Citation: Bin WANG, Ting-Hai MU, Jun-Rong LING, You-Fu ZHOU, Wen-Tao XU, He LIN. Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 511-518. doi: 10.14102/j.cnki.0254-5861.2011-2452 shu

Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs

Bin WANG ^{a, b} ,
Ting-Hai MU ^{a, b} ,
Jun-Rong LING ^{a, b} ,
You-Fu ZHOU ^a,, ,
Wen-Tao XU ^a ,
He LIN ^a

a.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: You-Fu ZHOU, yfzhou@fjirsm.ac.cn
Received Date: 9 May 2019
Accepted Date: 27 June 2019

Fund Project: the grants of CAS Priority Research program XDB20010300the grants of CAS Priority Research program XDA21010204Natural Science Foundation of Fujian Province 2017H0048

Figures(11)

A series of Bi³⁺-doped YAG: Ce³⁺, Mn²⁺ ceramics was synthesized successfully by gel-casting method and structurally characterized by XRD and SEM. The doping effect and related mechanism of Bi³⁺ upon the luminescent property were studied. It can be assigned to the energy transfer of multipolar interaction from Bi³⁺ to Ce³⁺, leading to the improvement of emission intensity about 58% for 0.0001 Bi³⁺ and 0.05 Mn²⁺ doping. In addition, the emission is significantly red-shifted with the peak at 590 nm for the Y_2.9939Ce_0.006Bi_0.0001Al_4.96Mn_0.02Si_0.02O₁₂ ceramic specimen with in-line transmittance 81.6% at 1100 nm. The LED module assembled from Y_2.9939Ce_0.006Bi_0.0001Al_4.96Mn_0.02Si_0.02O₁₂ ceramic owns correlated color temperature (CCT) of 3960 K and luminous efficiency (LE) of 92 lm/W, implying that doping Bi³⁺ shows a good sensitization effect in the YAG: Ce³⁺, Mn²⁺ ceramic system and further serving as an attracting phosphor candidates for warm WLEDs applications.
- Bi³⁺ doping,
- gel-casting method,
- phosphor ceramic,
- microstructure,
- luminescent property
1. [1]
  Sun, Y.; Qin, X. P.; Zhou, G. H.; Zhang, H. L.; Peng, X.; Wang, S. W. Gelcasting and reactive sintering of sheet-like YAG transparent ceramics. J. Alloys Comp. 2015, 652, 250–253. doi: 10.1016/j.jallcom.2015.08.212
2. [2]
  Ikesue, A.; Kinoshita, T.; Kamata, K.; Yoshida, K. Fabrication and optical-properties of high-performance polycrystalline Nd: YAG ceramics for solid-state lasers. J. Am. Ceram. Soc. 1995, 78, 1033–1040. doi: 10.1111/j.1151-2916.1995.tb08433.x
3. [3]
  Tachiwaki, T.; Yoshinaka, M.; Hirota, K.; Ikegami, T.; Yamaguchi, O. Novel synthesis of Y₃Al₅O₁₂ (YAG) leading to transparent ceramics. Solid State Commun. 2001, 119, 603–606. doi: 10.1016/S0038-1098(01)00293-9
4. [4]
  Jiang, L. I.; Yusong, W. U.; Yubai, P. A. N.; Yong, Z. H. U.; Jingkun, G. U. O. Spectroscopic properties of Cr⁴⁺, Nd³⁺: YAG transparent ceramics for self-Q-switched laser. Chin. J. Lumin. 2007, 28, 219–224.
5. [5]
  Wu, Y. S.; Li, J.; Pan, Y. B.; Guo, J. K.; Jiang, B. X.; Xu, Y.; Xu, J. Diode-pumped Yb: YAG ceramic laser. J. Am. Ceram. Soc. 2007, 90, 3334–3337. doi: 10.1111/j.1551-2916.2007.01885.x
6. [6]
  Huie, J. C.; Dudding, C. B.; McCloy, J. Polycrystalline yttrium aluminum Garnet (YAG) for IR transparent missile domes and windows. Proc. of SPIE 2007, 6545: 65450E1–65450E12. doi: 10.1117/12.740783
7. [7]
  Zhang, W. X.; Pan, Y. B.; Zhou, J.; Liu, W. B.; Li, J.; Jiang, B. X.; Cheng, X. J.; Xu, J. Q. Diode-pumped Tm: YAG ceramic laser. J. Am. Ceram. Soc. 2009, 92, 2434–2437. doi: 10.1111/j.1551-2916.2009.03220.x
8. [8]
  Zhang, M.; Liang, Y.; Tang, R.; Yu, D.; Tong, M.; Wang, Q.; Zhu, Y.; Wu, X.; Li, G. Highly efficient Sr₃Y₂(Si₃O₉)₂: Ce³⁺, Tb³⁺/Mn²⁺/Eu²⁺ phosphors for white LEDs: structure refinement, color tuning and energy transfer. RSC Adv. 2014, 4, 40626–40637. doi: 10.1039/C4RA06538G
9. [9]
  Silveira, L. G. D.; Cotica, L. F.; Santos, I. A.; Belancon, M. P.; Rohling, J. H.; Baesso, M. L. Processing and luminescence properties of Ce: Y₃Al₅O₁₂ and Eu: Y₃Al₅O₁₂ ceramics for white-light applications. Mater. Lett. 2012, 89, 86–89. doi: 10.1016/j.matlet.2012.08.106
10. [10]
  Samuel, P.; Kumar, G. A.; Yanagitani, T.; Yagi, H.; Ueda, K. I.; Babu, S. M. Efficient energy transfer between Ce³⁺/Cr³⁺ and Nd³⁺ ions in transparent Nd/Ce/Cr: YAG ceramics. Opt. Mater. 2011, 34, 303–307. doi: 10.1016/j.optmat.2011.09.002
11. [11]
  Liu, J.; Sun, J.; Shi, C. The development of the white converter based on LED. Chemistry 2005, 68, 417–424.
12. [12]
  Setlur, A. A.; Heward, W. J.; Gao, Y.; Srivastava, A. M.; Chandran, R. G.; Shankar, M. V. Crystal chemistry and luminescence of Ce³⁺-doped Lu₂CaMg₂(Si, Ge)₃O₁₂ and its use in LED based lighting. Chem. Mater. 2006, 18, 3314–3322. doi: 10.1021/cm060898c
13. [13]
  Suehiro, T.; Hirosaki, N.; Xie, R. J. Synthesis and photoluminescent properties of (La, Ca)₃Si₆N₁₁: Ce³⁺ fine powder phosphors for solid-state lighting. Acs Appl. Mater. Inter. 2011, 3, 811–816. doi: 10.1021/am101160e
14. [14]
  Zhu, H.; Lin, C. C.; Luo, W.; Shu, S.; Liu, Z.; Liu, Y.; Kong, J.; Ma, E.; Cao, Y.; Liu, R. S.; Chen, X. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes. Nature Commun. 2014, 5, 1–10.
15. [15]
  Guo, N.; Huang, Y. J.; You, H. P.; Yang, M.; Song, Y. H.; Liu, K.; Zheng, Y. H. Ca₉Lu(PO₄)₇: Eu²⁺, Mn²⁺: a potential single-phased white-light-emitting phosphor suitable for white-light-emitting diodes. Inorg. Chem. 2010, 49, 10907–10913. doi: 10.1021/ic101749g
16. [16]
  Omatete, O. O.; Janney, M. A.; Strehlow, R. A. Gelcasting - a new ceramic forming process. Am. Ceram. Soc. Bull. 1991, 70, 1641–1649.
17. [17]
  Omatete, O. O.; Janney, M. A.; Nunn, S. D. Gelcasting: from laboratory development toward industrial production. J. Eur. Ceram. Soc. 1997, 17, 407–413. doi: 10.1016/S0955-2219(96)00147-1
18. [18]
  Yang, J.; Yu, J.; Huang, Y. Recent developments in gelcasting of ceramics. J. Eur. Ceram. Soc. 2011, 31, 2569–2591. doi: 10.1016/j.jeurceramsoc.2010.12.035
19. [19]
  Que, M.; Que, W.; Zhou, T.; Shao, J.; Kong, L. Photoluminescence and energy transfer of YAG: Ce³⁺, Gd³⁺, Bi³⁺. J. Adv. Dielectr. 2016, 06, 1650029-1-1650029-6. doi: 10.1142/S2010135X16500296
20. [20]
  Nguyen Huu Khanh, N.; Tran Hoang Quang, M.; Nguyen, T. N.; Voznak, M. Bi-layers red-emitting Sr₂Si₅N₈: Eu²⁺ phosphor and yellow-emitting YAG: Ce phosphor: a new approach for improving the color rendering index of the remote phosphor packaging WLEDs. Curr. Opt. Photonics 2017, 1, 613–617.
21. [21]
  Sun, X. W.; Tan, J.; Li, C. M.; Lei, T.; Meng, X. K.; Yan, W.; Zhang, W.; Feng, S. Doping effects of Sb, Bi, Zr and Si on the properties of YAG: Ce phosphor. Chin. J. Inorg. Chem. 2013, 29, 1863–1869.
22. [22]
  Zorenko, Y.; Gorbenko, V.; Savchyn, V.; Zorenko, T.; Nikl, M.; Mares, J. A.; Beitlerova, A.; Jary, V. Bi³⁺-Pr³⁺ energy transfer processes and luminescent properties of LuAG: Bi, Pr and YAG: Bi, Pr single crystalline films. J. Lumin. 2013, 141, 137–143. doi: 10.1016/j.jlumin.2013.03.036
23. [23]
  Wei, N. A.; Guan, Y. B.; Wu, H. J.; Lu, Z. W.; Chen, X. T.; Zhao, Y.; Qi, J. Q.; Lu, T. C.; Zhang, W.; Ma, B. Y. Fabrication of Yb³⁺-doped YAG transparent ceramics by aqueous gelcasting. J. Sol-Gel Sci. Technol. 2016, 77, 211–217. doi: 10.1007/s10971-015-3846-6
24. [24]
  Jia, Y. C.; Huang, Y. J.; Zheng, Y. H.; Guo, N.; Qiao, H.; Zhao, Q.; Lv, W. Z.; You, H. P. Color point tuning of Y₃Al₅O₁₂: Ce³⁺ phosphor via Mn²⁺-Si⁴⁺ incorporation for white light generation. J. Mater. Chem. 2012, 22, 15146–15152. doi: 10.1039/c2jm32233a
25. [25]
  Bonin, K. D.; Kadarkallen, M. A. Linear electric-dipole polarizabilities. Int. J. Mod. Phys. 1994, 8, 3313–3370. doi: 10.1142/S0217979294001391
26. [26]
  Noginov, M. A.; Loutts, G. B.; Warren, M. Spectroscopic studies of Mn³⁺ and Mn²⁺ ions in YAlO₃. J. Opt. Soc. Am. B 1999, 16, 475–483.
27. [27]
  Gedam, S. C.; Dhoble, S. J.; Moharil, S. V. Dy³⁺ and Mn²⁺ emission in KMgSO₄Cl phosphor. J. Lumin. 2007, 124, 120–126. doi: 10.1016/j.jlumin.2006.02.016
28. [28]
  Zhang, Z. M.; Liang, X. J.; Zhao, B. Y.; Chen, Z. P.; Liu, B. F.; Zhong, J. S.; Xiang, W. D.; Lu, C. Y. Growth and luminescence properties of Ce, Mn: YAG single crystal. Chem. Chem. J. Chin. U. 2013, 34, 1826–1832.
29. [29]
  Shi, Y. R.; Wang, Y. H.; Wen, Y.; Zhao, Z. Y.; Liu, B. T.; Yang, Z. G. Tunable luminescence Y₃Al₅O₁₂: 0.06Ce³⁺, xMn²⁺ phosphors with different charge compensators for warm white light emitting diodes. Opt. Express 2012, 20, 21656–21664. doi: 10.1364/OE.20.021656
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Doping Effect of Bi3+ on the Properties of YAG: Ce3+, Mn2+ Phosphor Ceramics for Warm WLEDs

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Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs