Citation: LIN Liang, YU Yan. Application of Modified Nickel Slag Adsorbent on the Removal of Pb²⁺ and Cu²⁺ from Aqueous Solution[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 879-888. doi: 10.14102/j.cnki.0254-5861.2011-1002 shu

Application of Modified Nickel Slag Adsorbent on the Removal of Pb²⁺ and Cu²⁺ from Aqueous Solution

LIN Liang ^a ,
YU Yan ^b,c,,

a.
a. Department of Safety Technology and Environmental Engineering, Fujian Chuanzheng Communications College, Fuzhou 350007, China;
b.
b. College of Materials Science and Engineering, Fuzhou University, New Campus, Fuzhou 350108, China;
c.
c. Key Laboratory of Eco-materials Advanced Technology, Fuzhou 350116, China

Corresponding author: YU Yan,
Received Date: 28 October 2015
Available Online: 22 February 2016
Fund Project: Supported by the National Natural Science Foundation of China (Nos. 51102047 & 51472050) (Nos. 51102047 & 51472050)

Al(OH)₃ modified nickel slag adsorbent was prepared by sintering technology. The structure of the sample was characterized by BET, XRD, IR, SEM and EDAX. The sample's adsorption performance of Pb²⁺ and Cu²⁺ from aqueous solution was studied. Results indicated that the adsorbent is a loose and porous mesoporous material. Its surface had mass aluminosilicate, high-activity γ-Al₂O₃ and its pH ranges from 4 to 12 that all have negative charges. The BET surface of the adsorbent is 23.90 m²/g. Furthermore, its surface contains rich oxygenic functional groups, which could not only provide abundant adsorption sites for Pb²⁺ and Cu²⁺, but also improve the adsorption performance of Pb²⁺ and Cu²⁺ from waste water through the complexation of heavy metal ions. The best pH values selected in the adsorption of Pb²⁺ and Cu²⁺ are 6 and 5, respectively. With the increase of the initial concentration of simulated solution, the adsorption capacities of Pb²⁺ and Cu²⁺ gradually increased but the removal rates showed a downward trend. The competitive adsorption results of Pb²⁺ and Cu²⁺ showed that Pb²⁺ has better preferential adsorption than Cu²⁺.
- Al(OH)₃ modified,
- nickel slag,
- adsorption,
- lead ion,
- copper ion
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Application of Modified Nickel Slag Adsorbent on the Removal of Pb2+ and Cu2+ from Aqueous Solution

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Application of Modified Nickel Slag Adsorbent on the Removal of Pb²⁺ and Cu²⁺ from Aqueous Solution