Citation: Nan DING, Zhong-Yi LIU, Rin-Min CHEN, Yi-Lin BO, Xiu-Guang WANG, Xiao-Jun ZHAO, En-Cui YANG. A New Pillared-layer Framework with Co^Ⅱ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 519-525. doi: 10.14102/j.cnki.0254-5861.2011-2423 shu

A New Pillared-layer Framework with Co^Ⅱ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration

College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: En-Cui YANG, encui_yang@163.com
Received Date: 19 April 2019
Accepted Date: 16 July 2019

Fund Project: NNSFC 21303121the Program for Innovative Research Team at University of Tianjin TD13-5074Innovation Program of Tianjin University students 201810065338

Figures(4)

One new coordination polymer, [Co₄(H₂O)₄(μ₃-OH)₂(atz)₂(L)]_n (1), was solvothermally prepared by the reaction of 3-amino-1, 2, 4-triazole (Hatz), 4, 8-disulfonyl-2, 6-naphthalenedicarboxylic acid (H₄L) and Co^Ⅱ salt. It crystallizes in monoclinic system, space group P2₁/c with a = 10.4454(7), b = 12.2214(8), c = 10.0818(7) Å, β = 102.284(7), V = 1257.56(15) Å³, D_c = 2.325 g/cm³, M_r = 880.24, Z = 2, F(000) = 880, μ = 2.859 mm^-1, the final R = 0.0426 and wR = 0.0822 for 5526 observed reflections with I > 2σ(I). Structural analyses indicate that 1 exhibits a three-dimensional (3D) pillared-layer framework with triazolate extended Co₄^Ⅱ layers supported by rigid L^4- connectors. Magnetically, complex 1 displays strong spin-frustrated antiferromagnetism due to the triangular magnetic lattice and cooperative antiferromagnetic couplings mediated by quadruple heterobridges.
- pillared-layer framework,
- 1,2,4-triazole,
- spin-frustration
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A New Pillared-layer Framework with CoⅡ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration

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通讯作者: 陈斌, bchen63@163.com

A New Pillared-layer Framework with Co^Ⅱ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration