Citation: Ru-Ru CHEN, Wei-Guang YANG, Min-Na CAO, Hong-Fang LI. Synthesis and Crystal Structure of a New Noble Metal-containing Supramolecular Self-assembly with Decamethylcucurbit[5]uril[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 535-542. doi: 10.14102/j.cnki.0254-5861.2011-2440 shu

Synthesis and Crystal Structure of a New Noble Metal-containing Supramolecular Self-assembly with Decamethylcucurbit[5]uril

Ru-Ru CHEN ^{a, b} ,
Wei-Guang YANG ^{a, b} ,
Min-Na CAO ^b,, ,
Hong-Fang LI ^b,,

a.
College of Chemistry, Fuzhou University, Fuzhou 350002, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Min-Na CAO, mncao@fjirsm.ac.cn Hong-Fang LI, hongfangli@fjirsm.ac.cn
Received Date: 5 May 2019
Accepted Date: 20 July 2019

Fund Project: the National Key R & D Program of China 2017YFA0206800the National Key R & D Program of China 2016YFB0600903the NSFC 21573238the NSFC 21571177the NSFC 21520102001Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH045"Strategic Priority Research Program" of the Chinese Academy of Sciences XDB20000000

Figures(6)

A new supramolecular self-assembly [Li(H₂O)₂]₂[(H₂O@Me₁₀CB[5])][PtCl₆]·7H₂O (1, Me₁₀CB[5] = decamethylcucurbit[5]uril), has been successfully constructed with Me₁₀CB[5] and [PtCl₆]^2- anion in the presence of lithium cation (Li⁺). Single-crystal X-ray diffraction study reveals that compound 1 crystallizes in monoclinic space group P2₁/n with a = 11.1681(18), b = 28.5425(4), c = 18.9342(3) Å, β = 99.0143(15)°, V = 5961.02(16) Å³, Z = 4, F(000) = 3224, μ = 2.714 mm^-1, R = 0.0470 and wR = 0.1076 (I > 2σ(I)). In the supramolecular self-assembly, two of the portal carbonyl oxygen atoms of Me₁₀CB[5] are coordinated to Li⁺ cation, yielding a "half-open" molecular capsule. Then adjacent molecular capsules are connected with each other through hydrogen-bonding to form a one-dimensional (1D) supramolecular chain structure. The [PtCl₆]^2- anions are fixed on one side of the 1D supramolecular chain through supramolecular interactions. The thermal stability, electronic valence and morphology of compound 1 are also investigated.
- decamethylcucurbit[5]uril,
- noble metal,
- supramolecular self-assembly,
- crystal structure
1. [1]
  Barrow, S. J.; Kasera, S.; Rowland, M. J.; Barrio, J.; Scherman, O. A. Cucurbituril-based molecular recognition. Chem. Soc. Rev. 2015, 115, 12320–12406. doi: 10.1021/acs.chemrev.5b00341
2. [2]
  Assaf, K. I.; Nau, W. M. Cucurbiturils: from synthesis to high-affinity binding and catalysis. Chem. Soc. Rev. 2015, 44, 394–418. doi: 10.1039/C4CS00273C
3. [3]
  Ni, X. L.; Xiao, X.; Cong, H.; Liang, L. L.; Cheng, K.; Cheng, X. J.; Ji, N. N.; Zhu, Q. J.; Xue, S. F.; Tao, Z. Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers. Chem. Soc. Rev. 2013, 42, 9480–9508. doi: 10.1039/c3cs60261c
4. [4]
  Gurbuz, S.; Idris, M.; Tuncel, D. Cucurbituril-based supramolecular engineered nanostructured materials. Org. Biomol. Chem. 2015, 13, 330–347. doi: 10.1039/C4OB02065K
5. [5]
  Ni, X. L.; Xiao, X.; Cong, H.; Tao, Z. Supramolecular assemblies of cucurbit[n]urils with metal ions: coordination, structures and properties. Springer 2015.
6. [6]
  Hu, J. X.; Hu, Y. F.; Xiao, X.; Zhang, Y. Q.; Tao, Z.; Xue, S. F.; Liu, J. X.; Zhu, Q. J. Coordination of pentacyclohexanocucurbit[5]uril with alkali metal ions and supramolecular self-assembly in the absence and presence of inorganic anions. Eur. J. Inorg. Chem. 2013, 3632–3640.
7. [7]
  Li, H. F.; Lu, J.; Lin, J. X.; Cao, R. Monodispersed Ag nanoparticles as catalyst: preparation based on crystalline supramolecular hybrid of decamethylcucurbit[5]uril and silver ions. Inorg. Chem. 2014, 53, 5692–5697. doi: 10.1021/ic500464v
8. [8]
  Han, L. W.; Lin, J. X.; Yin, Q.; Karadeniz, B.; Li, H. F.; Lü, J.; Cao, R. Sandwich-type inorganic-organic hybrid solids of iso-polyvanadate clusters and decamethylcucurbit[5]uril. Cryst. Growth. Des. 2016, 16, 1213–1217. doi: 10.1021/acs.cgd.5b01176
9. [9]
  Lin, J.; Lü, J.; Cao, M.; Cao, R. Effects of cocrystalline subunits on the supramolecular chemistry of Me₁₀Q[5]: from simple inorganic anions to cluster anions. Cryst. Growth. Des. 2011, 11, 778–783. doi: 10.1021/cg101355d
10. [10]
  Hu, Y. F.; Chen, K.; Liu, J. X.; Lin, R. L.; Sun, W. Q.; Xue, S. F.; Zhu, Q. J.; Tao, Z. Complexation of decamethylcucurbit[5]uril with alkali metal ions. Polyhedron 2012, 31, 632–637. doi: 10.1016/j.poly.2011.10.039
11. [11]
  Wei, L. T.; Zhang, Y. Q.; Zhou, K. Z.; Zhan, L. L.; Qu, Y. X.; Tao, Z.; Ma, P. H. Coordination of fully substituted cyclopentano cucurbit[5]uril with alkali cation in the presence of tetrachloridezicate anion. Inorga Chim. Acta 2016, 445, 1–7. doi: 10.1016/j.ica.2016.01.041
12. [12]
  Lin, R. L.; Sun, W. Q.; Yao, W. R.; Zhu, J.; Liu, J. X. Anion concentration control in the self-assembly of symmetrical α, α′, δ, δ′-tetramethyl-cucurbit[6]uril-based tubular architectures. RSC Advances 2014, 4, 18323–18328. doi: 10.1039/c4ra01671h
13. [13]
  Zhang, T.; Zhang, Y. Q.; Zhu, Q. J.; Tao, Z. Supramolecular assemblies based on the interaction of a copper dication with alky-substituted cucurbit[6]urils. Polyhedron 2013, 53, 98–102. doi: 10.1016/j.poly.2013.01.029
14. [14]
  Dong, C.; Lian, C.; Hu, S.; Deng, Z.; Gong, J.; Li, M.; Liu, H.; Xing, M.; Zhang, J. Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles. Nat. Commun. 2018, 9, 1252. doi: 10.1038/s41467-018-03666-2
15. [15]
  Ling, M.; Blackman, C. S. Gas-phase synthesis of hybrid nanostructured materials. Nanoscale 2018, 10, 22981–22989. doi: 10.1039/C8NR06257A
16. [16]
  Zhang, Y.; Hu, L.; Han, W. Insights into in situ one-step synthesis of carbon-supported nano-particulate gold-based catalysts for efficient electrocatalytic CO₂ reduction. J. Mater. Chem. A 2018, 6, 23610–23620. doi: 10.1039/C8TA08698B
17. [17]
  Dunwell, M.; Lu, Q.; Heyes, J. M.; Rosen, J.; Chen, J. G.; Yan, Y.; Jiao, F.; Xu, B. The central role of bicarbonate in the electrochemical reduction of carbon dioxide on gold. J. Am. Chem. Soc. 2017, 139, 3774–3783. doi: 10.1021/jacs.6b13287
18. [18]
  Wang, Q.; Wang, X. S.; Chen, C. H.; Yang, X.; Huang, Y. B.; Cao, R. Defective Pt nanoparticles encapsulated in mesoporous metal-organic frameworks for enhanced catalysis. Chem. Commun. 2018, 54, 8822–8825. doi: 10.1039/C8CC04485F
19. [19]
  Wang, D.; Xin, H. L.; Yu, Y.; Wang, H.; Rus, E.; Muller, D. A.; Hector D. A. Pt-Decorated PdCo@Pd/C core-shell nanoparticles with enhanced stability and electrocatalytic activity for the oxygen reduction reaction. J. Am. Chem. Soc. 2010, 132, 17664–17666. doi: 10.1021/ja107874u
20. [20]
  Wang, Y. R.; Huang, Q.; He, C. T.; Chen, Y.; Liu, J.; Shen, F. C.; Lan, Y. Q. Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO₂. Nat. Commun. 2018, 9, 4466. doi: 10.1038/s41467-018-06938-z
21. [21]
  Li, H.; Lu, J.; Lin, J.; Huang, Y.; Cao, M.; Cao, R. Crystalline hybrid solid materials of palladium and decamethylcucurbit[5]uril as recoverable precatalysts for Heck cross-coupling reactions. Chem. Eur. J. 2013, 19, 15661–15668. doi: 10.1002/chem.201301703
22. [22]
  Huang, X.; Zhao, Z.; Chen, Y.; Zhu, E.; Li, M.; Duan, X.; Huang, Y. A rational design of carbon-supported dispersive Pt-based octahedra as efficient oxygen reduction reaction catalysts. Energ. Environ. Sci. 2014, 7, 2957–2962. doi: 10.1039/C4EE01082E
23. [23]
  Du, W.; Chen, G.; Nie, R.; Li, Y.; Hou, Z. Highly dispersed Pt in MIL-101: an efficient catalyst for the hydrogenation of nitroarenes. Catal. Commun. 2013, 41, 56–59. doi: 10.1016/j.catcom.2013.06.038
24. [24]
  Jansen, K.; Buschmann, H. J.; Wego, A.; Dopp, D.; Mayer, C.; Drexler, H. J.; Holdt, H. J.; Schollmeyer, E. Cucurbit[5]uril, decamethylcucurbit[5]uril and cucurbit[6]uril. Synthesis, solubility and amine complex formation. J. Incl. Phenom. Macro. 2001, 39, 357–363. doi: 10.1023/A:1011184725796
25. [25]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. Sect. C 2015, 71, 3-8.
26. [26]
  Wang, X. L.; Dong, L. Z.; Qiao, M.; Tang, Y. J.; Liu, J.; Li, Y.; Li, S. L.; Su, J. X.; Lan, Y. Q. Exploring the performance improvement of the oxygen evolution reaction in a stable bimetal-organic framework system. Angew. Chem. Int. Ed. 2018, 57, 1–6. doi: 10.1002/anie.201712460
27. [27]
  Lin, J. X.; Lu, J.; Yang, H. X.; Cao, R. Construction of train-like supramolecular structures from decamethylcucurbit[5]uril and isoor hetero-Keggin-type polyoxotungstates. Cryst. Growth. Des. 2010, 10, 1966–1970. doi: 10.1021/cg1000528
28. [28]
  Zhao, M.; Deng, K.; He, L.; Liu, Y.; Li, G.; Zhao, H.; Tang, Z. Core-shell palladium nanoparticle@metal-organic frameworks as multifunctional catalysts for cascade reactions. J. Am. Chem. Soc. 2014, 136, 1738–1741. doi: 10.1021/ja411468e
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