Citation: ZHANG Xing-Jing, WANG Lu-Yao, WEI Bing, LI Meng, QIAO Yu, CHE Guang-Bo. Synthesis, Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1HTetrazol-5-yl)isophthalic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1213-1221. doi: 10.14102/j.cnki.0254-5861.2011-1029 shu

Synthesis, Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1HTetrazol-5-yl)isophthalic Acid Ligand

ZHANG Xing-Jing ^a,b ,
WANG Lu-Yao ^a ,
WEI Bing ^a ,
LI Meng ^a ,
QIAO Yu ^a,b ,
CHE Guang-Bo ^a,b

1.
a College of Chemistry, Jilin Normal University, Siping 136000, China;
2.
b Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping 136000, China

Received Date: 28 October 2015
Available Online: 12 January 2016
Fund Project: Supported by the National Natural Science Foundation of China (No. 21576112) (No. 21576112) the Program for New Century Excellent Talents in University (NCET-10-0176) of China and Natural Science Foundation Project of Jilin Province (No. 20130521019JH and 201215219) (NCET-10-0176)

A novel polymeric zinc(II) complex {[Zn₂(TIA)(H₂O)₃]·(NO₃)}_n (1, H₃TIA=5-(1H-tetrazol-5-yl)isophthalic acid) has been synthesized in mixed solvents under solvothermal conditions and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Complex 1 crystallizes in orthorhombic, space group Cmcm with a=10.4210(6), b=23.3526(14), c=6.9214(4)Å, V=1684.37(17)Å³, Z=4, C₉H₄N₅O₁₀Zn₂, M_r=472.91, D_c=1.865 g/cm³, F(000)=932, λ(MoKα)=2.909 mm^-1, R=0.0423 and wR=0.1287. The complex has good thermal stability and excellent photoluminescent property.
- zinc(II) complex,
- crystal structure,
- 5-(1H-tetrazol-5-yl)isophthalic acid,
- photoluminescence
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