Citation: MIAO Yan-Li, WANG Hong-Bo, GU Chang-Sheng, LI Yong. Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 973-979. doi: 10.14102/j.cnki.0254-5861.2011-0966 shu

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

a.
a. College of Science, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. School of Navigation, Wuhan University of Technology, Wuhan 430063, China

Received Date: 2 September 2015
Available Online: 14 January 2016
Fund Project: This work was supported by Guangdong Ocean University with doctor start-up fund (1112263) (1112263)

Two novel clusters [Mn^III₃(m₃-O)(phendox)₃]X·13H₂O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H₂phendox) with MnCl₂·4H₂O or anhydrous MnBr₂, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P3₁/c. X-ray analysis reveals that the neighbouring [Mn₃(m₃-O)(phendox)₃]⁺ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox^2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H₂O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO₂.
- clusters,
- 1,10-phenanthroline-2,9-dicarbaldehyde dioxime,
- crystal structure,
- gas adsorption
1. [1]
  (1) Mukhopadhyay, S.; Mandal, S. K.; Bhaduri, S.; Armstrong, W. H. Manganese clusters with relevance to photosystem II. Chem. Rev. 2004, 104, 3981-4026.
2. [2]
  (2) Aromi, G.; Brechin, E. K. Synthesis of 3d metallic single-molecule magnets. Struct. Bonding 2006, 122, 1-67.
3. [3]
  (3) Gatteschi, D.; Sessoli, R. Quantum tunneling of magnetization and related phenomena in molecular materials. Angew. Chem. Int. Ed. 2003, 42, 268-297.
4. [4]
  (4) Christou, G. Single-molecule magnets: a molecular approach to nanoscale magnetic materials original. Polyhedron 2005, 24, 2065–2075.
5. [5]
  (5) (a) Liu, J. L.; Huang, G. Z.; Tong, M. L. Field-induced dynamic magnetic behavior of a canted weak ferromagnetic chain material. Inorg. Chem. Front. 2015, 2, 403-408. (b) Liu, J. L.; Liu, W.; Huang, G. Z.; Tong, M. L. A breathing chiral molecular solid for enantioselective separation via crystal-to-crystal transformation. Sci. Bull. 2015, 60, 447-452. (c) Wang, W. G.; Zhou, A. J.; Zhang, W. X.; Tong, M. L.; Chen, X. M.; Nakano, M.; Beedle, C. C.; Hendrickson, D. N. Giant heterometallic Cu₁₇Mn₂₈ cluster with Td symmetry and high-spin ground state. J. Am. Chem. Soc. 2007, 129, 1014-1015. (d) Zhou, A. J.; Qin, L. J.; Beedle, C. C.; Ding, S.; Nakano, M.; Leng, J. D.; Tong, M. L.; Hendrickson, D. N. New Mn₁₂ clusters with tunable oxidation states via the use of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine. Inorg. Chem. 2007, 46, 8111-8113. (e) Zheng, Y. Z.; Xie, W.; Zhang, W. X.; Tong, M. L.; Chen, X. M. From pseudo to true C₃-symmetry: magnetic anisotropy enhanced by site-specific ligand substitution in two Mn₁₅-carboxylate clusters. Inorg. Chem. 2007, 46, 6437-6443. (f) Zhou, A. J.; Liu, J. L.; Herchel, R.; Leng, J. D.; Tong, M. L. High-spin tetranuclear Mn^II₂Mn^IV₂ clusters with unique Mn(II)-Mn(IV) magnetic exchange. Synthesis, structures and magnetic properties of Mn₄ and Fe₄ clusters with tetrakis(2-hydroxyethyl)ethylenediamine. Dalton Trans. 2009, 3182-3192.
6. [6]
  (6) Kaes, C.; Katz, A.; Hosseini, M. W. The most widely used ligand. A review of molecules comprising at least two 2,2'-bipyridine units. Chem. Rev. 2000, 100, 3553-3590.
7. [7]
  (7) (a) Angeloff, A.; Daran, J. C.; Bernadou, J.; Meunier, B. The ligand 1,10-phenanthroline-2,9-dicarbaldehyde dioxime can act both as a tridentate and as a tetradentate ligand - synthesis, characterization and crystal structures of its transition metal complexes. Eur. J. Inorg. Chem. 2000, 1985-1996; (b) Fan, L. L.; Li, C. J.; Meng, Z. S.; Tong, M. L. Metal-mediated one-step in situ oxidation of 2,9-dimethyl-1,10-phenanthroline and formation of transition-metal and lanthanoid complexes. Eur. J. Inorg. Chem. 2008, 3905-3909.
8. [8]
  (8) Alborés, P.; Rentschler, E. A. A. T-shaped m₃-oxido trinuclear iron cluster with high easy-plane anisotropy: structural and magnetic characterization. Eur. J. Inorg. Chem. 2008, 4004-4011.
9. [9]
  (9) (a) Sreerama, S. G.; Pal, S. A triiron complex containing the carboxylate-free {Fe₃(m₃-O)}⁷⁺ core and distorted pentagonal-bipyramidal metal centers. Eur. J. Inorg. Chem. 2004, 4718-4723; (b) Sreerama, S. G.; Pal, S. A novel carboxylate-free ferromagnetic trinuclear μ₃-oxo-manganese(III) complex with distorted pentagonal-bipyramidal metal centers. Inorg. Chem. 2002, 41, 4843-4845.
10. [10]
  (10) (a) Miao, Y. L.; Liu, J. L.; Lin, Z. J.; Ou, Y. C.; Leng, J. D.; Tong, M. L. Synthesis, structures, adsorption behavior and magnetic properties of a new family of polynuclear iron clusters. Dalton Trans. 2010, 39, 4893-4902. (b) Miao, Y. L.; Liu, J. L.; Leng, J. D.; Lin, Z. J.; Tong, M. L. Chloride templated formation of {Dy₁₂(OH)₁₆}²⁰⁺ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate. CrystEngComm. 2011, 13, 3345-3348. (c) Miao, Y. L.; Liu, J. L.; Li, J. Y.; Leng, J. D.; Ou, Y. C.; Tong, M. L. Two novel Dy₈ and Dy₁₁ clusters with cubane [Dy₄(m₃-OH)₄]⁸⁺ units exhibiting slow magnetic relaxation behavior. Dalton Trans. 2011, 40, 10229-10236. (d) Miao, Y. L.; Liu, J. L.; Guo, F. S.; Tong, M. L. Synthesis, structures and magnetic properties of octahedral clusters of [M^II₆(m₆-Cl)(phenda)₆]^- (M = Mn, Co and Ni; phenda = 1,10-phenanthroline-2,9-dicarboxylate). Inorg. Chem. Comm. 2015, 52, 77-79.
11. [11]
  (11) Chandler, C. J.; Deady, L. W.; Reiss, J. A. Synthesis of some 2,9-disubstituted-1,10-phenanthrolines. J. Heterocycl. Chem. 1981, 18, 599-601.
12. [12]
  (12) (a) Blessing, R. H. An empirical correction for absorption anisotropy. Acta Cryst. 1995, A51, 33-38; (b) Sheldrick, G. M. SADABS 2.05, Area-detector Absorption Correction. University of Göttingen, Germany 1996.
13. [13]
  (13) SHELXTL 6.10, Bruker Analytical Instrumentation, Madison, Wisconsin, USA 2000.
14. [14]
  (14) (a) Angeloff, A.; Daran, J. C.; Bernadou, J.; Meunier, B. The Ligand 1,10-phenanthroline-2,9-dicarbaldehyde dioxime can act both as a tridentate and as a tetradentate ligand. Synthesis, characterization and crystal structures of its transition metal complexes. Eur. J. Inorg. Chem. 2000, 1985-1996; (b) Sreerama, S. G.; Pal, S. A novel carboxylate-free ferromagnetic trinuclear m₃-oxo-manganese(III) complex with distorted pentagonal-bipyramidal metal centers. Inorg. Chem. 2002, 41, 4843-4849.
15. [15]
  (15) Dalice, P.; Peter, B.; Roman, B.; Radovan, H.; Michael, K.; Raphael, G. R.; Franz, R.; Yiannis, S. A pyrazolate-supported Fe₃(m₃-O)-core; structural, spectroscopic, electrochemical and magnetic study. Inorg. Chem. 2007, 46, 10981-10989.
1. [1]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
2. [2]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
3. [3]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
4. [4]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
5. [5]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
6. [6]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
7. [7]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
10. [10]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
11. [11]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
12. [12]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
13. [13]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
14. [14]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
15. [15]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
16. [16]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
17. [17]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
18. [18]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
19. [19]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
20. [20]
  Yijia Jiao , Yuzhu Li , Yuting Zhou , Peipei Cen , Yi Ding , Yan Guo , Xiangyu Liu . Structural evolution and zero-field SMM behaviour in ferromagnetically-coupled disk-type Co₇ clusters bearing exclusively end-on azido bridges. Chinese Chemical Letters, 2024, 35(8): 109082-. doi: 10.1016/j.cclet.2023.109082

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(657)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142