Citation: LI Sa-Ying. Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 980-986. doi: 10.14102/j.cnki.0254-5861.2011-0976 shu

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

LI Sa-Ying

1.
Department of Chemistry Chemical Engineering, Shaanxi Xueqian Normal University, Xi'an 710100, China

Received Date: 15 September 2015
Available Online: 7 January 2016
Fund Project: Project supported by College Programs SNIE (No. 2014ZDKJ011) (No. 2014ZDKJ011)

A new 3D cobalt metal-organic framework [C₇H₁₃N₂]₂[(CH₃COO)₂Co₇(oba)₅- (Hoba)₂(OH)₂]·H₂O has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, and TG. This complex crystallizes in monoclinic system, space group P2₁/c with a = 19.4499(4), b = 10.8839(2), c = 27.7796(5) Å, β = 104.467(2)°, V = 5694.22(19) Å³, Z = 2, C₁₁₆H₉₂Co₇N₄O₄₂, M_r = 2626.45, D_c = 1.532 g/cm³, F(000) = 2682, μ = 1.085 mm^-1, R = 0.0387 and wR = 0.1177. Its structure is characterized as a 3D open framework constructed by seven nuclear clusters [(CH₃COO)₂Co₇(OH)₂] and the 4,4'-oxybisbenzoic acid ligand. The used ILs cations are located in the middle of the pore and compensate for the negative charges of framework. Furthermore, its fluorescence property has also been studied.
- cobalt complex,
- ionothermal synthesis,
- crystal structure,
- fluorescence property
1. [1]
  (1) Janiak, C. Engineering coordination polymers towards applications. Dalton Trans. 2003, 32, 2781-2804.
2. [2]
  (2) Ma, L. Q.; Abney, C.; Lin, W. B. Enantioselective catalysis with homochiral metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1248-1256.
3. [3]
  (3) (a) Rogers, R. D.; Seddon, K. R. Ionic liquids-solvents of the future. Science 2003, 302, 792–793. (b) Kuhn, P.; Antonietti, M.; Thomas, A. Porous, covalent triazine-based frameworks prepared by ionothermal synthesis. Angew. Chem. Int. Ed. 2008, 47, 3450-3453.
4. [4]
  (4) (a) Parnham, E. R.; Morris, R. E. Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids. Acc. Chem. Res. 2007, 40, 1005-1003. (b) Morris, R. E. Ionothermal synthesis-ionic liquids as functional solvents in the preparation of crystalline materials. Chem. Commun. 2009, 21, 2990-2998. (c) Li, J. R.; Xie, Z. L.; He, X. W.; Li, L. H.; Huang, X. Y. Crystalline open-framework selenidostannates synthesized inionic liquids. Angew. Chem. Int. Ed. 2011, 50, 11395-11399.
5. [5]
  (5) Wang, X. F.; Zhang, Y. B.; Huang, H.; Zhang, J. P. Microwave-assisted solvothermal synthesis of a dynamic porous metal-carboxylate framework. Cryst. Growth Des. 2008, 12, 4559-4563.
6. [6]
  (6) Wang, J. M.; Li, B.; Sun, L.; Li, T. Synthesis, structure, thermostability and DFT calculations of a cobalt(Ⅱ) coordination compound constructed by oxybis (benzoic acid) and pyridyl-triazole. Chin. J. Inorg. Chem. 2014, 30, 683-689.
7. [7]
  (7) Zhang, C. L.; Qin, L.; Shi, Z. Z.; Zheng, H. G. Diverse structures of metal-organic frameworks based on different metal ions: luminescence and gas adsorption properties. Dalton Trans. 2015, 44, 4238-4245.
8. [8]
  (8) Zhao, N.; Liu, P.; An, C. X.; Wang, T. X.; Lian, Z. X. Structures and third-order nonlinear optical properties of two cobalt(II) coordination polymers constructed from bis(imidazol-l-yl-methyl) benzene and aromatic dicarboxylic ligands. Inorg. Chem. Commun. 2014, 50, 97-100.
9. [9]
  (9) Singha, D. K.; Mahata, P. Highly selective and sensitive luminescence turn-on-based sensing of Al³⁺ ions in aqueous medium using a MOF with free functional sites. Inorg. Chem. 2015, 54, 6373-6379.
10. [10]
  (10) Hu, F. L.; Wang, S. L.; Wu, B.; Yu, H.; Wang, F.; Lang, J. P. Ligand geometry-directed assembly of seven entangled coordination polymers. Cryst. Eng. Comm. 2014, 16, 6354-6363.
11. [11]
  (11) Xu, C. Y.; Li, L. K.; Wang, Y. P.; Guo, Q. Q.; Wang, X. J.; Hou, H. W.; Fan, Y. T. Three-dimensional Cd(II) coordination polymers based on semirigid bis(methylbenzimidazole) and aromatic polycarboxylates: syntheses, topological structures and photoluminescent properties. Cryst. Growth Des. 2011, 11, 4667-4675.
12. [12]
  (12) Qin, L.; Hu, J. S.; Zhang, M. D.; Yang, Q. X.; Li, Y. Z.; Zheng, H. G. Tuning structural topologies of a series of metal-organic frameworks: different bent dicarboxylates. Cryst. Growth Des. 2013, 13, 2111-2117.
13. [13]
  (13) Shi, Z. Q.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Six new 2D or 3D metal-organic frameworks based on bithiophene-containing ligand and dicarboxylates: syntheses, structures, and properties. Cryst. Growth Des. 2013, 13, 3078-3086.
14. [14]
  (14) Martin, D. P.; Supkowski, R. M.; LaDuca, R. L. Self-catenated and interdigitated layered coordination polymers constructed from kinked dicarboxylate and organodiimine ligands. Inorg. Chem. 2007, 46 , 7917-7922.
15. [15]
  (15) SAINT, Version 6.02A.; Bruker AXS Inc.: Madison W12002.
16. [16]
  (16) Sheldrick, G. M. SHELXL-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
17. [17]
  (17) Sheldrick, G. M. SHELXS-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
18. [18]
  (18) Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.
19. [19]
  (19) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330-1352.
20. [20]
  (20) Lee, T.; Zheng, X. L.; Lee. H. L. A biomimetic nose by microcrystals and oriented films of luminescent porous metal-organic frameworks. Cryst. Growth Des. 2011, 11, 4146-4154.
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Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH3COO)2Co7(OH)2] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

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通讯作者: 陈斌, bchen63@163.com

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand