Citation: WU Zhen-Dong. Synthesis, Structure and Photoluminescence of a New Pb(II) Coordination Polymer [Pb(1, 4-chdc)(L)]_n·nH₂OBased on a Flexible 1,4-Cyclohexanedicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 753-757. doi: 10.14102/j.cnki.0254-5861.2011-0958 shu

Synthesis, Structure and Photoluminescence of a New Pb(II) Coordination Polymer [Pb(1, 4-chdc)(L)]_n·nH₂OBased on a Flexible 1,4-Cyclohexanedicarboxylic Acid

WU Zhen-Dong ^,

1.
Department of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China

Corresponding author: WU Zhen-Dong,
Received Date: 25 August 2015
Available Online: 10 November 2015
Fund Project: Project supported by the National Natural Science Foundation of China (No. 51474086 ) (No. 51474086 )

A new Pb(II) coordination polymer, [Pb(1,4-chdc)(L)]_n·nH₂O (1), was synthesized under hydrothermal condition (1,4-H₂chdc = 1,4-cyclohexanedicarboxylic acid and L = 2-(3-fluoro-phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline). Its crystal structure was determined by single-crystal X-ray diffraction. Compound 1 crystallizes in triclinic, space group P1 with a = 9.1182(8), b = 11.3249(10), c = 12.7326(12) Å, α = 77.897(2), β = 81.644(2), γ = 84.491(2)°, V = 1269.0(2) Å³, Z = 2, C₂₇H₂₄FN₄O₅Pb, M_r = 710.69, D_c = 1.860 g/cm³, F(000) = 690, μ(MoKa) = 6.701 mm^-1, R = 0.0349 and wR = 0.0746. In 1, each 1,4-chdc anion bridges two neighboring Pb(II) atoms in a bidentate chelating coordination mode to give a chain structure. The L ligands are attached on one side of the chain through chelating the Pb(II) atoms, and are stacked with those of an adjacent chain through π-π interactions, yielding a layer structure. The O–H…O and N–H…O hydrogen bonding interactions further stabilize the supramolecular layer structure of 1. Moreover, solid state luminescent property of 1 was also studied.
- crystal structure,
- coordination polymer,
- 1,
- 4-cyclohexanedicarboxylic acid,
- luminescent property
1. [1]
  (1) Knichal, J. V.; Gee, W. J.; Burrows, A. D.; Raithby, P. R.; Wilson, C. C. Role of ethynyl-derived weak hydrogen-bond interactions in the supramolecular structures of 1D, 2D, and 3D coordination polymers containing 5-ethynyl-1,3-benzenedicarboxylate. Cryst. Growth Des. 2015, 15, 465-474.
2. [2]
  (2) Luo, L.; Chen, K.; Liu, Q.; Lu, Y.; Okamura, T.; Lv, G. C.; Zhao, Y.; Sun, W. Y. Zinc(II) and cadmium(II) complexes with 1,3,5-benzenetricarboxylate and imidazole-containing ligands: structural variation via reaction temperature and solvent. Cryst. Growth Des. 2013, 13, 2312-2321.
3. [3]
  (3) Su, Z.; Fan, J.; Okamura, T.; Sun, W. Y.; Ueyama, N. Ligand-directed and pH-controlled assembly of chiral 3d-3d heterometallic metal-organic frameworks. Cryst. Growth Des. 2010, 10, 3515-3521.
4. [4]
  (4) Yang, Y.; Du, P.; Ma, J. F.; Kan, W. Q.; Liu, B.; Yang, J. A series of metal-organic frameworks based on different salicylic derivatives and 1,1'-(1,4-butanediyl)bis(imidazole) ligand: syntheses, structures, and luminescent properties. Cryst. Growth Des. 2011, 11, 5540-5553.
5. [5]
  (5) Kong, Z. G.; Sun, X. R.; Jin, X. M.; Liu, B.; Chen, W. W. Synthesis, crystal structure, thermal behavior and photoluminescent property of complex [Zn(L)(SO₄)]·0.5H₂O. Chin. J. Struct. Chem. 2013, 32, 1019-1022.
6. [6]
  (6) Bradshaw, D.; Claridge, J. B.; Cussen, E. J.; Prior, T. J.; Rosseinsky, M. J. J. Design, chirality, and flexibility in nanoporous molecule-based materials. Acc. Chem. Res. 2005, 38, 273-282.
7. [7]
  (7) Ockwig, N. W.; Delgado-Friedrichs, O.; O’Keeffe, M.; Yaghi, O. M. Reticular chemistry: occurrence and taxonomy of nets and grammar for the design of frameworks. Acc. Chem. Res. 2005, 38, 176-182.
8. [8]
  (8) Wang, X. Y.; Liu, R.; Li, F. Y.; Meng, X. Y.; Sun, Q. H.; Zhao, Z. Y. Crystal structure and luminescence of a new Zn(II) complex [Zn(L)(IPP)(H₂O)]·2H₂O based on nicotinate derivative and 1,10-phenanthroline derivative. Chin. J. Struct. Chem. 2015, 34, 960-964.
9. [9]
  (9) Wang, X. Y.; Zhao, Z. Y.; Liu, R.; Xu, Y.; Li, X. H.; Xu, Z. L. Synthesis, crystal structure and luminescence of a new Zn(II) complex [Zn(1,2,3-HBTC)(L)]₂ constructed by mixed ligands. Chin. J. Struct. Chem. 2015, 34, 725-728.
10. [10]
  (10) Kong, Z. G.; Sun, X. R.; Guo, S. N.; Xiao, Y. B.; Pang, G. J. Synthesis, structure and physical property of a new 3D lead coordination polymer: [Pb₂(L)₂(dea)]_n·nH₂O. Chin. J. Struct. Chem. 2013, 32, 1031-1035.
11. [11]
  (11) Yang, J.; Li, G. D.; Cao, J. J.; Yue, Q.; Li, G. H.; Chen, J. S. Structural variation from 1D to 3D: effects of ligands and solvents on the construction of lead(II)-organic coordination polymers. Chem. Eur. J. 2007, 13, 3248-3261.
12. [12]
  (12) Kong, Z. G.; Wang, W.; Zhang, S. Q.; Zhao, Y. F.; Wang, X. Y. Synthesis, crystal structure, physical properties and theoretical calculations of a new one-dimensional Ni(II) coordination polymer constructed by 1,10-phenanthroline derivative ligand and sulfate. J. Inorg. Organomet. Polym. 2015, 25, 1441-1447.
13. [13]
  (13) Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structure. University of Göttingen 1997.
14. [14]
  (14) Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structure. University of Göttingen 1997.
15. [15]
  (15) Li, S. H.; Gao, S. K.; Liu, S. X.; Guo, Y. N. Five metal(II) coordination polymers constructed from two vanillin derivatives: from discrete structure to 3D diamondoid network. Cryst. Growth Des. 2010, 10, 495-503.
16. [16]
  (16) Zhang, K.; Jin, C.; Sun, Y.; Chang, F.; Huang, W. Base-induced self-assembly for one-dimensional coordination polymers via chiral pendant-armed Schiff base mononuclear Pb(II) macrocycles. Inorg. Chem. 2014, 53, 7803-7805.
17. [17]
  (17) Sadeghzadeh, H.; Morsali, A. New reversible crystal-to-crystal conversion of a mixed-ligand lead(II) coordination polymer by de-and rehydration. Inorg. Chem. 2009, 48, 10871-10873.
1. [1]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
2. [2]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
3. [3]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
4. [4]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
5. [5]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
6. [6]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
7. [7]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
8. [8]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
9. [9]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
10. [10]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
11. [11]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
12. [12]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
13. [13]
  Junying LI , Xinyan CHEN , Xihui DIAO , Muhammad Yaseen , Chao CHEN , Hao WANG , Chuansong QI , Wei LI . Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2497-2504. doi: 10.11862/CJIC.20240084
14. [14]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
15. [15]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
16. [16]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
17. [17]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
18. [18]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
19. [19]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
20. [20]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(674)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Photoluminescence of a New Pb(II) Coordination Polymer [Pb(1, 4-chdc)(L)]n·nH2OBased on a Flexible 1,4-Cyclohexanedicarboxylic Acid

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Photoluminescence of a New Pb(II) Coordination Polymer [Pb(1, 4-chdc)(L)]_n·nH₂OBased on a Flexible 1,4-Cyclohexanedicarboxylic Acid