Citation: Xu-Min CAI, Xin-Fei CHEN, Xue-Dan ZHANG, Yuan HUANG, Wen GU, Fei WANG. Syntheses, Crystal Structures, and Electrochemical Properties of Three Anhydrides Based on Ferrocenecarboxylic Acid and Dehydroabietic Acid[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 579-587. doi: 10.14102/j.cnki.0254-5861.2011-2472 shu

Syntheses, Crystal Structures, and Electrochemical Properties of Three Anhydrides Based on Ferrocenecarboxylic Acid and Dehydroabietic Acid

College of Chemical Engineering, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest Biomass, Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: Xu-Min CAI, xumin.cai@njfu.edu.cn
Received Date: 27 May 2019
Accepted Date: 29 August 2019

Fund Project: the National Natural Science Foundation of China 21601087the Topnotch Academic Programs Project TAPPthe Priority Academic Program Development of Jiangsu Higher Education Institution PAPD

Figures(4)

Three title compounds (3~5) have been successfully synthesized via interactive reactions between ferrocenecarboxylic and dehydroabietic acids, which can be characterized by FT-IR, elemental analysis, ESI-MS, and NMR spectroscopy. The crystal structures of compounds 4 and 5 can be determined by single-crystal X-ray diffraction. Compound 4 is of orthorhombic system, space group P2₁2₁2₁ with a = 7.7010(5), b = 11.7542(9), c = 28.3173(18) Å, Z = 4, V = 2563.3(3) Å³, M_r = 512.45, D_c = 1.328 g/cm^-1, S = 1.041, μ = 0.619 mm^-1, F(000) = 1088, the final R = 0.0396 and wR = 0.0945 for 4394 observed reflections (I > 2σ(I)). Compound 5 crystallizes in orthorhombic system, space group P2₁2₁2 as well, with parameters of a = 11.9875(15), b = 19.651(2), c = 7.2163(9) Å, Z = 2, V = 1699.9(3) Å³, M_r = 582.83, D_c = 1.139 g/cm^-1, S = 1.091, μ = 0.070 mm^-1, F(000) = 636, the final R = 0.0653 and wR = 0.0719 for 1518 observed reflections (I > 2σ(I)). Additionally, electrochemical properties of compounds 3 and 4 have been investigated by the cyclic and differential pulse voltammogram techniques.
- dehydroabietic acid,
- anhydride,
- crystal structure,
- electrochemical properties
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