Citation: Bin WANG, Ting-Hai MU, Jun-Rong LING, You-Fu ZHOU, Wen-Tao XU, He LIN. Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 511-518. doi: 10.14102/j.cnki.0254-5861.2011-2452 shu

Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs

Bin WANG ^{a, b} ,
Ting-Hai MU ^{a, b} ,
Jun-Rong LING ^{a, b} ,
You-Fu ZHOU ^a,, ,
Wen-Tao XU ^a ,
He LIN ^a

a.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: You-Fu ZHOU, yfzhou@fjirsm.ac.cn
Received Date: 9 May 2019
Accepted Date: 27 June 2019

Fund Project: the grants of CAS Priority Research program XDB20010300the grants of CAS Priority Research program XDA21010204Natural Science Foundation of Fujian Province 2017H0048

Figures(11)

A series of Bi³⁺-doped YAG: Ce³⁺, Mn²⁺ ceramics was synthesized successfully by gel-casting method and structurally characterized by XRD and SEM. The doping effect and related mechanism of Bi³⁺ upon the luminescent property were studied. It can be assigned to the energy transfer of multipolar interaction from Bi³⁺ to Ce³⁺, leading to the improvement of emission intensity about 58% for 0.0001 Bi³⁺ and 0.05 Mn²⁺ doping. In addition, the emission is significantly red-shifted with the peak at 590 nm for the Y_2.9939Ce_0.006Bi_0.0001Al_4.96Mn_0.02Si_0.02O₁₂ ceramic specimen with in-line transmittance 81.6% at 1100 nm. The LED module assembled from Y_2.9939Ce_0.006Bi_0.0001Al_4.96Mn_0.02Si_0.02O₁₂ ceramic owns correlated color temperature (CCT) of 3960 K and luminous efficiency (LE) of 92 lm/W, implying that doping Bi³⁺ shows a good sensitization effect in the YAG: Ce³⁺, Mn²⁺ ceramic system and further serving as an attracting phosphor candidates for warm WLEDs applications.
- Bi³⁺ doping,
- gel-casting method,
- phosphor ceramic,
- microstructure,
- luminescent property
1. [1]
  Sun, Y.; Qin, X. P.; Zhou, G. H.; Zhang, H. L.; Peng, X.; Wang, S. W. Gelcasting and reactive sintering of sheet-like YAG transparent ceramics. J. Alloys Comp. 2015, 652, 250–253. doi: 10.1016/j.jallcom.2015.08.212
2. [2]
  Ikesue, A.; Kinoshita, T.; Kamata, K.; Yoshida, K. Fabrication and optical-properties of high-performance polycrystalline Nd: YAG ceramics for solid-state lasers. J. Am. Ceram. Soc. 1995, 78, 1033–1040. doi: 10.1111/j.1151-2916.1995.tb08433.x
3. [3]
  Tachiwaki, T.; Yoshinaka, M.; Hirota, K.; Ikegami, T.; Yamaguchi, O. Novel synthesis of Y₃Al₅O₁₂ (YAG) leading to transparent ceramics. Solid State Commun. 2001, 119, 603–606. doi: 10.1016/S0038-1098(01)00293-9
4. [4]
  Jiang, L. I.; Yusong, W. U.; Yubai, P. A. N.; Yong, Z. H. U.; Jingkun, G. U. O. Spectroscopic properties of Cr⁴⁺, Nd³⁺: YAG transparent ceramics for self-Q-switched laser. Chin. J. Lumin. 2007, 28, 219–224.
5. [5]
  Wu, Y. S.; Li, J.; Pan, Y. B.; Guo, J. K.; Jiang, B. X.; Xu, Y.; Xu, J. Diode-pumped Yb: YAG ceramic laser. J. Am. Ceram. Soc. 2007, 90, 3334–3337. doi: 10.1111/j.1551-2916.2007.01885.x
6. [6]
  Huie, J. C.; Dudding, C. B.; McCloy, J. Polycrystalline yttrium aluminum Garnet (YAG) for IR transparent missile domes and windows. Proc. of SPIE 2007, 6545: 65450E1–65450E12. doi: 10.1117/12.740783
7. [7]
  Zhang, W. X.; Pan, Y. B.; Zhou, J.; Liu, W. B.; Li, J.; Jiang, B. X.; Cheng, X. J.; Xu, J. Q. Diode-pumped Tm: YAG ceramic laser. J. Am. Ceram. Soc. 2009, 92, 2434–2437. doi: 10.1111/j.1551-2916.2009.03220.x
8. [8]
  Zhang, M.; Liang, Y.; Tang, R.; Yu, D.; Tong, M.; Wang, Q.; Zhu, Y.; Wu, X.; Li, G. Highly efficient Sr₃Y₂(Si₃O₉)₂: Ce³⁺, Tb³⁺/Mn²⁺/Eu²⁺ phosphors for white LEDs: structure refinement, color tuning and energy transfer. RSC Adv. 2014, 4, 40626–40637. doi: 10.1039/C4RA06538G
9. [9]
  Silveira, L. G. D.; Cotica, L. F.; Santos, I. A.; Belancon, M. P.; Rohling, J. H.; Baesso, M. L. Processing and luminescence properties of Ce: Y₃Al₅O₁₂ and Eu: Y₃Al₅O₁₂ ceramics for white-light applications. Mater. Lett. 2012, 89, 86–89. doi: 10.1016/j.matlet.2012.08.106
10. [10]
  Samuel, P.; Kumar, G. A.; Yanagitani, T.; Yagi, H.; Ueda, K. I.; Babu, S. M. Efficient energy transfer between Ce³⁺/Cr³⁺ and Nd³⁺ ions in transparent Nd/Ce/Cr: YAG ceramics. Opt. Mater. 2011, 34, 303–307. doi: 10.1016/j.optmat.2011.09.002
11. [11]
  Liu, J.; Sun, J.; Shi, C. The development of the white converter based on LED. Chemistry 2005, 68, 417–424.
12. [12]
  Setlur, A. A.; Heward, W. J.; Gao, Y.; Srivastava, A. M.; Chandran, R. G.; Shankar, M. V. Crystal chemistry and luminescence of Ce³⁺-doped Lu₂CaMg₂(Si, Ge)₃O₁₂ and its use in LED based lighting. Chem. Mater. 2006, 18, 3314–3322. doi: 10.1021/cm060898c
13. [13]
  Suehiro, T.; Hirosaki, N.; Xie, R. J. Synthesis and photoluminescent properties of (La, Ca)₃Si₆N₁₁: Ce³⁺ fine powder phosphors for solid-state lighting. Acs Appl. Mater. Inter. 2011, 3, 811–816. doi: 10.1021/am101160e
14. [14]
  Zhu, H.; Lin, C. C.; Luo, W.; Shu, S.; Liu, Z.; Liu, Y.; Kong, J.; Ma, E.; Cao, Y.; Liu, R. S.; Chen, X. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes. Nature Commun. 2014, 5, 1–10.
15. [15]
  Guo, N.; Huang, Y. J.; You, H. P.; Yang, M.; Song, Y. H.; Liu, K.; Zheng, Y. H. Ca₉Lu(PO₄)₇: Eu²⁺, Mn²⁺: a potential single-phased white-light-emitting phosphor suitable for white-light-emitting diodes. Inorg. Chem. 2010, 49, 10907–10913. doi: 10.1021/ic101749g
16. [16]
  Omatete, O. O.; Janney, M. A.; Strehlow, R. A. Gelcasting - a new ceramic forming process. Am. Ceram. Soc. Bull. 1991, 70, 1641–1649.
17. [17]
  Omatete, O. O.; Janney, M. A.; Nunn, S. D. Gelcasting: from laboratory development toward industrial production. J. Eur. Ceram. Soc. 1997, 17, 407–413. doi: 10.1016/S0955-2219(96)00147-1
18. [18]
  Yang, J.; Yu, J.; Huang, Y. Recent developments in gelcasting of ceramics. J. Eur. Ceram. Soc. 2011, 31, 2569–2591. doi: 10.1016/j.jeurceramsoc.2010.12.035
19. [19]
  Que, M.; Que, W.; Zhou, T.; Shao, J.; Kong, L. Photoluminescence and energy transfer of YAG: Ce³⁺, Gd³⁺, Bi³⁺. J. Adv. Dielectr. 2016, 06, 1650029-1-1650029-6. doi: 10.1142/S2010135X16500296
20. [20]
  Nguyen Huu Khanh, N.; Tran Hoang Quang, M.; Nguyen, T. N.; Voznak, M. Bi-layers red-emitting Sr₂Si₅N₈: Eu²⁺ phosphor and yellow-emitting YAG: Ce phosphor: a new approach for improving the color rendering index of the remote phosphor packaging WLEDs. Curr. Opt. Photonics 2017, 1, 613–617.
21. [21]
  Sun, X. W.; Tan, J.; Li, C. M.; Lei, T.; Meng, X. K.; Yan, W.; Zhang, W.; Feng, S. Doping effects of Sb, Bi, Zr and Si on the properties of YAG: Ce phosphor. Chin. J. Inorg. Chem. 2013, 29, 1863–1869.
22. [22]
  Zorenko, Y.; Gorbenko, V.; Savchyn, V.; Zorenko, T.; Nikl, M.; Mares, J. A.; Beitlerova, A.; Jary, V. Bi³⁺-Pr³⁺ energy transfer processes and luminescent properties of LuAG: Bi, Pr and YAG: Bi, Pr single crystalline films. J. Lumin. 2013, 141, 137–143. doi: 10.1016/j.jlumin.2013.03.036
23. [23]
  Wei, N. A.; Guan, Y. B.; Wu, H. J.; Lu, Z. W.; Chen, X. T.; Zhao, Y.; Qi, J. Q.; Lu, T. C.; Zhang, W.; Ma, B. Y. Fabrication of Yb³⁺-doped YAG transparent ceramics by aqueous gelcasting. J. Sol-Gel Sci. Technol. 2016, 77, 211–217. doi: 10.1007/s10971-015-3846-6
24. [24]
  Jia, Y. C.; Huang, Y. J.; Zheng, Y. H.; Guo, N.; Qiao, H.; Zhao, Q.; Lv, W. Z.; You, H. P. Color point tuning of Y₃Al₅O₁₂: Ce³⁺ phosphor via Mn²⁺-Si⁴⁺ incorporation for white light generation. J. Mater. Chem. 2012, 22, 15146–15152. doi: 10.1039/c2jm32233a
25. [25]
  Bonin, K. D.; Kadarkallen, M. A. Linear electric-dipole polarizabilities. Int. J. Mod. Phys. 1994, 8, 3313–3370. doi: 10.1142/S0217979294001391
26. [26]
  Noginov, M. A.; Loutts, G. B.; Warren, M. Spectroscopic studies of Mn³⁺ and Mn²⁺ ions in YAlO₃. J. Opt. Soc. Am. B 1999, 16, 475–483.
27. [27]
  Gedam, S. C.; Dhoble, S. J.; Moharil, S. V. Dy³⁺ and Mn²⁺ emission in KMgSO₄Cl phosphor. J. Lumin. 2007, 124, 120–126. doi: 10.1016/j.jlumin.2006.02.016
28. [28]
  Zhang, Z. M.; Liang, X. J.; Zhao, B. Y.; Chen, Z. P.; Liu, B. F.; Zhong, J. S.; Xiang, W. D.; Lu, C. Y. Growth and luminescence properties of Ce, Mn: YAG single crystal. Chem. Chem. J. Chin. U. 2013, 34, 1826–1832.
29. [29]
  Shi, Y. R.; Wang, Y. H.; Wen, Y.; Zhao, Z. Y.; Liu, B. T.; Yang, Z. G. Tunable luminescence Y₃Al₅O₁₂: 0.06Ce³⁺, xMn²⁺ phosphors with different charge compensators for warm white light emitting diodes. Opt. Express 2012, 20, 21656–21664. doi: 10.1364/OE.20.021656
1. [1]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
2. [2]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
3. [3]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
4. [4]
  Zhixue Liu , Haiqi Chen , Lijuan Guo , Xinyao Sun , Zhi-Yuan Zhang , Junyi Chen , Ming Dong , Chunju Li . Luminescent terphen[3]arene sulfate-activated FRET assemblies for cell imaging. Chinese Chemical Letters, 2024, 35(9): 109666-. doi: 10.1016/j.cclet.2024.109666
5. [5]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
6. [6]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
7. [7]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
8. [8]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
9. [9]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
10. [10]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
11. [11]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085
12. [12]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
13. [13]
  Yue Mao , Zhonghang Chen , Tiankai Sun , Wenyue Cui , Peng Cheng , Wei Shi . Luminescent coordination polymers with mixed carboxylate and triazole ligands for rapid detection of chloroprene metabolite. Chinese Journal of Structural Chemistry, 2024, 43(9): 100353-100353. doi: 10.1016/j.cjsc.2024.100353
14. [14]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
15. [15]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
16. [16]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
17. [17]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
18. [18]
  Zhiwei Zhong , Yanbin Huang , Wantai Yang . A simple photochemical method for surface fluorination using perfluoroketones. Chinese Chemical Letters, 2024, 35(5): 109339-. doi: 10.1016/j.cclet.2023.109339
19. [19]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
20. [20]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(189)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Doping Effect of Bi3+ on the Properties of YAG: Ce3+, Mn2+ Phosphor Ceramics for Warm WLEDs

Metrics

通讯作者: 陈斌, bchen63@163.com

Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs