Citation: WANG Qing, MA Cheng-Bing, CHEN Hui, HUANG De-Guang, CHEN Chang-Neng. Five-heterocyclic-biphosphinesubstituted Fe-only Hydrogenase Mimic: Synthesis, Characterization and Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1972-1979. doi: 10.14102/j.cnki.0254-5861.2011-1211 shu

Five-heterocyclic-biphosphinesubstituted Fe-only Hydrogenase Mimic: Synthesis, Characterization and Properties

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: CHEN Chang-Neng, ccn@fjirsm.ac.cn
Received Date: 22 March 2016
Accepted Date: 2 June 2016

Fund Project: the NNSFC 21231003 and 21203195

Figures(4)

A new five-heterocyclic-biphosphine-substituted Fe-only hydrogenase mimic,[(μ-pdt)Fe₂(CO)₅]₂(PTP) (1), has been synthesized at room temperature. 1·H₂O crystallizes in triclinic system, space group P1, with a=11.5897(4), b=13.6156(4), c=18.0333(6)Å, α=76.306(3), β=72.742(3), γ=68.939(3)°, V=2508.84(14)Å³, D_c=1.570 g/cm³, Z=2, M_r=1186.37, F(000)=1204, the final R=0.0748, and wR=0.2012. In the tetranuclear complex 1·H₂O, each[2Fe2S] butterfly unit is attached to one P atom of the diphosphine bridge and exhibits a square-pyramidal geometry. Complex 1 was characterized by elemental analysis, IR spectra, UV-vis absorption spectra, ¹H-NMR and ³¹P-NMR. The cyclic voltammetry behavior of compound 1 was investigated as well.
- Fe-only hydrogenase mimic,
- spectral analysis,
- cyclic voltammetry
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