Citation: YE Yan-Zhu, WU Xin-Jian, ZHANG Xian-Jin, WANG A-Lian. Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare (H2O)22 Clusters[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1980-1986. doi: 10.14102/j.cnki.0254-5861.2011-1418 shu

Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare (H2O)22 Clusters

  • Corresponding author: YE Yan-Zhu, yanzhuye@126.com
  • Received Date: 15 July 2016
    Accepted Date: 27 October 2016

    Fund Project: the Foundation of Fujian Educational Committee JA14348

Figures(5)

  • A novel Dy3+ coordination compound, (H2pipz)(H3O)[Dy(pydc)3]·11H2O (1, pipz=piperazine and H2pydc=pyridine-2,6-dicarboxylic acid), has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction, elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O…H…O hydrogen bonding interactions. Furthermore, the luminescent property of compound 1 was also investigated.
  • 加载中
    1. [1]

      Gu J. Z, Wu J, Lv D. Y, Tang Y, Zhu K, Wu J. Lanthanide coordination polymers based on 5-(2?-carboxylphenyl) nicotinate: syntheses, structure diversity, dehydration/hydration, luminescence and magnetic properties[J]. Dalton Trans., 2013,42:4822-4830. doi: 10.1039/c2dt32674d

    2. [2]

      Zhang F. M, Yan P. F, Zou X. Y, Zhang J. W, Hou G. F, Li G. M. Novel 3D alkali-lanthanide heterometal-organic frameworks with pyrazine-2,3,5,6-tetracarboxylic acid: synthesis, structure, and magnetism[J]. Cryst. Growth Des., 2014,14:2014-2021. doi: 10.1021/cg5001254

    3. [3]

      Wei X. H, Yang L. Y, Liao S. Y, Zhang M, Tian J. L, Du P. Y, Gu W, Liu X. A series of rare earth complexes with novel non-interpenetrating 3D networks: synthesis, structures, magnetic and optical properties[J]. Dalton Trans., 2014,43:5793-5800. doi: 10.1039/c3dt53112k

    4. [4]

      Feng X, Ling X. L, Liu L, Song H. L, Wang L. Y, Ng S. W, Su B. Y. A series of 3D lanthanide frameworks constructed from aromatic multi-carboxylate ligand: structural diversity, luminescence and magnetic properties[J]. Dalton Trans., 2013,42:10292-10303. doi: 10.1039/c3dt50810b

    5. [5]

      Vilela S. M. F, Firmino A. D. G, Mendes R. F, Fernandes J. A, Ananias D, Valente A. A, Ott H, Carlos L. D, Rocha J, Tome J. P. C, Paz F. A. A. Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties[J]. Chem. Commun., 2013,49:6400-6402. doi: 10.1039/c3cc42632g

    6. [6]

      Feng, W.; Zhang, Y.; Lü, X.; Hui, Y.; Shi, G.; Zou, D.; Song, J.; Fan, D.; Wong, W. K.; Richard, A. J. Near-infrared (NIR) luminescent homoleptic lanthanide salen complexes Ln4(Salen)4 (Ln = Nd, Yb or Er). CrystEngComm. 2012, 14, 3456-3463.

    7. [7]

      Xu J, Su W. P, Hong M. C. A series of lanthanide secondary building units based metal-organic frameworks constructed by organic pyridine-2,6-dicarboxylate and inorganic sulfate[J]. Cryst. Growth Des., 2011,11:337-346. doi: 10.1021/cg101343k

    8. [8]

      Ye Y. Z, Wu X. J, Wang A. L. Synthesis, structure and property of a novel coordination polymer[J]. J. Struct. Chem., 2014,33:1860-1864.

    9. [9]

      Yang L. R, Song S, Shao C. Y, Zhang W, Zhang H. M, Bu Z. W, Ren T. G. Synthesis, structure and luminescent properties of 3D lanthanide (La(III), Ce(III)) coordination polymers possessing 1D nanosized cavities based on pyridine-2,6-dicarboxylic acid[J]. Synth. Met., 2011,161:1500-1508. doi: 10.1016/j.synthmet.2011.04.016

    10. [10]

      (a) Li, M.; Feng, R.; Huang, Q. Z.; Feng, Y. Q.; Shi, H. Z. Synthesis, crystal structure and luminescent property of a novel lanthanide coordination polymer containing (H2O)20 clusters. Inorg. Chem. Commun. 2014, 50, 8-12. (b) Aghabozorg, H.; Motieiyan, E.; Salimi, A. R.; Mirzaei, M.; Manteghi, F.; Shokrollahi, A.; Derki, S.; Ghadermazi, M.; Sheshmani, S.; Eshtiagh-Hosseini, H. Piperazinediium, Zr(IV) and Ce(IV) pyridine-2,6-dicarboxylates: syntheses, characterizations, crystal structures, ab initio HF, DFT calculations and solution studies. Polyhedron 2010, 29, 1453-1464. (c) Dalai, S.; Rana, A.; Chowdhuri, D. S.; Bera, M.; Zangrando, E. Cubane-like water clusters in a 3D supramolecular network of zinc with pyridine-2,6-dicarboxylic acid and 5-aminotetrazole. Inorg. Chim. Acta 2010, 363, 1052-1055. (d) Deng, D. S.; Liu, P.; Fu, W. J.; Li, L.; Yang, F. X.; Ji, B. M. Metal-organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: syntheses, crystal structures, and physical characterization. Inorg. Chim. Acta 2010, 363, 891-898.

    11. [11]

      Zhu T. Y, Ikarashi K, Ishigaki T, Uematsu K, Toda K, Okawa H, Sato M. Structure and luminescence of sodium and lanthanide(III) coordination polymers with pyridine-2,6-dicarboxylic acid[J]. Inorg. Chim. Acta, 2009,362:3407-3414. doi: 10.1016/j.ica.2009.01.036

    12. [12]

      Deng D. S, Liu P, Fu W. J, Li L, Yang F. X, Ji B. M. Metal-organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: syntheses, crystal structures, and physical characterization[J]. Inorg. Chim. Acta, 2010,363:891-898. doi: 10.1016/j.ica.2009.12.044

    13. [13]

      Dalai S, Rana A, Chowdhuri D. S, Bera M, Zangrando E. Cubane-like water clusters in a 3D supramolecular network of zinc with pyridine-2,6-dicarboxylic acid and 5-aminotetrazole[J]. Inorg. Chim. Acta, 2010,363:1052-1055. doi: 10.1016/j.ica.2009.12.018

    14. [14]

      Zeng X. Z, Zhang A. Y, He C, Li Y. W. Synthesis, structure and thermal properties of two cerium(Ⅳ) complexes with 2,6-pyridinedicarboxylic acid[J]. Chin. J. Inorg. Chem., 2013,29:1557-1562.

    15. [15]

      Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of G?ttingen, G?ttingen (Germany) 1997.

    16. [16]

      Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of G?ttingen, G?ttingen (Germany) 1997.

    17. [17]

      Biswas S, Jena H. S, Goswami S, Sanda S, Konar S. Synthesis and characterization of two lanthanide (Gd3+and Dy3+)-based three-dimensional metal organic frameworks with squashed metallomacrocycle type building blocks and their magnetic, sorption, and fluorescence properties study[J]. Cryst. Growth Des., 2014,14:1287-1295. doi: 10.1021/cg401804e

    18. [18]

      Ghosh S. K. Structure of a discrete hexadecameric water cluster in a metal-organic framework structure[J]. Inorg. Chem., 2004,43:6687-6889.  

    19. [19]

      Mao P. D, Yan L. L, Wu W. N, Liu M. Q, Zhou L. H, Fu S. L. Lanthanide (La, Tb, Dy) complexes with quinolinyloxy acetamide ligand: crystal structures and fluorescence properties[J]. Chin. J. Inorg. Chem., 2016,32:1095-1100.

    20. [20]

      Li H. H, Li H, Niu Z, Wang Y. P. Structural diversity of two novel Dy(III) metal-organic frameworks based on binuclear nodes with furan-2,5-dicarboxylic acid: crystal structures and luminescent properties[J]. Inorg. Chem. Commun., 2015,55:103-107. doi: 10.1016/j.inoche.2015.03.013

    21. [21]

      Yang R, He S. Y, Wu W. T, Wen Z. Y, Shi Q. Z, Wang D. Q. Crystal structure, fluorescence characterization of dysprosium(III) multicomponent complex with acylhydrazone and 1,10-phenanthroline[J]. Acta Chimica Sinica, 2004,62:2040-2044.

  • 加载中
    1. [1]

      Gaofeng WANGShuwen SUNYanfei ZHAOLixin MENGBohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479

    2. [2]

      Xiumei LIYanju HUANGBo LIUYaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109

    3. [3]

      Xiumei LILinlin LIBo LIUYaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273

    4. [4]

      Xiaoxia WANGYa'nan GUOFeng SUChun HANLong SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478

    5. [5]

      Xiaoling WANGHongwu ZHANGDaofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214

    6. [6]

      Yao HUANGYingshu WUZhichun BAOYue HUANGShangfeng TANGRuixue LIUYancheng LIUHong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359

    7. [7]

      Jia JIZhaoyang GUOWenni LEIJiawei ZHENGHaorong QINJiahong YANYinling HOUXiaoyan XINWenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344

    8. [8]

      Yinling HOUJia JIHong YUXiaoyun BIANXiaofen GUANJing QIUShuyi RENMing FANG . A rhombic Dy4-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251

    9. [9]

      Lu LIUHuijie WANGHaitong WANGYing LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489

    10. [10]

      Lulu DONGJie LIUHua YANGYupei FUHongli LIUXiaoli CHENHuali CUILin LIUJijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171

    11. [11]

      Chao LIUJiang WUZhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153

    12. [12]

      Yan XUSuzhi LIYan LILushun FENGWentao SUNXinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226

    13. [13]

      Kaimin WANGXiong GUNa DENGHongmei YUYanqin YEYulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009

    14. [14]

      Huan ZHANGJijiang WANGGuang FANLong TANGErlin YUEChao BAIXiao WANGYuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291

    15. [15]

      Ruikui YANXiaoli CHENMiao CAIJing RENHuali CUIHua YANGJijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301

    16. [16]

      Meirong HANXiaoyang WEISisi FENGYuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu2+. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150

    17. [17]

      Shuyan ZHAO . Field-induced Co single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231

    18. [18]

      Liyang ZHANGDongdong YANGNing LIYuanyu YANGQi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

    19. [19]

      Jiakun Bai Junhui Jia Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323

    20. [20]

      Hai-Ling Wang Zhong-Hong Zhu Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372

Metrics
  • PDF Downloads(0)
  • Abstract views(5961)
  • HTML views(138)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return