Citation: CHEN Yan-Guo, WANG Qi-Ying, TANG Qiang, HONG Peng, HU Chuan-Qun. Syntheses, Crystal Structures and Fluorescence Properties of Two Mononuclear Copper(II) Compounds[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1885-1893. doi: 10.14102/j.cnki.0254-5861.2011-1142 shu

Syntheses, Crystal Structures and Fluorescence Properties of Two Mononuclear Copper(II) Compounds

  • Corresponding author: CHEN Yan-Guo, chenyg1965@163.com
  • Received Date: 19 January 2016
    Accepted Date: 8 June 2016

    Fund Project: Natural Foundation of Hubei Province 2010CDA020Key Foundation of Industry-University-Research Cooperation of Education Department, Hubei Province CXY2009A010Research Fund for the Doctor Program of Hubei University of Technology BSQD12139Ministry of Science and Technology Small and Medium-sized Enterprise Venture Funds 12C26214204453

Figures(6)

  • Two new compounds, 1 ([Cu(IDB)2]Cl2·2CH3CH2OH·2H2O (IDB=N,N-di(2-benzimidazolylmethyl)imine]) and 2 ([Cu(EDTB)]·2[C6H4(OH)COO]·6H2O (EDTB=N,N,N',N'-tetrakis-[(2-benzimidazolyl)methyl]-1,2-ethanediamine]), have been synthesized and their crystal structures were determined by single-crystal X-ray diffraction. Crystal 1 belongs to the triclinic system, space group P>1 with a=9.565(2), b=9.863(2), c=10.252(3)Å, α=81.915, β=88.330, γ=87.347°, V=956.28(40)Å3, Z=1, F(000)=427, Dc=1.419 g/cm3, Mr=817.27 and μ(Mo)=0.764 mm-1. The final R indices (I>2σ(I)):R=0.0505, wR=0.1417; R indices (all data):R=0.0591, wR=0.1525. Crystal 2 is of triclinic system, space group P>1 with a=11.487(3), b=13.396(4), c=17.977(5)Å, α=73.899(5), β=86.629(5), γ=65.018(4)°, V=2403.8(12)Å3, Z=2, F(000)=1072, Dc=1.417 g/cm3, Mr=1025.54, μ(Mo)=0.528 mm-1. The final R indices (I>2σ(I)):R=0.0769, wR=0.163 2; R indices (all data):R=0.0769, wR=0.1632. The two compounds exhibit mononuclear structures. The copper(II) atom of crystal 1 is six-coordinated by four nitrogen atoms of benzimidazole groups and two amine nitrogen atoms from the ligand IDB to adopt a distorted octahedral coordination geometry. The copper(II) atom of crystal 2 is six-coordinated by four nitrogen atoms of benzimidazole groups and two amine nitrogen atoms from the ligand EDTB to show a distorted octahedral coordination geometry. Particularly, the two compounds exhibit fluorescent properties at room temperature in ethanol.
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    1. [1]

      Kostakis G. E, Ako A. M, Powell A. K. Structural motifs and topological representation of Mn coordination clusters[J]. Chem. Soc. Rev, 2010,39:2238-2271. doi: 10.1039/b918192j

    2. [2]

      Hu X. L, Shi P. F, Xu X. Y, Yin F. J, Yang Q, Wang D. Q. The synthesis, structure and property study of mixed-valence tetranuclear copper complex [Cu2L2 ]·[Cu(pht)2 ]2[J]. Chin. Acta Chim. Sinica, 2010,68:487-492.  

    3. [3]

      Hu X. L, Shi P. F, Xu X. Y, Luan Y, Chen J. P, Wang D. Q. The synthesis, crystal structure and DNA-binding studies of Cu(I/II) complex [Cu(en)2]·[Cu(pht)2] 2[J]. Chin. Acta Chim. Sinica, 2009,67:2517-2522.  

    4. [4]

      Hu X. L, Xu X., Xu T. T, Wang D. Q. (5,5-Diphenylhydantoinato-κN3)[trisi(3-aminoprepyl)amine]copper(II) 5,5-diphenylhydantoinate methnol solvate[J]. Acta Cryst, 2006,62:2352-2353.

    5. [5]

      Hu X. L, Xu X. Y, Xu T. T, Wang D. Q. Trans-bis(5,5-diphenylhydantoinato-?N3)bis(furfurylamine-N)copper(II) 5,5-dipheny-lhydantoindisolvate[J]. Acta Cryst, 2006,62:2974-2975.

    6. [6]

      Ren Y. H, Dong J. L, Wang Z. W, Ren J. G. Synthesis and crystal structure of the azo copper(II)-complex[J]. Chin. J. Struct. Chem, 2011,30:376-379.  

    7. [7]

      Kocaka A, Yilmazc H, Faizb O, Andacc O. Experimental and theoretical studies on Cu(II) complex of N,N'-disalicylidene-2,3-diaminopyridine ligand reveal indirect evidence for DNA intercalation[J]. Polyhedron, 2016,104:106-115. doi: 10.1016/j.poly.2015.11.037

    8. [8]

      Venkatramaiah N, Firmino D. G, Paz F. A, Tome J. P. C. Fast detection of nitroaromatics using phosphonate pyrene motifs as dual chemosensors[J]. Chem. Commun, 2014,50:9683-9686. doi: 10.1039/C4CC03980G

    9. [9]

      Bazzicalupi C, Caltagirone C, Cao Z. F, Chen Q. B, Natale C. D, Garau A, Lippolis V, Lvova L, Liu H. L, Paolesse R, Zaccheroni N. Multimodal use of new coumarin-based fluorescent chemosensors: towards highly selective optical sensors for Hg2+ probing[J]. Chem. Eur. J, 2013,19:14639-14653. doi: 10.1002/chem.v19.43

    10. [10]

      Nejati K, Rezvani Z, Seyedahmadian M. The synthesis, characterization, thermal and optical properties of copper, nickel, and vanadyl complexes derived from azo dyes[J]. Dyes Pigm, 2009,83:304-311. doi: 10.1016/j.dyepig.2009.05.007

    11. [11]

      Cui Y. J, Xu H, Yue Y. F, Guo Z. Y, Yu J. C, Chen Z. X, Gao J. K, Yang Y, Qian G. D, Chen B. L. A luminescent mixed-lanthanide metal-organic framework thermometer[J]. J. Am. Chem. Soc, 2012,134:3979-3982. doi: 10.1021/ja2108036

    12. [12]

      Lan Y. Q, Jiang H. L, Li S. L, Xu Q. Solvent-induced controllable synthesis, single-crystal to single-crystal transformation and encapsulation of Alq3 for modulated luminescence in (4,8)-connected metal-organic frameworks[J]. Inorg. Chem, 2012,51:7484-7491. doi: 10.1021/ic202635a

    13. [13]

      Chen Y. G, Liao Z. R, Li W. K, Li D. F, Mei F. S, Wei Y. G. Synthesis, crystal structure and the activity about catalytic urea hydrolysis of [Ni(IDB)2][C6H4(OH)COO]·ClO4·CH3CH2OH·H2O[J]. Acta Chim. Sinica, 2000,58:1191-1195.  

    14. [14]

      Hendriks H. M. J, Bokkel H. W. O, Reedijk J. Synthesis, characterization and complex formation of N,N,N',N'-tetrakis--[(2-benzimidazolyl) methyl]-1,2-ethanediamine, a new hexadentate ligand[J]. Recl Trav Chim. Pays-Bas, 1979,98:499-500.

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