Citation: LI Sa-Ying. Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 980-986. doi: 10.14102/j.cnki.0254-5861.2011-0976 shu

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

LI Sa-Ying

1.
Department of Chemistry Chemical Engineering, Shaanxi Xueqian Normal University, Xi'an 710100, China

Received Date: 15 September 2015
Available Online: 7 January 2016
Fund Project: Project supported by College Programs SNIE (No. 2014ZDKJ011) (No. 2014ZDKJ011)

A new 3D cobalt metal-organic framework [C₇H₁₃N₂]₂[(CH₃COO)₂Co₇(oba)₅- (Hoba)₂(OH)₂]·H₂O has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, and TG. This complex crystallizes in monoclinic system, space group P2₁/c with a = 19.4499(4), b = 10.8839(2), c = 27.7796(5) Å, β = 104.467(2)°, V = 5694.22(19) Å³, Z = 2, C₁₁₆H₉₂Co₇N₄O₄₂, M_r = 2626.45, D_c = 1.532 g/cm³, F(000) = 2682, μ = 1.085 mm^-1, R = 0.0387 and wR = 0.1177. Its structure is characterized as a 3D open framework constructed by seven nuclear clusters [(CH₃COO)₂Co₇(OH)₂] and the 4,4'-oxybisbenzoic acid ligand. The used ILs cations are located in the middle of the pore and compensate for the negative charges of framework. Furthermore, its fluorescence property has also been studied.
- cobalt complex,
- ionothermal synthesis,
- crystal structure,
- fluorescence property
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Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH3COO)2Co7(OH)2] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

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通讯作者: 陈斌, bchen63@163.com

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand