Citation: LI Fu-An, YANG Wei-Chun, MIAO Xu, LI Song-Tian. Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-organic Coordination Polymer with Helical Chains Based on 5-(Imidazol-1-ylmethyl)isophthalic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 421-427. doi: 10.14102/j.cnki.0254-5861.2011-0878 shu

Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-organic Coordination Polymer with Helical Chains Based on 5-(Imidazol-1-ylmethyl)isophthalic Acid

1.
College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, China

Received Date: 30 June 2015
Available Online: 9 October 2015
Fund Project: This project was supported by Education Chamber of Henan Province (No.15A150068) (No.15A150068)

A novel 3D metal-organic coordination polymer with helical chains based on a flexible 5-(imidazol-1-ylmethyl)isophthalic acid (H₂L) as a main ligand and 1, 2-bis(4-pyridyl)ethane(bpa) as a N-containing ancillary ligand, [CdL(bpa)_0.5]_n (1), has been obtained under hydrothermal conditions and characterized by elemental analysis, powder X-ray diffraction (PXRD), IR, thermal gravimetric analyses (TGA) and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P2₁/c with a = 10.984(2), b = 10.1829(12), c = 17.782(3) Å, β = 123.156(11)°, V = 1665.1(5) Å³, Z = 4, M_r = 448.72, D_c = 1.790 g/cm³, R_int = 0.0871, F(000) = 892, the final R = 0.0687 and wR = 0.1294 for 2920 observed reflections (I > 2σ(I)). In complex 1, the L^2- anions connect Cd(II) ions to form two-dimensional metal-organic layers (Cd₂L₂)_n, in which the 1D helical chains (Cd-L)_n are alternately arranged in a right-and left-handed sequence. These layers are further linked to build a 3D network by the bpa ligand. In addtion, photo-luminescent properties for 1 are also investigated.
- cadmium,
- 5-(imidazol-1-ylmethyl)isophthalic acid,
- PXRD,
- luminescent properties
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