Citation: LI Sa-Ying. Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 980-986. doi: 10.14102/j.cnki.0254-5861.2011-0976 shu

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

LI Sa-Ying

1.
Department of Chemistry Chemical Engineering, Shaanxi Xueqian Normal University, Xi'an 710100, China

Received Date: 15 September 2015
Available Online: 7 January 2016
Fund Project: Project supported by College Programs SNIE (No. 2014ZDKJ011) (No. 2014ZDKJ011)

A new 3D cobalt metal-organic framework [C₇H₁₃N₂]₂[(CH₃COO)₂Co₇(oba)₅- (Hoba)₂(OH)₂]·H₂O has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, and TG. This complex crystallizes in monoclinic system, space group P2₁/c with a = 19.4499(4), b = 10.8839(2), c = 27.7796(5) Å, β = 104.467(2)°, V = 5694.22(19) Å³, Z = 2, C₁₁₆H₉₂Co₇N₄O₄₂, M_r = 2626.45, D_c = 1.532 g/cm³, F(000) = 2682, μ = 1.085 mm^-1, R = 0.0387 and wR = 0.1177. Its structure is characterized as a 3D open framework constructed by seven nuclear clusters [(CH₃COO)₂Co₇(OH)₂] and the 4,4'-oxybisbenzoic acid ligand. The used ILs cations are located in the middle of the pore and compensate for the negative charges of framework. Furthermore, its fluorescence property has also been studied.
- cobalt complex,
- ionothermal synthesis,
- crystal structure,
- fluorescence property
1. [1]
  (1) Janiak, C. Engineering coordination polymers towards applications. Dalton Trans. 2003, 32, 2781-2804.
2. [2]
  (2) Ma, L. Q.; Abney, C.; Lin, W. B. Enantioselective catalysis with homochiral metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1248-1256.
3. [3]
  (3) (a) Rogers, R. D.; Seddon, K. R. Ionic liquids-solvents of the future. Science 2003, 302, 792–793. (b) Kuhn, P.; Antonietti, M.; Thomas, A. Porous, covalent triazine-based frameworks prepared by ionothermal synthesis. Angew. Chem. Int. Ed. 2008, 47, 3450-3453.
4. [4]
  (4) (a) Parnham, E. R.; Morris, R. E. Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids. Acc. Chem. Res. 2007, 40, 1005-1003. (b) Morris, R. E. Ionothermal synthesis-ionic liquids as functional solvents in the preparation of crystalline materials. Chem. Commun. 2009, 21, 2990-2998. (c) Li, J. R.; Xie, Z. L.; He, X. W.; Li, L. H.; Huang, X. Y. Crystalline open-framework selenidostannates synthesized inionic liquids. Angew. Chem. Int. Ed. 2011, 50, 11395-11399.
5. [5]
  (5) Wang, X. F.; Zhang, Y. B.; Huang, H.; Zhang, J. P. Microwave-assisted solvothermal synthesis of a dynamic porous metal-carboxylate framework. Cryst. Growth Des. 2008, 12, 4559-4563.
6. [6]
  (6) Wang, J. M.; Li, B.; Sun, L.; Li, T. Synthesis, structure, thermostability and DFT calculations of a cobalt(Ⅱ) coordination compound constructed by oxybis (benzoic acid) and pyridyl-triazole. Chin. J. Inorg. Chem. 2014, 30, 683-689.
7. [7]
  (7) Zhang, C. L.; Qin, L.; Shi, Z. Z.; Zheng, H. G. Diverse structures of metal-organic frameworks based on different metal ions: luminescence and gas adsorption properties. Dalton Trans. 2015, 44, 4238-4245.
8. [8]
  (8) Zhao, N.; Liu, P.; An, C. X.; Wang, T. X.; Lian, Z. X. Structures and third-order nonlinear optical properties of two cobalt(II) coordination polymers constructed from bis(imidazol-l-yl-methyl) benzene and aromatic dicarboxylic ligands. Inorg. Chem. Commun. 2014, 50, 97-100.
9. [9]
  (9) Singha, D. K.; Mahata, P. Highly selective and sensitive luminescence turn-on-based sensing of Al³⁺ ions in aqueous medium using a MOF with free functional sites. Inorg. Chem. 2015, 54, 6373-6379.
10. [10]
  (10) Hu, F. L.; Wang, S. L.; Wu, B.; Yu, H.; Wang, F.; Lang, J. P. Ligand geometry-directed assembly of seven entangled coordination polymers. Cryst. Eng. Comm. 2014, 16, 6354-6363.
11. [11]
  (11) Xu, C. Y.; Li, L. K.; Wang, Y. P.; Guo, Q. Q.; Wang, X. J.; Hou, H. W.; Fan, Y. T. Three-dimensional Cd(II) coordination polymers based on semirigid bis(methylbenzimidazole) and aromatic polycarboxylates: syntheses, topological structures and photoluminescent properties. Cryst. Growth Des. 2011, 11, 4667-4675.
12. [12]
  (12) Qin, L.; Hu, J. S.; Zhang, M. D.; Yang, Q. X.; Li, Y. Z.; Zheng, H. G. Tuning structural topologies of a series of metal-organic frameworks: different bent dicarboxylates. Cryst. Growth Des. 2013, 13, 2111-2117.
13. [13]
  (13) Shi, Z. Q.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Six new 2D or 3D metal-organic frameworks based on bithiophene-containing ligand and dicarboxylates: syntheses, structures, and properties. Cryst. Growth Des. 2013, 13, 3078-3086.
14. [14]
  (14) Martin, D. P.; Supkowski, R. M.; LaDuca, R. L. Self-catenated and interdigitated layered coordination polymers constructed from kinked dicarboxylate and organodiimine ligands. Inorg. Chem. 2007, 46 , 7917-7922.
15. [15]
  (15) SAINT, Version 6.02A.; Bruker AXS Inc.: Madison W12002.
16. [16]
  (16) Sheldrick, G. M. SHELXL-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
17. [17]
  (17) Sheldrick, G. M. SHELXS-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
18. [18]
  (18) Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.
19. [19]
  (19) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330-1352.
20. [20]
  (20) Lee, T.; Zheng, X. L.; Lee. H. L. A biomimetic nose by microcrystals and oriented films of luminescent porous metal-organic frameworks. Cryst. Growth Des. 2011, 11, 4146-4154.
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
5. [5]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
6. [6]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
7. [7]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
10. [10]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
11. [11]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
12. [12]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
13. [13]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
14. [14]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
15. [15]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
16. [16]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
17. [17]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
18. [18]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
19. [19]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
20. [20]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(751)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH3COO)2Co7(OH)2] Clusters and 4,4'-Oxybisbenzoic Acid Ligand

Metrics

通讯作者: 陈斌, bchen63@163.com

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear (CH₃COO)₂Co₇(OH)₂] Clusters and 4,4'-Oxybisbenzoic Acid Ligand