Citation: ZHANG Xin, SUN Ming-Ling, QIN Ye-Yan, YAO Yuan-Gen. Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 914-920. doi: 10.14102/j.cnki.0254-5861.2011-1001 shu

Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology

a.
a. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: YAO Yuan-Gen,
Received Date: 9 September 2015
Available Online: 28 October 2015
Fund Project: Supported by the 973 Program of China (2011CBA00505) (2011CBA00505) the "Strategic Priority Research Program" of the Chinese Academy of Sciences (XDA07070200, XDA09030102) (XDA07070200, XDA09030102)

A new Cd(II) coordination polymer, namely {Cd₂(L)(biimpy)(H₂O)}_n (1, H₄L = 3-(3',5'-dicarboxylphenoxy)phthalic acid, biimpy = 2,6-bis(1-imdazoly)pyridine), has been success- fully synthesized via the hydrothermal reactions of Cd(II) ions, H₄L and biimpy. The crystal structure is of triclinic, space group P with a = 7.7874(5), b = 9.9716(5), c = 18.5278(6) Å, α = 91.327(4), β = 96.689(4), γ = 111.896(5)°, V = 1322.39(12) Å³, C₂₇H₁₇Cd₂N₅O₁₀, M_r = 796.26, Z = 2, D_c = 2.000 g/cm³, F(000) = 780, μ = 1.679 mm^-1, R= 0.0345 and wR= 0.0767 for 3890 observed reflections (I > 2s(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework based on two different dinuclear [Cd₂(COO)₂] building subunits, and topological analysis shows that it can be simplified into a binodal (4,6)-connected topological network with the point symbol of {3.4².5².6}{3².4².5².6⁴.7⁴.8}. Moreover, the thermal stability and luminescent property of compound 1 were also studied.
- Cd(II) compound,
- hydrothermal reaction,
- 3D framework,
- luminescence
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