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Citation: TU Chang-Zheng, MIAO Jiao-Jiao, HOU Neng-Bang, CHEN Guang, LI Jun-Li, YANG Yu-Ting. Two New Complexes with the Same (3,8)-Connected tfz-d Topology Based on [Co4(μ3-OH)2] Clusters and Different Aromatic Multicarboxylic Acids[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 903-913. doi: 10.14102/j.cnki.0254-5861.2011-1008 shu

Two New Complexes with the Same (3,8)-Connected tfz-d Topology Based on [Co4(μ3-OH)2] Clusters and Different Aromatic Multicarboxylic Acids

  • 1.

    Department of Chemistry and Engineering, Qujing Normal University, Qujing 655011, China

  • Corresponding author: YANG Yu-Ting, 
  • Received Date: 14 October 2015
    Available Online: 28 December 2015

    Fund Project: the major project of Qujing Normal University (2012ZD002) (201401CB00299)

  • Two new metal-organic frameworks (MOFs), namely, [Co2(L1)(bix)(µ3-OH)]·2H2O (1) and [Co2(L2)(bix)(µ3-OH)]·2.5H2O (2) (H3L1 = 5-oxyacetate isophthalic acid, H3L2 = 3,5-bis-oxyacetate-benzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), have been synthesized under hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra, and powder X-ray diffraction (PXRD) analysis. Both complexes 1 and 2 demonstrate identical three-dimensional (3D) (3,8)-connected tfz-d nets with (43)2(46·618·84) topologies, where the tetranuclear [Co4(μ3-OH)2] clusters act as 8-connected nodes and aromatic multicarboxylic ligands as 3-connected nodes. The results show that the ligands with different geometrical conformations can form products with the same topological structures. Their thermal and magnetic properties were also investigated.
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