Citation: LIU Ying, WANG Yu-Ling, CHEN Ling, LIU Qing-Yan, YAO Yang. Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 921-928. doi: 10.14102/j.cnki.0254-5861.2011-0974 shu

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n

1.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Received Date: 15 September 2015
Available Online: 27 November 2015
Fund Project:

The reaction of Cd(NO₃)₂·4H₂O with 4,4'-dipyridylacetylene (4,4'-DPA) and 2-nitroterephthalic acid (2-NO₂-H₂BDC) in DMF/H₂O mixed solvent has afforded a compound {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n (1). Compound 1 has been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry analysis, and IR spectrum. Com- pound 1 crystallizes in the monoclinic system, space group P2₁/n, with a = 12.1488(3), b = 14.6689(3), c = 13.1615(3) Å, β = 111.809(3)^o, V = 2177.63(9) Å³, Z = 4, C₂₃H₁₈ N₄O₇Cd, M_r= 574.81, D_c= 1.753 g/cm³, μ = 8.523 mm^-1, F(000) = 1152, the final R = 0.0411 and wR = 0.1064 for 3589 observed reflections with I > 2s(I). In compound 1, the Cd(II) ions are linked by the carboxylate groups of 2-NO₂-BDC ligands to give a two-dimensional layered structure based on the centrosymmetric dinuclear Cd₂(COO)₂ units, which are further connected by the 4,4'-DPA ligands to produce a three-dimensional framework with pcu topology. Careful examination revealed that compound 1 is a 2-fold interpenetrating framework. Furthermore, the gas adsorption properties of 1 for N₂ and CO₂ have also been investigated.
- synthesis,
- 2-fold interpenetrating framework,
- crystal structure,
- gas adsorption
1. [1]
  (1) Eddaoudi, M.; Moler, D. B.; Li, H. L.; Chen, B. L.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Acc. Chem. Res. 2001, 34, 319–330.
2. [2]
  (2) Chen, X.; Zhang, M. X.; Huang, K. L.; Xiao, F.; Zhang, X. P. A 3-connected 3D microporous metal-organic framework with intersected channels and rare DEH topology. Chin. J. Struct. Chem.2014, 33, 1831-1835.
3. [3]
  (3) D'Alessandro, D. M.; Smit, B.; Long, J. R. Carbon dioxide capture: prospects for new materials. Angew. Chem., Int. Ed. 2010, 49, 6058–6082.
4. [4]
  (4) Yoon, M.; Srirambalaji, R.; Kim, K. Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis. Chem. Rev. 2012, 112, 1196–1231.
5. [5]
  (5) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Luminescent metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1330–1352.
6. [6]
  (6) He, Y. P.; Tan, Y. X.; Zhang, J. Organic cation templated synthesis of three zinc-2,5-thiophenedicarboxylate frameworks for selective gas sorption. Cryst. Growth Des. 2014, 14, 3493–3498.
7. [7]
  (7) Wang, C.; Liu, D.; Lin, W. Metal-organic frameworks as a tunable platform for designing functional molecular materials. J. Am. Chem. Soc. 2013, 135, 13222–13234.
8. [8]
  (8) Wang, X. Y.; Wang, Z. M.; Gao, S. Constructing magnetic molecular solids by employing three-atom ligands as bridges. Chem. Commun. 2008, 281–294.
9. [9]
  (9) Rocca, J. D.; Liu, D.; Lin, W. B. Nanoscale metal-organic frameworks for biomedical imaging and drug delivery. Acc. Chem. Res. 2011, 44, 957–968.
10. [10]
  (10) Norbert, S.; Shyam, B. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chem. Rev. 2012, 112, 933–936.
11. [11]
  (11) Ma, A. Q.; Zhu, L. G. Unprecedented but the long-waited 3D hydroxide layered single-crystal structure, [Cu₂(OH)₂(nbdc)(H₂O)]_n. Inorg. Chem Commun. 2004, 7, 186–188.
12. [12]
  (12) Zhu, L. G.; Ma, A. Q.; Lu, J. Y. A new nitrophenyldicarboxylato-bridged tetranuclear-copper complex linked into a polymeric network showing intense fluorescent emissions, Inorg. Chem Commun. 2004, 7, 1053–1055.
13. [13]
  (13) Wang, Y. L.; Jiang, Y. L.; Fu, Y.; Liu, Q. Y.; Tan, Y. X.; Wei, J. J.; Zhang, J. A series of three-dimensional lanthanide(III) coordination polymers of 2,5-dihydroxy-1,4-benzenedicarboxylic acid based on dinuclear lanthanide units. CrystEngComm. 2011, 13, 4981–4987.
14. [14]
  (14) Dietzel, P. D. C.; Panella, B.; Hirscher, M.; Blom, R.; Fjellvag, H. Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework. Chem. Commun. 2006, 24, 959–294.
15. [15]
  (15) Xia, C. K.; Wu, X. Y.; Wu, M.; Lu, C. Z. Synthesis and crystal structure of a two-dimensional cadmium complex based on terephthalate and 1-methyl-2,2'-bibenzimidazole. Chin. J. struct. Chem. 2013, 32, 585-589.
16. [16]
  (16) Groeneman, R. H.; MacGillivray, L. R.; Atwood, J. L. Aromatic inclusion within a neutral cavity-containing rectangular grid. Chem. Commun. 1998, 2735–2736.
17. [17]
  (17) Hijikata, Y.; Horike, S.; Sugimoto, M.; Sato, H.; Matsuda, R.; Kitagawa, S. Relationship between channel and sorption properties in coordination polymers with interdigitated structures. Chem. Eur. J. 2011, 17, 5138–5144.
18. [18]
  (18) Ma, L. F.; Li, X. Q.; Meng, Q. L.; Wang, L. Y.; Du, M.; Hou, H. W. Significant positional isomeric effect on structural assemblies of Zn(II) and Cd(II) coordination polymers based on bromoisophthalic acids and various dipyridyl-type coligands. Crystal Growth & Design 2011, 1, 175–181.
19. [19]
  (19) Kanoo, P.; Maji, T. K. Construction of a 2D rectangular grid and 3D diamondoid interpenetrated frameworks and their functionalities by changing the second spacers. Eur. J. Inorg. Chem. 2010, 5, 3762–3769.
20. [20]
  (20) Lan, A. J.; Li, K. H.; Wu, H. H.; David, H. O.; Li, J. A luminescent microporous metal organic framework for the fast and reversible detection of high explosives. Angew. Chem. Int. Ed. 2009, 48, 2334–2338.
21. [21]
  (21) Li, G. L.; Liu, G. Z.; Ma, L. F.; Xin, L. Y.; Li, L.; Wang, L. Y. Crystallographic determination of solid-state structural transformations in a dynamic metal–organic framework. Chem. Commun. 2014, 50, 2615–2617.
22. [22]
  (22) Zaman, M. B.; Smith, M. D.; Ciurtin, D. M.; Loye, H. C. Z. New Cd(II)-, Co(II)-, and Cu(II)-containing coordination polymers synthesized by using the rigid ligand 1,2-bis(3-pyridyl)ethyne (3,3'-DPA). Inorg. Chem. 2002, 41, 4895–4903.
23. [23]
  (23) Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Solution. University of Göttingen, Germany 1997.
24. [24]
  (24) Sheldrick, G. M. SHELXL-97, program for X-ray Crystal Structure Refinement. University of Göttingen, Germany 1997.
25. [25]
  (25) Sheldrick, G. M. A short history of SHELXTL. Acta Crystallogr. Sect. A 2008, 64, 112–122.
26. [26]
  (26) Salles, F.; Jobic, H.; Devic, T. Self and transport diffusivity of CO₂ in the metal-organic framework MIL-47(V) explored by quasi-elastic neutron scattering experiments and molecular dynamics simulations. ACS Nano. 2010, 4, 143–152.
27. [27]
  (27) Bohnsack, A. M.; Ibarra, I. A.; Hatfield, P. W. High capacity CO₂ adsorption in a Mg(II)-based phosphine oxide coordination material. Chem. Commun. 2011, 47, 4899–4901.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO2-BDC)(4,4'-DPA)]·(DMF)}n

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Gas Adsorption of a Two-fold Interpenetrated Three-dimensional Framework {[Cd(2-NO₂-BDC)(4,4'-DPA)]·(DMF)}_n