arms. Inorg. Chem. 2002, 41, 4058–4062.
doi: 10.1021/ic0255297
Sakamoto, M.; Nishida, Y.; Yamasaki, M. Dinuclear cobalt(Ⅱ) complexes of an acyclic phenol-based dinucleating ligand with four methoxyethyl chelating arms first magnetic analyses in an axially distorted octahedral field. Eur. J. Inorg. Chem. 2001, 2705.
Wang, L.; Gu, W.; Deng, J. X.; Liu, M. L.; Xu, N.; Liu, X. Syntheses, structures, and photoluminescent and magnetic properties of four novel complexes constructed from 2, 4, 5-tri(4-pyridyl)-imidazole and benzene-1, 3, 5-tricarboxylic acid. Z. Anorg. Allg. Chem. 2010, 636, 1124–1128.
doi: 10.1002/zaac.200900436
Li, X. J.; Guan, T. N.; Guo, X. F.; Li, X. X.; Yu, Z. J. Construction of metal-organic frameworks consisting of dinuclear metal units based on 5-hydroxyisophthalate and flexible dipyridyl ligands. Eur. J. Inorg. Chem. 2014, 2307–2316.
Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
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Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
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