Citation: WANG Xiao-Ning, WANG Yu-Fang, GENG Jun-Lei, LI Fei-Fei. Synthesis, Structure and Magnetic Property of a New Three-dimensional Copper(II) Coordination Polymer Constructed from 5-Tert-butyl Isophthalic Acid and N-donor Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 953-958. doi: 10.14102/j.cnki.0254-5861.2011-0973 shu

Synthesis, Structure and Magnetic Property of a New Three-dimensional Copper(II) Coordination Polymer Constructed from 5-Tert-butyl Isophthalic Acid and N-donor Ligand

a.
a. Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, China;
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b. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Received Date: 10 September 2015
Available Online: 6 December 2015
Fund Project:

A new 3D copper(II) coordination polymer, {[Cu₂(tbip)₂(1,3,5-tib)]·2H₂O}_n (1, H₂tbip = 5-tert-butyl isophthalic acid, 1,3,5-tib = 1,3,5-tris(1-imidazolyl)benzene), has been synthe- sized by hydrothermal reaction of Cu(OAc)₂·4H₂O, H₂tbip and 1,3,5-tib. It has been structurally characterized by element analysis, IR and magnetic measurement. X-ray single-crystal analysis was carried out for 1, which crystallizes in the triclinic system, space group P with a = 7.822(3), b = 15.854(6), c = 17.553(6) Å, a = 113.033(4), β = 90.694(4), g = 101.006(4)°, V = 1957.3(12) Å³, Z = 1, D_c = 1.493 g/cm³, M_r = 1759.70, F(000) = 908, R = 0.0721 and wR = 0.1978 with I > 2s(I). The single-crystal X-ray diffraction studies reveal that compound 1 exhibits 2D [Cu(tbip)] layers which are further pillared by 1,3,5-tib ancillary ligand with terminal tridentate coordination mode to generate the final 3D structure. Magnetic susceptibility data for 1 have been measured in the range of 2~300 K. There are antiferromagnetic interactions between copper ions of the compound.
- copper(II),
- coordination polymer,
- antiferromagnetic interaction
1. [1]
  (1) Chen, H. J.; Mao, Z. W.; Gao S.; Chen, X. M. Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits. Chem. Commun. 2001, 2320–2321.
2. [2]
  (2) Wu, D. C.; Xu, F.; Sun, B.; Fu, R. W.; He, H. K.; Matyjaszewski, K. Design and preparation of porous polymers. Chem. Rev. 2012, 112, 3959–4015.
3. [3]
  (3) Sanna, A.; Uibu, M.; Caramanna, G.; Kuusik, R.; Maroto-Valer, M. M. A review of mineral carbonation technologies to sequester CO₂. Chem. Soc. Rev. 2014, 43, 8049–88080.
4. [4]
  (4) Tang, C. W.; VanSlyke, S. A. Organic electroluminescent diodes. Appl. Phys. Lett. 1987, 51, 913–915.
5. [5]
  (5) Yu, Z. Q.; Pan, M.; Jiang, J. J.; Liu, Z. M.; Su, C. Y. Anion modulated structural diversification in the assembly of Cd(II) complexes based on a balance-like dipodal ligand. Cryst. Growth Des. 2012, 12, 2389–2396.
6. [6]
  (6) Du, M.; Li, C. P.; Liu, C. S.; Fang, S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy. Coord. Chem. Rev. 2013, 257, 1282–1305.
7. [7]
  (7) Gu, J. Z.; Gao, Z. Q.; Tang, Y. pH and auxiliary ligand influence on the structural variations of 5(2'-carboxylphenyl) nicotate coordination polymers. Cryst. Growth Des. 2012, 12, 3312–3323.
8. [8]
  (8) Stepenson, A.; Ward, M. D. A triple helix of double helicates: three hierarchical levels of self-assembly in a single structure. Chem. Commun. 2012, 3605–3607.
9. [9]
  (9) Ji, B. M.; Deng, D. S.; Ma, N.; Miao, S. B.; Yang, X. G.; Ji, L. G.; Du, M. Multicomponent hydrogen-bonding salts constructed from tris(2-benzimidazylmethyl)amine and various carboxylic acids: role of benzimidazolium-carboxylate supramolecular heterosynthons on network assembly. Cryst. Growth Des. 2010, 10, 3060–3069.
10. [10]
  (10) Zhong, D. C.; Deng, J. H.; Luo, X. Z.; Liu, H. J.; Zhong, J. L.; Wang, K. J.; Lu, T. B. Two cadmium-cluster-based metal-organic frameworks with mixed ligands of 1,2,3-benzenetriazole (HBTA) and 1,4-benzenedicarboxylic acid (H₂BDC). Cryst. Growth Des. 2012, 12, 1992–1998.
11. [11]
  (11) Zhang, X. J.; Wang, L. Y.; Wei, B.; Zhang, W. T.; Che, G. B. Syntheses, structures and photoluminescence of cadmium(II) and copper(II) complexes based on 4'-(4''-pyridyl)-2,2',6',2''-terpyridine and 1,4-benzenedicarboxylic acid ligands. Chin. J. Struct. Chem. 2015, 34, 1069–1079.
12. [12]
  (12) Sudik, A. C.; Côté, A. P.; Yaghi, O. M. Metal-organic frameworks based on trigonal prismatic building blocks and the new “acs” topology. Inorg. Chem. 2005, 44, 2998–3000.
13. [13]
  (13) Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Determination. University of Gottingen, Germany 1997.
14. [14]
  (14) Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. University of Gottingen, Germany 1997.
15. [15]
  (15) Liu, L.; Huang, C.; Zhang, L.; Ding, R.; Xue, X. N.; Hou, H. W.; Fan, Y. T. Co(II)/Mn(II)/Cu(II) coordination polymers based on flexible 5,5'-(hexane-1,6-diyl)-bis(oxy)diisophthalic acid: crystal structures, magnetic properties, and catalytic activity. Cryst. Growth Des. 2015, 15, 2712–2722.
16. [16]
  (16) Pérez-Yáńez, S.; Beobide, G.; Castillo, O.; Cepeda, J.; Luque, A.; Román, P. Directing the formation of adenine coordination polymers from tunable copper(II)/dicarboxylato/adenine Paddle-Wheel building units. Cryst. Growth Des. 2012, 12, 3324–3334.
17. [17]
  (17) Wang, S. H.; Zheng, F. K.; Wu, M. F.; Liu, Z. F.; Chen, J.; Xiao, Y.; Li, R.; Guo, G. C. Assembly of Co(II)/Cu(II)-azido polynuclear polymers: structural diversity and magnetic behavior. CrystEngComm. 2014, 16, 2009–2015.
18. [18]
  (18) Navarro, J. A. R.; Romero, M. A.; Salas, J. M.; Quirós, M.; Tiekink, R. T. First example of equatorial-equatorial disposition of end-to-end thiocyanate bridges in a polynuclear copper(II) complex and its relation to the very efficient transmission of the magnetic interaction. Inorg. Chem. 1997, 36, 4988–4991.
19. [19]
  (19) Dias, S. S. P.; André, V.; Klak, J.; Duarte, M. T.; Kirillov, A. M. Topological diversity of supramolecular networks constructed from copper(II) aminoalcohol blocks and 2,6-naphthalenedicarboxylate linkers: self-assembly synthesis, structural features, andmagnetic properties. Cryst. Growth Des. 2014, 14, 3398–3407.
20. [20]
  (20) Li, X.; Cheng, D. Y.; Lin, J. L.; Li, Z. F.; Zheng, Y. Q. Di-, tetra-, and hexanuclear hydroxy-bridged copper(II) cluster compounds: syntheses, structures, and properties. Cryst. Growth Des. 2008, 8, 2853–2861.
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