Citation: JIN Suo, GU Qing-Yun, CHEN Jing, WANG Yang-Zhi, YUAN Guo-Zan. Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 929-938. doi: 10.14102/j.cnki.0254-5861.2011-0984 shu

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

a.
a. School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, China;
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b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 24 September 2015
Available Online: 2 December 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21201002) (No. 21201002) the Foundation of State Key Laboratory of Structural Chemistry (20130016) (20130016) Anhui Provincial Natural Science Foundation (1308085QB22) (1308085QB22)

In order to perform a study on the structural modulation in the Cd(II)-L architecture (HL = (E)-2-[2-(3-pyridyl)ethenyl]-8-hydroxyquinoline), two different dicarboxylic acids, namely, 2-aminoterephthalic acid (H₂ATA) and 4,4'-biphenyldicarboxylic acid (H₂BPDC), are employed as the secondary auxiliary ligands. Two new complexes [Cd₂L₂(ATA)] (1) and [Cd₂L₂(BPDC)·2MeOH· 4H₂O] (2) with distinct 3D frameworks were obtained. In complex 1, ligands ATA bridge the 1D Cd(II)-L infinite chains into a 3D polymeric coordination network. Complex 2 is a 3D porous framework, in which adjacent 2D Cd(II)-L coordination layers were linked together by the coor- dinated BPDC ligands. The variant structures of two complexes indicate that the skeleton of dicarboxylate anions plays a great role in the assembly of such different frameworks. In addition, the photoluminescent properties (fluorescent emission, lifetime, and quantum yield) of polymers 1 and 2 were also investigated in the solid state.
- coordination polymer,
- dicarboxylate,
- crystal structure,
- photoluminescence
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Crystal Structures and Photoluminescent Properties of Two Cd2+ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand

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通讯作者: 陈斌, bchen63@163.com

Crystal Structures and Photoluminescent Properties of Two Cd²⁺ Coordination Polymers Constructed from an 8-Hydroxyquinolinate Ligand